Di-palladium tris(dibenzylideneacetone)-catalyzed synthesis of five-membered N-heterocycles

The heteroatom possessing bis-allylpalladium analogs were reacted by extending the reaction of bis-allylation. The 2-alkynylisocyanobenzenes, allyl methyl carbonate, and trimethylsilyl azide were reacted by palladium-catalyzed three-component coupling reaction to afford good yields of N-cyanoindoles (Scheme 17).[84] The reaction proceeded through the formation of allylpalladium azide, and subsequently the allylpalladium intermediate was produced by the insertion of divalent carbon of isocyanide into the NPd bond of allylpalladium azide. The allylpalladium intermediate eliminated the nitrogen to form the bis-allylpalladium analog (3-allyl)(3-cyanamido)palladium complex.

 

Yamamoto et al.[85,86] synthesized 2-substituted 3-allylindoles through cyclization of alkynylbenzenes possessing isocyano and isocyanato moieties in the ortho position. The 2-substituted 3-allyl-N-cyanoindoles were formed when o-alkynylisocyanobenzenes, allyl methyl carbonate, and trimethylsilyl azide were reacted through a three-component reaction in Pd2(dba)3.3CHCl3 and tri(2-furyl)phosphine at 100 C. With a number of substituents in the aryl ring good to allowable yields were reported. The Curtius-like rearrangement of p-allylpalladiumintermediate to the palladium-carbodiimide complex
was a distinctive and interesting aspect of this mechanism. The palladium-carbodiimide and palladium-cyanamide complexes were in equilibrium. The presence of heteroatom possessing bis-p-allylpalladium complex was also suggested. The insertion of alkyne functionality into the Pd-N bond of intermediate followed by a reductive elimination of Pd(0) formed the N-cyanoindole. At 100 C temperature indoles were obtained whereas, reductive elimination of Pd(0) from the palladium-cyanamide complex occurred to produce allyl cyanamides at lower temperature (up to 40 C).[13,44]
Barluenga et al.[87] synthesized indole derivatives by a three-component reaction. This strategy involved a Pd-catalyzed cascade sequence which involved an alkenyl amination, C-arylation and a subsequent intramolecular N-arylation. During the start of the reaction equimolecular amounts of haloalkene, o-dihaloarene, and amines were mixed. The higher reactivity of haloalkene as compared to the haloarene towards the oxidative addition with palladium allowed the unique synthesis of imine intermediate. Further the deprotonation in basic media produced the corresponding aza-allylic anion. The 2-substituted indoles were formed in a subsequent Pd-assisted intermolecular alkylation with the dihalogeno substrate followed by an intramolecular N-arylation. The palladium catalyst was intervened in three different coupling reactions in this cascade reaction. Those three coupling reactions were: intermolecular N-alkenylation, C-arylation, and intramolecular N-arylation (Scheme 18).[88]

 

Barluenga et al.[87] reported a domino reaction of o-halobenzene or o-dihaloarenes sulfonates (o-chlorononaflates were the best substrates) with imines for the preparation of indoles through a selective palladium-catalyzed imine C-arylation followed by an intramolecular C–N bond formation reaction with palladium catalyst (Scheme 19).

 

Palladium catalyst was utilized for the formation of these precursors in concert with cyclization as well as simply mediated the formation of C–N bonds. Barluenga demonstrated the one example where palladium catalyst was used for the formation of two separate bonds; first through arylation of the azaallylic anion of imine the C–C bond was formed and then C-N bond was formed catalytically.[31b,44]
The reaction showed wide scope with o-dibromobenzene. The alkyl, aryl, and vinyl substituents were introduced at different positions of pyrrole ring of the indole. The regioselective preparation of indoles substituted in the benzene ring was conducted, with the advantage of different reactivities of Cl, Br, and I in oxidative addition reactions, by reacting o-dihalobenzene derivatives with two different halogens
(Scheme 20).[44,89]

 

A more general approach was developed to influence the regioselectivity using catalyst which affected the alkyne insertion step. Konno[90] found that the bulkier P(o-tol)3 ligand favored the formation of 3-CF3 substituted products whereas PPh3 preferred the generation of 2-CF3 substituted indoles (Scheme 21).

Jorgensen et al.[91] transformed primary allylamines into indoles and aza-indoles by a novel one-flask strategy through sequential aryl amination and Heck cyclization reactions in the presence of a single catalyst (Scheme 22).[92]

 

The precursors for Heck cyclization were generated by an efficient palladium catalyzed C–N bond forming reactions. Jorgensen[91] has shown that how the tandem C–N bond formation (with the aryl-iodide)/Heck cyclization cascade of starting material and allyl amines in the presence of palladium catalyst can afford one pot synthetic protocol for the formation of indoles (Scheme 23).[92,93] After screening, it was found that the dppf ligand in concert with Pd2dba3 was optimum catalyst for these two steps and it afforded a pathway for the synthesis of a variety of 3-substituted indoles.[31b]

 

The 2-haloanilines were coupled with vinylbromides in this method. Barluenga[94] has demonstrated that depending upon the used ligand, this method formed either indoles or simple imines. The indole was synthesized exclusively with bulky phosphines (Scheme 24). The o-bromoanilines were reacted with alkenyl halides for the synthesis of indoles through a domino process through an alkenyl amination followed by an intramolecular Heck reaction. The alkenyl halides reacted in the order as follows: alkenyl bromides > aryl bromides > alkenyl chlorides > aryl chlorides. The combination of 2 dicyclohexylphosphino-N,N-dimethylaminobiphenyl (DavePhos), Pd2(dba)3, and t-BuONa at 100 C in toluene afforded the best results. The reaction occurred with alkyl, aryl, and functionalized substituents in both starting substrates. The indoles were only synthesized with 1-substituted-2-bromoalkenes by cyclization of N-substituted o-bromoanilines (which provided N-substituted indoles). A catalytic combination of Pd2(dba)3 and XPhos was needed for employing this strategy to o-chloroanilines.[31b,44]

 

Ethyl 3-(o-trifluoroacetamidoaryl)-1-propargylic carbonates were reacted with primary or secondary amines to form the N-unsubstituted indole-2-acetamides with the help of 1,10-bis(dimethylphosphino)ferrocene (dppf), Pd2(dba)3, and CO at 80 C in THF (Scheme 25).[95,96] The reaction was employed for the preparation of N-unsubstituted indole 2-acetic acid methyl esters [dppf, Pd2(dba)3, MeOH/THF, CO, 24 h, 80 C].[44]

 

Kondo and coworkers[97] synthesized the indole skeleton through enamine process under solid-phase conditions in which immobilized N-(o-bromo-) and N-(o-iodoaryl) enaminoesters were cyclized to form indolecarboxylate derivatives after a transesterification step (Schemes 26 and 27). The isolated yield increased on adding P(o-tol)3. The Pd2(dba)3.3CHCl3 worked better than Pd(OAc)2 with N-(o-bromoaryl) enaminoesters.

The intramolecular cyclization of immobilized a-acetamido-b-(o-bromophenyl)acrylates was performed as a domino process under solid-phase conditions for the formation of indole through Heck reaction of solid supported N-acetyl-dehydroalanine with 2-bromophenyl triflates or 1,2-dibromobenzenes, then the formed a-acetamido-b-(obromophenyl) acrylate intermediates underwent in situ intramolecular cyclization (Scheme 28).[44,98,99]

 

The 2-substituted bromoalkenes were reacted for the synthesis of 3-substituted indoles. However, it needed N-substituted-o-haloanilines. Thus, the N-alkyl-3-substituted indoles were furnished in higher yields under similar reaction conditions (Scheme 29).[52,100]

 

The stereoselectivity, which afforded congested quaternary carbon centers in the palladium-catalyzed intramolecular Heck cyclizations, can be inverted with a silver salt (Scheme 30).[101] The coordination of angular vinyl group during the insertion step has shown high selectivity in this case.[102]

 

The o-ethynyltrifluoroacetanilide was used for the synthesis of 2-unsubstituted 3-aryl indoles in this process.[103] Much more optimization was required in the reaction of aryl iodides with anilide which possessed an o-terminal alkyne moiety, because under the standard conditions developed for o-alkynyltrifluoroacetanilides, coupling derivatives[104,105] were formed in a significant side reaction. Indeed, under a variety of reaction conditions coupling derivatives were obtained in the presence of a number of phosphine ligands. The coupling derivative was observed in 83% yield from the reaction of o-ethynyltrifluoroacetanilide with p-iodoacetophenone [Pd2(dba)3, 60 C, THF, 7 h] using tris(p-chlorophenyl)phosphine. One more significant side reaction was observed in which 2-unsubstituted 3-aryl indoles were formed with the nucleophilic attack of oxygen at the “internal” carbon of the activated C,C triple bond. The N-/O-cyclization ratio was influenced strongly by both the nature of the catalyst and the solvent. The use of DMSO as the solvent, Pd2(dba)3 as the palladium(0) source, and K2CO3 as the base in the absence of phosphine ligands afforded best results (Scheme 31). Cesium carbonate was also used successfully. The indole was obtained in 80% yield when o-ethynyltrifluoroacetanilide was reacted under same reaction conditions omitting aryl iodides.[44,49b]

 

The 2-substituted 3-acylindoles were synthesized regioselectively from 2-substituted 3-alkynylindole intermediates. The reaction regioselectivity was promoted by the addition of water in high yield in the presence of catalytic amounts of TsOH at room temperature. The regioselectivity of the acid-induced hydration was not influenced in the presence of electron-donating or electron-withdrawing substituents in the alkyne moiety or in the C2-position. The o-alkynyltrifluoroacetanilides and 1-bromoalkynes were reacted through a one-pot cyclization-hydration process for the convenient synthesis of 2-substituted 3-acylindoles and it omitted the isolation of 2-substituted 3-alkynylindoles (Scheme 32).[44,49b,103]

 

2,3-Diarylindoles possess a wide range of biological activities. This reaction is especially suitable for a straightforward synthesis of symmetrical and unsymmetrical 2,3-diarylindoles. The regioselectivity was followed from the sequence of events and is unambiguous during the synthesis of unsymmetrical 2,3-diarylindoles which was the major advantage of this protocol. Good to excellent results were observed using Pd(PPh3)4 catalyst with aryl bromides, iodides, and triflates. Aryl chlorides were more reluctant to undergo oxidative addition to Pd(0) and needed XPhos (Scheme 33),[70]

 

one of the biaryl monophosphines which increased the rate of the oxidative addition of aryl chlorides to Pd(0) species.[106–108] One of the major problems realized in this indole synthesis was solved using this ligand with relatively unreactive precursors of organopalladium complexes, like, the competitive formation of simple 2-substituted indoles, the formation of which does not involve the aryl halide partner.[44,65,67–69]

 

Metal-catalyzed amide C-arylations (Scheme 34) effectively afford the expected oxindole products.[26,109] This oxindole ring can be formed when aromatic substrates contain a halogen atom situated ortho to a moiety containing a reactive functional group. For example, intramolecular radical cyclizations and Heck cyclizations have been used to form the C3-C4 bond of the oxindole nucleus (Scheme 35).[110–116]

 

Grigg and coworkers[117] described the in situ Pd-catalyzed preparation of tributylstannyl-1,2-carbodialkylidene through one-pot protocol from 1,6-diynes and TBTH which was then further coupled with iodobenzene possessing a proximate alkene group and anion capture to provide the good yields of targeted indoline derivatives (Scheme 36).[91]

 

The alkyl, aryl, and functionalized geminal bromoalkenes participated in an indolization reaction. A new optimization was done with o-chloroanilines. When XPhos was used as a supporting ligand then only the tandem process was achieved. The indoles were synthesized with similar yields to those observed with o-bromoanilines under these conditions[52,118] (Scheme 37).

 

Spirooxindoles are key intermediates to synthesize (-)-physostigmine, (-)-eptazocine, halenaquinol, and indolizidine alkaloids.[119,120] An indolizidine and spirooxindole skeletons were synthesized as shown in Scheme 38.[121,122]

 

The starting substrates N-(o-halophenyl)allenamides were utilized in a new protocol for the formation of 3-substituted, 2-unsubstituted, and 2,3-disubstituted indoles through an intramolecular carbopalladation/anion capture domino reaction with boron nucleophiles. The 2-silylindoles were synthesized when an appropriate silicon group was selectively introduced to the a-position of the allenamide functionality. The formed 2-silylindoles were substrates for further functionalization at the C-2 position (Scheme 39). Fuwa and Sasaki[123a] described this approach based on the intramolecular carbopalladation/cyclization-anion capture protocol for the synthesis of 2,3-disubstituted indole derivatives. The palladium p-allyl intermediate was formed from allenamides which contain a substituent at the a-position through a facile carbopalladation/cyclization. The formed palladium p-allyl intermediate was then cross-coupled with a number of orgnanoboron species to provide various 2,3-disubstituted indoles.[44,123b]

 

Precedent for competitive oxidative amination in a carboamination reaction was seen previously by the Wolfe group.[124,125] For example, as shown in Scheme 40, in the reaction of N-benzyl-2-allylaniline with 4-bromotoluene to form an indoline, the oxidative amination product N-benzyl-2-methylindole was formed as a byproduct. Furthermore, oxidative amination products can even be preferentially formed over carboamination products with proper ligand choice.

 

The 2-acetylenic anilines en route to 2-amido-indoles were synthesized by aminative cross-coupling of aryl halides through metal-promoted 5-endo-dig cyclization[126–143] (Schemes 41 and 42). The ynamide 7-Br underwent amination in the presence of p-tolNH2 and 2.5 mol% Pd2(dba)3 to afford 2-amido-indole in good yields using either 5 mol% of Buchwald’s X-phos or van Leeuwen’s xantphos as ligands.[144] The reaction time decreased in the presence of X-phos in comparison to xantphos while there was no use of BINAP. On the other hand, the 2-amido-indole was formed in 78% yield by amination of 7-Cl only with X-phos. In contrast to aryl iodides, aryl chlorides and bromides performed better in this reaction.

 

The nitrogen behaved as an ambivalent atom in this operation. As a nucleophile, it intervened in the N-allylation step and in the cyclization step as a leaving group which favored the synthesis of a p-allylpalladium complex. With a number of o-alkynyltrifluoroacetanilides and allylic carbonates, these methods afforded good results. In one of the method, o-ethynyltrifluoroacetanilide was utilized to provide 2-unsubstituted 3-allylindoles in allowable yields. The substituent present on the central carbon atom of the allylic compound was tolerated, whereas the cyclization reaction was hampered when
the sterically encumbered substituents were present at one end of the alkyne moiety or the substitution was available at both termini of the allylic system. The most challenging situation to the regiochemistry of the new C-C bond was faced when there were small steric differences between the two allylic termini. The best results were observed with tris(2,4,6-trimethoxyphenyl)-phosphine (ttmpp) and the reaction afforded remarkable regioselectivity and the less substituted terminus of the allylic system bears the indole unit almost exclusively. Some loss of olefin geometry was observed in this process[44,145](Scheme 43).

 

Previously in the Wolfe group,[83,146,147] the Pd-catalyzed carboamination of c-(N-arylamino) alkenes and c-(N-Boc-amino) alkenes to afford substituted pyrrolidines has been demonstrated. For example, reaction of a 1-substituted c-(N-arylamino) alkene with 4-bromoanisole gave cis-2,5-disubstituted pyrrolidine and a regioisomer in good yield and diastereoselectivity as a 10:1 mixture of regioisomers (Scheme 44).

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CAS No. 10175-28-7 Mercury, (dichloromethyl)phenyl- Catalog No.:AG0005EV MDL No.: MF:C7H6Cl2Hg MW:361.6185	CAS No. 10175-33-4 Benzenemethanamine, 2-iodo-N,N-dimethyl- Catalog No.:AG0005EU MDL No.: MF:C9H12IN MW:261.1028	CAS No. 10175-35-6 Magnesium, butylethoxy- Catalog No.:AG0005ET MDL No.: MF:C6H14MgO MW:126.4798
CAS No. 10175-46-9 Disiloxane, 1,5-bis(1,1-dimethylethyl)-2,2,4,4-tetramethyl- Catalog No.:AG0005ES MDL No.: MF: MW:	CAS No. 10175-53-8 Silane, triethyloctyl- Catalog No.:AG0005ER MDL No.: MF:C14H32Si MW:228.4894	CAS No. 10175-95-8 Phosphonic acid, P-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-, monobutyl ester, zinc salt (2:1) Catalog No.:AG0005EQ MDL No.: MF:C38H64O8P2Zn MW:776.2375
CAS No. 10176-13-3 Phenol, 4-(2-chloroethyl)-2,6-bis(1,1-dimethylethyl)- Catalog No.:AG0005FK MDL No.: MF:C16H25ClO MW:268.8221	CAS No. 10176-23-5 2-Quinoxalineacetic acid, 3-chloro-α-cyano-, methyl ester Catalog No.:AG0005FJ MDL No.:MFCD07345521 MF:C12H8ClN3O2 MW:261.6638	CAS No. 10176-63-3 3-Pyridinecarbonitrile, 2-chloro-6-methyl-5-phenyl- Catalog No.:AG0005FI MDL No.:MFCD00231559 MF:C13H9ClN2 MW:228.6770
CAS No. 10176-84-8 3-Pyridinecarboxylic acid, 6-methyl-5-phenyl-, methyl ester Catalog No.:AG0005FH MDL No.: MF:C14H13NO2 MW:227.2585	CAS No. 10176-93-9 3-Pyridinecarbonitrile, 6-methyl-5-phenyl- Catalog No.:AG0005FG MDL No.: MF:C13H10N2 MW:194.2319	CAS No. 101760-45-6 L-Glutamic acid, N-[4-[[(2-amino-1,4-dihydro-4-oxo-6-pteridinyl)methyl]-2-propynylamino]benzoyl]- (9CI) Catalog No.:AG0005FF MDL No.: MF:C22H21N7O6 MW:479.4454
CAS No. 1017601-63-6 4(1H)-Pyridinone, 3-(4-chlorophenyl)-5,6-dihydro-1-(phenylmethyl)- Catalog No.:AG0005F4 MDL No.: MF:C18H16ClNO MW:297.7787	CAS No. 1017601-65-8 4(1H)-Pyridinone, 5,6-dihydro-1-(phenylmethyl)-3-(3,4,5-trimethoxyphenyl)- Catalog No.:AG0005F3 MDL No.: MF:C21H23NO4 MW:353.4116	CAS No. 1017601-66-9 4(1H)-Pyridinone, 5,6-dihydro-3-(3-hydroxyphenyl)-1-(phenylmethyl)- Catalog No.:AG0005F2 MDL No.: MF:C18H17NO2 MW:279.3331
CAS No. 1017603-80-3 2-Pyrazinecarboxylic acid, 5-(1-piperidinyl)-, methyl ester Catalog No.:AG0005F1 MDL No.: MF:C11H15N3O2 MW:221.2557	CAS No. 1017604-09-9 2-Pyrazinecarboxylic acid, 5-(4-morpholinyl)-, methyl ester Catalog No.:AG0005F0 MDL No.: MF:C10H13N3O3 MW:223.2285	CAS No. 1017605-89-8 4-Morpholinemethanaminium, α-fluoro-N,N-dimethyl-, hexafluorophosphate(1-) (1:1) Catalog No.:AG0005EZ MDL No.:MFCD24368601 MF: MW:
CAS No. 1017606-58-4 1-Piperazinecarboxylic acid, 4-[(2S)-2-aminopropyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005EY MDL No.:MFCD18249855 MF:C12H25N3O2 MW:243.3458	CAS No. 1017608-20-6 Phenol, 4-iodo-3-(1-methylethyl)- Catalog No.:AG0005EX MDL No.:MFCD11101057 MF:C9H11IO MW:262.0875	CAS No. 1017609-55-0 1H-Indole-2,3-dione, 5,7-dimethyl-1-(phenylmethyl)- Catalog No.:AG0005EW MDL No.:MFCD11111099 MF:C17H15NO2 MW:265.3065
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CAS No. 101766-91-0 1-Butanol, 2-methyl-4-[(tetrahydro-2H-pyran-2-yl)oxy]- Catalog No.:AG0005FB MDL No.: MF:C10H20O3 MW:188.2640	CAS No. 101767-28-6 4-Thiazolecarboxylic acid, 2-methyl-, hydrazide Catalog No.:AG0005FA MDL No.:MFCD00662677 MF:C5H7N3OS MW:157.1936	CAS No. 101767-69-5 Ethanone, 1-[3-methyl-6-(trifluoromethyl)-4H-1,4-benzothiazin-2-yl]- Catalog No.:AG0005F9 MDL No.: MF:C12H10F3NOS MW:273.2741
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CAS No. 101768-64-3 Piperidine, 4-[(4-chlorophenyl)sulfonyl]-, hydrochloride (1:1) Catalog No.:AG0005F5 MDL No.:MFCD04115824 MF:C11H15Cl2NO2S MW:296.2133	CAS No. 1017682-73-3 1H-Indazole, 7-fluoro-3-methyl- Catalog No.:AG0005FO MDL No.:MFCD17010089 MF:C8H7FN2 MW:150.1530	CAS No. 1017682-83-5 1H-Indazole, 6,7-difluoro-3-methyl- Catalog No.:AG0005FN MDL No.:MFCD28041003 MF:C8H6F2N2 MW:168.1434
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CAS No. 10177-21-6 Pyridine, 4-chloro-2-(chloromethyl)- Catalog No.:AG0005G3 MDL No.:MFCD07774098 MF:C6H5Cl2N MW:162.0166	CAS No. 10177-23-8 3-Pyridinecarboxylic acid, 6-(chloromethyl)-, ethyl ester Catalog No.:AG0005G2 MDL No.:MFCD10697587 MF:C9H10ClNO2 MW:199.6342	CAS No. 10177-24-9 Pyridine, 5-chloro-2-(chloromethyl)- Catalog No.:AG0005G1 MDL No.:MFCD10697588 MF:C6H5Cl2N MW:162.0166
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CAS No. 10177-65-8 Germane, dibromobis(2,3,4,5,6-pentafluorophenyl)- Catalog No.:AG0005FU MDL No.: MF:C12Br2F10Ge MW:566.5604	CAS No. 10177-75-0 1,2-Oxaphospholan-3-ol, 2-methoxy-3-methyl-5-(2-nitrophenyl)-, 2-oxide Catalog No.:AG0005FT MDL No.: MF:C11H14NO6P MW:287.2057	CAS No. 10177-78-3 Phosphine, bis(3-methylphenyl)- Catalog No.:AG0005FS MDL No.: MF:C14H15P MW:214.2427
CAS No. 10177-79-4 Phosphine, bis(2-methoxyphenyl)- Catalog No.:AG0005FR MDL No.: MF:C14H15O2P MW:246.2415	CAS No. 10177-98-7 Silane, pentyl- Catalog No.:AG0005FQ MDL No.: MF:C5H14Si MW:102.2502	CAS No. 101770-15-4 D-Valine, N-[N-(phenylacetyl)-L-cysteinyl]- (9CI) Catalog No.:AG0005GX MDL No.: MF:C16H22N2O4S MW:338.4219
CAS No. 101770-20-1 L-Argininamide, N-[(2Z)-3-carboxy-1-oxo-2-propenyl]-L-phenylalanyl- (9CI) Catalog No.:AG0005GW MDL No.: MF:C19H26N6O5 MW:418.4469	CAS No. 101771-59-9 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-2-(2-methylbenzoyl)- Catalog No.:AG0005GV MDL No.: MF:C12H12N2O2 MW:216.2359	CAS No. 101772-02-5 Quinoline, 2-(2H-tetrazol-5-yl)- Catalog No.:AG0005GU MDL No.: MF:C10H7N5 MW:197.1961
CAS No. 101772-29-6 L-Serine, N-[(1,1-dimethylethoxy)carbonyl]-N-methyl- Catalog No.:AG0005GT MDL No.:MFCD00037249 MF:C9H17NO5 MW:219.2350	CAS No. 101772-33-2 Benzamide, 4-(hexyloxy)- Catalog No.:AG0005GS MDL No.: MF:C13H19NO2 MW:221.2955	CAS No. 101772-41-2 1H-Imidazole-2-carboxamide, 4-[[[4-[[2-[(aminoiminomethyl)amino]acetyl]amino]-1-methyl-1H-pyrrol-2-yl]carbonyl]amino]-N-(3-amino-3-iminopropyl)-1-methyl-, sulfate (1:1) Catalog No.:AG0005GR MDL No.: MF:C17H27N11O7S MW:529.5308
CAS No. 101772-43-4 1H-Imidazole-2-carboxamide, 4-[[2-[(aminoiminomethyl)amino]acetyl]amino]-N-[2-[[(3-amino-3-iminopropyl)amino]carbonyl]-1-methyl-1H-imidazol-4-yl]-1-methyl-, sulfate (1:1) Catalog No.:AG0005GQ MDL No.: MF:C16H26N12O7S MW:530.5188	CAS No. 101772-44-5 1H-Imidazole-2-carboxamide, 4-[[[4-[[2-[(aminoiminomethyl)amino]acetyl]amino]-1-methyl-1H-imidazol-2-yl]carbonyl]amino]-N-[2-[[(3-amino-3-iminopropyl)amino]carbonyl]-1-methyl-1H-imidazol-4-yl]-1-methyl-, hydrochloride (1:2) Catalog No.:AG0005GP MDL No.: MF:C21H31Cl2N15O4 MW:628.4749	CAS No. 101772-52-5 Ethanaminium, 2-[[5-[[[5-[[(3-amino-3-iminopropyl)amino]carbonyl]-1-methyl-1H-pyrrol-3-yl]amino]carbonyl]-1-methyl-1H-pyrrol-3-yl]amino]-N,N,N-trimethyl-2-oxo-, sulfate (1:1) Catalog No.:AG0005GO MDL No.: MF:C20H32N8O7S MW:528.5825
CAS No. 101772-53-6 Silacyclohexane, 1,1,3-trimethyl- Catalog No.:AG0005GN MDL No.: MF:C8H18Si MW:142.3140	CAS No. 101772-81-0 Boronic acid, (1,1-dichloroethyl)-, dimethyl ester (9CI) Catalog No.:AG0005GM MDL No.: MF:C4H9BCl2O2 MW:170.8301	CAS No. 101773-62-0 5(1H)-Indolizinone, 2,3-dihydro- Catalog No.:AG0005GL MDL No.:MFCD19704726 MF:C8H9NO MW:135.1632
CAS No. 101774-07-6 1-Cyclobutene-1,2-dicarboxylic acid, 3-ethenyl-, 1,2-dimethyl ester Catalog No.:AG0005GK MDL No.: MF:C10H12O4 MW:196.1999	CAS No. 101774-26-9 Isoxazole, 4-bromo-3-phenyl- Catalog No.:AG0005GJ MDL No.:MFCD27940886 MF:C9H6BrNO MW:224.0540	CAS No. 101774-27-0 1H-Indole-3-carboxylic acid, 6-bromo- Catalog No.:AG0005GI MDL No.:MFCD05664008 MF:C9H6BrNO2 MW:240.0534
CAS No. 101774-33-8 4-Isoquinolinol, 3-chloro- Catalog No.:AG0005GH MDL No.:MFCD11846288 MF:C9H6ClNO MW:179.6030	CAS No. 101774-49-6 4(1H)-Quinolinone, 5-chloro- Catalog No.:AG0005GG MDL No.: MF:C9H6ClNO MW:179.6030	CAS No. 101774-57-6 Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-chloro- Catalog No.:AG0005GF MDL No.: MF:C8H11ClO2 MW:174.6247
CAS No. 101774-81-6 2,4(1H,3H)-Pyrimidinedione, 1,3-diethyl-6-(methylamino)- Catalog No.:AG0005GE MDL No.: MF:C9H15N3O2 MW:197.2343	CAS No. 101776-23-2 Isoquinoline, 1,2,3,4-tetrahydro-6,7-dimethoxy-1-propyl-, hydrochloride (1:1) Catalog No.:AG0005GD MDL No.: MF:C14H22ClNO2 MW:271.7830	CAS No. 1017777-45-5 Ethanone, 1-(4-chloro-2,6-difluorophenyl)- Catalog No.:AG0005GC MDL No.:MFCD09832259 MF:C8H5ClF2O MW:190.5745
CAS No. 1017777-58-0 Benzenamine, 2-chloro-6-fluoro-3-methoxy- Catalog No.:AG0005GB MDL No.:MFCD09832265 MF:C7H7ClFNO MW:175.5880	CAS No. 1017777-60-4 Phenol, 2-chloro-6-fluoro-3-methoxy- Catalog No.:AG0005GA MDL No.:MFCD09832266 MF:C7H6ClFO2 MW:176.5727	CAS No. 1017777-83-1 Benzeneacetic acid, 6-chloro-2-fluoro-3-methoxy- Catalog No.:AG0005HM MDL No.:MFCD09832273 MF:C9H8ClFO3 MW:218.6094
CAS No. 1017777-92-2 Benzenamine, 2,3-dichloro-6-(trifluoromethyl)- Catalog No.:AG0005HL MDL No.:MFCD09832277 MF:C7H4Cl2F3N MW:230.0146	CAS No. 1017777-98-8 Benzenepropanoic acid, 2-methyl-3-(trifluoromethyl)- Catalog No.:AG0005HK MDL No.:MFCD09832282 MF:C11H11F3O2 MW:232.1990	CAS No. 1017778-05-0 Phenol, 2-methyl-5-(trifluoromethyl)- Catalog No.:AG0005HJ MDL No.:MFCD09832287 MF:C8H7F3O MW:176.1358
CAS No. 1017778-60-7 Benzoic acid, 3,4-difluoro-5-methyl- Catalog No.:AG0005HI MDL No.:MFCD09832332 MF:C8H6F2O2 MW:172.1288	CAS No. 1017778-64-1 Benzaldehyde, 3,4-difluoro-5-methyl- Catalog No.:AG0005HH MDL No.:MFCD09832333 MF:C8H6F2O MW:156.1294	CAS No. 1017779-10-0 Benzeneacetic acid, 2-methoxy-6-(trifluoromethyl)- Catalog No.:AG0005HG MDL No.:MFCD09832328 MF:C10H9F3O3 MW:234.1719
CAS No. 1017779-42-8 Benzene, 1-(bromomethyl)-2-(difluoromethoxy)-4-fluoro- Catalog No.:AG0005HF MDL No.:MFCD09832363 MF:C8H6BrF3O MW:255.0318	CAS No. 1017779-48-4 Benzaldehyde, 4-ethoxy-2,6-difluoro- Catalog No.:AG0005HE MDL No.:MFCD09258695 MF:C9H8F2O2 MW:186.1554	CAS No. 1017779-51-9 Benzene, 2-(bromomethyl)-5-ethoxy-1,3-difluoro- Catalog No.:AG0005HD MDL No.:MFCD09258697 MF:C9H9BrF2O MW:251.0680
CAS No. 1017779-56-4 Benzenepropanoic acid, 3-fluoro-5-methyl- Catalog No.:AG0005HC MDL No.:MFCD09832369 MF:C10H11FO2 MW:182.1915	CAS No. 1017779-62-2 Benzeneacetic acid, 4-ethoxy-2,3-difluoro- Catalog No.:AG0005HB MDL No.:MFCD09258707 MF:C10H10F2O3 MW:216.1814	CAS No. 1017779-69-9 Benzenamine, 3-fluoro-4-(trifluoromethoxy)- Catalog No.:AG0005HA MDL No.:MFCD09832383 MF:C7H5F4NO MW:195.1143
CAS No. 1017779-71-3 Benzenamine, 4,5-difluoro-2-methoxy- Catalog No.:AG0005H9 MDL No.:MFCD09832387 MF:C7H7F2NO MW:159.1334	CAS No. 1017779-75-7 Benzenesulfonyl chloride, 2,3,6-trifluoro- Catalog No.:AG0005H8 MDL No.:MFCD09832391 MF:C6H2ClF3O2S MW:230.5921	CAS No. 1017779-90-6 Benzoyl chloride, 3-ethoxy-2,4-difluoro- Catalog No.:AG0005H7 MDL No.:MFCD09258724 MF:C9H7ClF2O2 MW:220.6005
CAS No. 1017781-16-6 1H-Pyrazol-5-amine, 1-(2,3-dichlorophenyl)-3-(1,1-dimethylethyl)- Catalog No.:AG0005H6 MDL No.:MFCD04115079 MF:C13H15Cl2N3 MW:284.1843	CAS No. 1017781-18-8 1H-Pyrazol-5-amine, 1-(2,4-dichlorophenyl)-3-(1,1-dimethylethyl)- Catalog No.:AG0005H5 MDL No.:MFCD04115080 MF:C13H15Cl2N3 MW:284.1843	CAS No. 1017781-19-9 1H-Pyrazol-5-amine, 1-(2,6-dichlorophenyl)-3-(1,1-dimethylethyl)- Catalog No.:AG0005H4 MDL No.:MFCD04115081 MF:C13H15Cl2N3 MW:284.1843
CAS No. 1017781-20-2 1H-Pyrazol-5-amine, 1-(2,5-dichlorophenyl)-3-(1,1-dimethylethyl)- Catalog No.:AG0005H3 MDL No.:MFCD04115089 MF:C13H15Cl2N3 MW:284.1843	CAS No. 1017781-23-5 1H-Pyrazole-3-carboxylic acid, 5-[4-(methylthio)phenyl]-1-[4-(trifluoromethyl)phenyl]- Catalog No.:AG0005H2 MDL No.:MFCD04115084 MF:C18H13F3N2O2S MW:378.3682	CAS No. 1017781-24-6 1H-Pyrazole-3-carboxylic acid, 1-cyclohexyl-5-[4-(methylthio)phenyl]- Catalog No.:AG0005H1 MDL No.:MFCD04115102 MF:C17H20N2O2S MW:316.4179
CAS No. 1017781-25-7 1H-Pyrazole-4-carboxylic acid, 5-[[(1,1-dimethylethoxy)carbonyl]amino]-1-(4-fluorophenyl)- Catalog No.:AG0005H0 MDL No.:MFCD04115103 MF:C15H16FN3O4 MW:321.3036	CAS No. 1017781-26-8 1H-Pyrazole-4-carboxylic acid, 1-(4-fluorophenyl)-5-[[(phenylmethoxy)carbonyl]amino]- Catalog No.:AG0005GZ MDL No.:MFCD04115104 MF:C18H14FN3O4 MW:355.3199	CAS No. 1017781-27-9 1H-Pyrazol-5-amine, 3-(3-bromophenyl)-1-methyl- Catalog No.:AG0005GY MDL No.:MFCD06738293 MF:C10H10BrN3 MW:252.1105
CAS No. 1017781-28-0 1H-Pyrazol-5-amine, 3-(3-fluorophenyl)-1-methyl- Catalog No.:AG0005IB MDL No.:MFCD06738294 MF:C10H10FN3 MW:191.2049	CAS No. 1017781-30-4 1H-Pyrazol-5-amine, 3-(4-bromophenyl)-1-(1-methylethyl)- Catalog No.:AG0005IA MDL No.:MFCD06738300 MF:C12H14BrN3 MW:280.1637	CAS No. 1017781-31-5 1H-Pyrazole-4-carbothioamide Catalog No.:AG0005I9 MDL No.:MFCD06738945 MF:C4H5N3S MW:127.1676
CAS No. 1017781-34-8 1H-Pyrazol-5-amine, 3-(4-iodophenyl)-1-phenyl- Catalog No.:AG0005I8 MDL No.:MFCD06738765 MF:C15H12IN3 MW:361.1803	CAS No. 1017781-35-9 1H-Pyrazol-5-amine, 3-(3-iodophenyl)-1-phenyl- Catalog No.:AG0005I7 MDL No.:MFCD06738298 MF:C15H12IN3 MW:361.1803	CAS No. 1017781-36-0 1H-Pyrazol-5-amine, 1-phenyl-3-propyl- Catalog No.:AG0005I6 MDL No.:MFCD06738761 MF:C12H15N3 MW:201.2676
CAS No. 1017781-37-1 1H-Pyrazol-5-amine, 3-ethyl-1-phenyl- Catalog No.:AG0005I5 MDL No.:MFCD02255835 MF:C11H13N3 MW:187.2410	CAS No. 1017781-38-2 1H-Pyrazol-5-amine, 3-(4-iodophenyl)-1-(1-methylethyl)- Catalog No.:AG0005I4 MDL No.:MFCD06738299 MF:C12H14IN3 MW:327.1641	CAS No. 1017781-39-3 2-Naphthalenesulfonic acid, 1,2,3,4-tetrahydro-2-hydroxy-6-methoxy-, sodium salt (1:1) Catalog No.:AG0005I3 MDL No.:MFCD05663953 MF:C11H13NaO5S MW:280.2727
CAS No. 1017781-43-9 2H-Pyran-4-carboxamide, tetrahydro-N-methyl- Catalog No.:AG0005I2 MDL No.:MFCD09997712 MF:C7H13NO2 MW:143.1836	CAS No. 1017781-45-1 Benzenepropanoic acid, 4-[[(1,1-dimethylethoxy)carbonyl]amino]-β-oxo-, ethyl ester Catalog No.:AG0005I1 MDL No.:MFCD09997714 MF:C16H21NO5 MW:307.3416	CAS No. 1017781-46-2 Benzenepropanoic acid, 2-[[(1,1-dimethylethoxy)carbonyl]amino]-β-oxo-, ethyl ester Catalog No.:AG0005I0 MDL No.:MFCD09997715 MF:C16H21NO5 MW:307.3416
CAS No. 1017781-47-3 Benzenepropanoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-β-oxo-, ethyl ester Catalog No.:AG0005HZ MDL No.:MFCD09997716 MF:C16H21NO5 MW:307.3416	CAS No. 1017781-48-4 1-Piperidinecarboxylic acid, 4-[3-(3-bromophenyl)-1,3-dioxopropyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005HY MDL No.:MFCD09997717 MF:C19H24BrNO4 MW:410.3022	CAS No. 1017781-49-5 1-Piperidinecarboxylic acid, 4-[3-(4-bromophenyl)-1,3-dioxopropyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005HX MDL No.:MFCD09997718 MF:C19H24BrNO4 MW:410.3022
CAS No. 1017781-50-8 1-Piperidinecarboxylic acid, 4-[3-(4-chlorophenyl)-1,3-dioxopropyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005HW MDL No.:MFCD09997719 MF:C19H24ClNO4 MW:365.8512	CAS No. 1017781-51-9 1-Piperidinecarboxylic acid, 4-[3-(3-chlorophenyl)-1,3-dioxopropyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005HV MDL No.:MFCD09997720 MF:C19H24ClNO4 MW:365.8512	CAS No. 1017781-52-0 2-Thiazolecarbonitrile, 4-bromo- Catalog No.:AG0005HU MDL No.:MFCD09607690 MF:C4HBrN2S MW:189.0331
CAS No. 1017781-53-1 1-Piperidinecarboxylic acid, 4-(1,3-dioxo-3-phenylpropyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005HT MDL No.:MFCD09997722 MF:C19H25NO4 MW:331.4061	CAS No. 1017781-55-3 Ethanone, 1-[4-(aminomethyl)phenyl]-2-(4-methoxyphenyl)- Catalog No.:AG0005HS MDL No.:MFCD09997752 MF:C16H17NO2 MW:255.3117	CAS No. 1017781-57-5 3-Thiopheneethanamine, α-(trifluoromethyl)- Catalog No.:AG0005HR MDL No.:MFCD09997754 MF:C7H8F3NS MW:195.2053
CAS No. 1017781-58-6 4-Piperidinol, 1-(4-bromo-2-thiazolyl)- Catalog No.:AG0005HQ MDL No.:MFCD09607693 MF:C8H11BrN2OS MW:263.1547	CAS No. 1017781-59-7 Carbamic acid, N-[[4-[2-(4-chlorophenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005HP MDL No.:MFCD09997756 MF:C20H22ClNO3 MW:359.8466	CAS No. 1017781-60-0 Morpholine, 4-(4-bromo-2-thiazolyl)- Catalog No.:AG0005HO MDL No.:MFCD09607696 MF:C7H9BrN2OS MW:249.1282
CAS No. 1017781-61-1 Ethanone, 1-[4-(aminomethyl)phenyl]-2-(4-chlorophenyl)- Catalog No.:AG0005HN MDL No.:MFCD09997757 MF:C15H14ClNO MW:259.7308	CAS No. 1017781-63-3 Carbamic acid, N-[[3-[2-(4-chlorophenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005J0 MDL No.:MFCD09997759 MF:C20H22ClNO3 MW:359.8466	CAS No. 1017781-64-4 4-Piperidinol, 1-(6-bromo-2-pyridinyl)- Catalog No.:AG0005IZ MDL No.:MFCD09607698 MF:C10H13BrN2O MW:257.1270
CAS No. 1017781-65-5 Ethanone, 1-[3-(aminomethyl)phenyl]-2-(4-chlorophenyl)- Catalog No.:AG0005IY MDL No.:MFCD09997760 MF:C15H14ClNO MW:259.7308	CAS No. 1017781-66-6 Carbamic acid, N-[[4-(2-phenylacetyl)phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IX MDL No.:MFCD09997764 MF:C20H23NO3 MW:325.4015	CAS No. 1017781-67-7 Ethanone, 1-[3-(aminomethyl)phenyl]-2-phenyl- Catalog No.:AG0005IW MDL No.:MFCD09997765 MF:C15H15NO MW:225.2857
CAS No. 1017781-68-8 Morpholine, 4-(5-chloro-2-pyrazinyl)- Catalog No.:AG0005IV MDL No.: MF:C8H10ClN3O MW:199.6375	CAS No. 1017781-69-9 Carbamic acid, N-[[4-[2-(4-fluorophenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IU MDL No.:MFCD09997767 MF:C20H22FNO3 MW:343.3920	CAS No. 1017781-71-3 Ethanone, 1-[4-(aminomethyl)phenyl]-2-(4-fluorophenyl)- Catalog No.:AG0005IT MDL No.:MFCD09997768 MF:C15H14FNO MW:243.2762
CAS No. 1017781-73-5 Carbamic acid, N-[[3-[2-(4-fluorophenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IS MDL No.:MFCD09997770 MF:C20H22FNO3 MW:343.3920	CAS No. 1017781-75-7 Ethanone, 1-[3-(aminomethyl)phenyl]-2-(4-fluorophenyl)- Catalog No.:AG0005IR MDL No.:MFCD09997771 MF:C15H14FNO MW:243.2762	CAS No. 1017781-77-9 Carbamic acid, N-[[4-[2-(4-methylphenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IQ MDL No.:MFCD09997773 MF:C21H25NO3 MW:339.4281
CAS No. 1017781-79-1 Ethanone, 1-[4-(aminomethyl)phenyl]-2-(4-methylphenyl)- Catalog No.:AG0005IP MDL No.:MFCD09997774 MF:C16H17NO MW:239.3123	CAS No. 1017781-81-5 Carbamic acid, N-[[3-[2-(4-methylphenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IO MDL No.:MFCD09997776 MF:C21H25NO3 MW:339.4281	CAS No. 1017781-83-7 Carbamic acid, N-[[4-[2-(4-methoxyphenyl)acetyl]phenyl]methyl]-, 1,1-dimethylethyl ester Catalog No.:AG0005IN MDL No.:MFCD09997777 MF:C21H25NO4 MW:355.4275
CAS No. 1017781-88-2 Carbamic acid, N-(2-amino-6-bromophenyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005IM MDL No.:MFCD09997784 MF:C11H15BrN2O2 MW:287.1530	CAS No. 1017781-90-6 1H-Indazole, 3-chloro-1-(3-pyridinylmethyl)- Catalog No.:AG0005IL MDL No.:MFCD09997802 MF:C13H10ClN3 MW:243.6916	CAS No. 1017781-91-7 Pyrimidine, 4,6-dichloro-2-(1-piperazinyl)- Catalog No.:AG0005IK MDL No.: MF:C8H10Cl2N4 MW:233.0978
CAS No. 1017781-92-8 1H-Indazole, 3-chloro-1-(2-pyridinylmethyl)- Catalog No.:AG0005IJ MDL No.:MFCD09997803 MF:C13H10ClN3 MW:243.6916	CAS No. 1017781-94-0 1H-Indazole, 3-bromo-5,6-difluoro- Catalog No.:AG0005II MDL No.:MFCD09997805 MF:C7H3BrF2N2 MW:233.0129	CAS No. 1017781-96-2 Oxazolo[4,5-c]pyridine, 2-(4-bromophenyl)-4,5,6,7-tetrahydro-5-methyl- Catalog No.:AG0005IH MDL No.:MFCD09997824 MF:C13H13BrN2O MW:293.1591
CAS No. 1017781-98-4 Oxazolo[4,5-c]pyridine, 4,5,6,7-tetrahydro-2,5-dimethyl- Catalog No.:AG0005IG MDL No.:MFCD09997826 MF:C8H12N2O MW:152.1937	CAS No. 1017782-05-6 4-Piperidinamine, 3-methyl-1-(1-methylethyl)- Catalog No.:AG0005IF MDL No.:MFCD09997859 MF:C9H20N2 MW:156.2685	CAS No. 1017782-07-8 2-Pyridinamine, 6-methoxy-3-nitro-5-phenyl- Catalog No.:AG0005IE MDL No.:MFCD09997887 MF:C12H11N3O3 MW:245.2340
CAS No. 1017782-09-0 2-Pyridinamine, 5-bromo-6-methoxy-3-nitro- Catalog No.:AG0005ID MDL No.:MFCD09997888 MF:C6H6BrN3O3 MW:248.0341	CAS No. 1017782-11-4 Carbamic acid, N-(3-amino-6-chloro-2-pyridinyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005IC MDL No.:MFCD09997889 MF:C10H14ClN3O2 MW:243.6901	CAS No. 1017782-13-6 Carbamic acid, N-(6-chloro-3-nitro-2-pyridinyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005JP MDL No.:MFCD09997890 MF:C10H12ClN3O4 MW:273.6730
CAS No. 1017782-15-8 Imidazo[1,2-a]pyrazine-2-carboxaldehyde Catalog No.:AG0005JO MDL No.:MFCD09995736 MF:C7H5N3O MW:147.1341	CAS No. 1017782-21-6 4H-Pyrrolo[3,4-c]quinolin-4-one, 1,2,3,3a,5,9b-hexahydro-2-(phenylmethyl)- Catalog No.:AG0005JN MDL No.:MFCD09997913 MF:C18H18N2O MW:278.3483	CAS No. 1017782-45-4 1H-Pyrazole-4-carboxylic acid, 3-(1,1-dimethylethyl)-, methyl ester Catalog No.:AG0005JM MDL No.:MFCD00829900 MF:C9H14N2O2 MW:182.2197
CAS No. 1017782-64-7 Pyridine, 5-bromo-2-chloro-3-(chloromethyl)- Catalog No.:AG0005JL MDL No.:MFCD09865020 MF:C6H4BrCl2N MW:240.9127	CAS No. 1017782-65-8 3-Piperidinecarboxylic acid, 1-[[[(1,1-dimethylethoxy)carbonyl](phenylmethyl)amino]sulfonyl]- Catalog No.:AG0005JK MDL No.:MFCD09972238 MF:C18H26N2O6S MW:398.4738	CAS No. 1017782-79-4 1-Piperazinecarboxylic acid, 4-(3-methoxy-4-nitrophenyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005JJ MDL No.:MFCD09972251 MF:C16H23N3O5 MW:337.3709
CAS No. 1017782-89-6 3-Piperidinecarboxylic acid, 1-[[(2-bromoethyl)[(1,1-dimethylethoxy)carbonyl]amino]sulfonyl]-, ethyl ester Catalog No.:AG0005JI MDL No.:MFCD09972257 MF:C15H27BrN2O6S MW:443.3537	CAS No. 1017782-91-0 Methanone, (5-bromo-3-pyridinyl)-1-piperazinyl- Catalog No.:AG0005JH MDL No.:MFCD09972258 MF:C10H12BrN3O MW:270.1258	CAS No. 1017782-99-8 3-Pyridinecarboxylic acid, 5-bromo-2-(4-morpholinyl)-, methyl ester Catalog No.:AG0005JG MDL No.:MFCD09972266 MF:C11H13BrN2O3 MW:301.1365
CAS No. 1017783-03-7 3-Pyridinecarboxylic acid, 5-bromo-2-(4-morpholinyl)- Catalog No.:AG0005JF MDL No.:MFCD09972268 MF:C10H11BrN2O3 MW:287.1099	CAS No. 1017783-09-3 2H-3,1-Benzoxazin-2-one, 6-bromo-1,4-dihydro- Catalog No.:AG0005JE MDL No.:MFCD09972273 MF:C8H6BrNO2 MW:228.0427	CAS No. 1017784-36-9 1H-Pyrazole-4-carboxylic acid, 3-(4-fluorophenyl)-, methyl ester Catalog No.:AG0005JD MDL No.: MF:C11H9FN2O2 MW:220.1998
CAS No. 1017785-26-0 1H-Pyrazole-4-methanamine, 5-amino-1-(4-fluorophenyl)- Catalog No.:AG0005JC MDL No.:MFCD06212838 MF:C10H11FN4 MW:206.2195	CAS No. 1017785-80-6 Benzenemethanamine, 4-(1H-pyrazol-3-yl)- Catalog No.:AG0005JB MDL No.:MFCD11200994 MF:C10H11N3 MW:173.2144	CAS No. 1017786-10-5 2-Propenoic acid, 3-[1,3-dimethyl-5-(4-morpholinyl)-1H-pyrazol-4-yl]- Catalog No.:AG0005JA MDL No.: MF:C12H17N3O3 MW:251.2817
CAS No. 1017788-63-4 1-Piperidinecarboxylic acid, 2-cyano-, phenylmethyl ester Catalog No.:AG0005J9 MDL No.:MFCD08704536 MF:C14H16N2O2 MW:244.2890	CAS No. 1017788-66-7 3-Quinolinecarbonitrile, 4-chloro-7-hydroxy- Catalog No.:AG0005J8 MDL No.: MF:C10H5ClN2O MW:204.6125	CAS No. 1017789-01-3 Pyrimidine, 5-bromo-2-(2-bromo-4-methylphenoxy)- Catalog No.:AG0005J7 MDL No.: MF:C11H8Br2N2O MW:344.0020
CAS No. 1017789-07-9 Pyrimidine, 5-bromo-2-(4-pyridinyloxy)- Catalog No.:AG0005J6 MDL No.: MF:C9H6BrN3O MW:252.0674	CAS No. 1017789-08-0 1,2,4-Triazolo[4,3-a]pyrimidine-3-carboxylic acid, 5,7-dimethyl-, ethyl ester Catalog No.:AG0005J5 MDL No.: MF:C10H12N4O2 MW:220.2279	CAS No. 1017789-14-8 2-Thiophenecarbonitrile, 3-amino-5-bromo- Catalog No.:AG0005J4 MDL No.:MFCD09991574 MF:C5H3BrN2S MW:203.0597
CAS No. 1017789-16-0 2-Thiophenecarbonitrile, 3-amino-5-ethyl- Catalog No.:AG0005J3 MDL No.: MF:C7H8N2S MW:152.2168	CAS No. 1017789-26-2 Benzamide, 2-amino-3-fluoro-N-methyl- Catalog No.:AG0005J2 MDL No.: MF:C8H9FN2O MW:168.1683	CAS No. 1017789-28-4 2-Propenoic acid, 2-ethoxy-3-[4-(phenylmethoxy)phenyl]- Catalog No.:AG0005J1 MDL No.: MF:C18H18O4 MW:298.3331
CAS No. 1017789-30-8 1,3,8-Triazaspiro[4.5]dec-1-en-4-one, 8-(phenylmethyl)- Catalog No.:AG0005KE MDL No.: MF:C14H17N3O MW:243.3043	CAS No. 1017789-33-1 Benzeneacetic acid, α-(3-bromopropyl)-4-chloro- Catalog No.:AG0005KD MDL No.:MFCD09991598 MF:C11H12BrClO2 MW:291.5688	CAS No. 1017789-34-2 3,6-Diazabicyclo[3.2.0]heptane-3-carboxylic acid, 1,1-dimethylethyl ester Catalog No.:AG0005KC MDL No.:MFCD09991607 MF:C10H18N2O2 MW:198.2621
CAS No. 1017789-36-4 1-Piperidinecarboxylic acid, 4-[3-methoxy-3-oxo-2-[[(phenylmethoxy)carbonyl]amino]-1-propen-1-yl]-, 1,1-dimethylethyl ester Catalog No.:AG0005KB MDL No.: MF:C22H30N2O6 MW:418.4834	CAS No. 1017789-37-5 1-Piperidinecarboxylic acid, 3-[3-methoxy-3-oxo-2-[[(phenylmethoxy)carbonyl]amino]-1-propen-1-yl]-, 1,1-dimethylethyl ester Catalog No.:AG0005KA MDL No.: MF:C22H30N2O6 MW:418.4834	CAS No. 1017789-38-6 Carbamic acid, N-(4,6-dichloro-2-pyridinyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005K9 MDL No.:MFCD09991634 MF:C10H12Cl2N2O2 MW:263.1205
CAS No. 1017789-39-7 Benzenepropanoic acid, 4-chloro-β-[[(1,1-dimethylethoxy)carbonyl]amino]-, phenylmethyl ester Catalog No.:AG0005K8 MDL No.: MF:C21H24ClNO4 MW:389.8726	CAS No. 1017789-40-0 1-Pyrrolidinecarboxylic acid, 3-amino-4-(hydroxymethyl)-, phenylmethyl ester Catalog No.:AG0005K7 MDL No.:MFCD09991641 MF:C13H18N2O3 MW:250.2936	CAS No. 1017789-45-5 Propanamide, N-(2,3-dimethyl-4-nitrophenyl)-2,2-dimethyl- Catalog No.:AG0005K6 MDL No.: MF:C13H18N2O3 MW:250.2936
CAS No. 1017789-46-6 Phosphonic acid, P,P'-9,10-anthracenediylbis-, P,P,P',P'-tetraethyl ester Catalog No.:AG0005K5 MDL No.:MFCD09991665 MF:C22H28O6P2 MW:450.4016	CAS No. 1017789-47-7 Propanamide, N-(2,3-dimethyl-6-nitrophenyl)-2,2-dimethyl- Catalog No.:AG0005K4 MDL No.: MF:C13H18N2O3 MW:250.2936	CAS No. 1017789-48-8 Benzenebutanol, 2,4-dinitro- Catalog No.:AG0005K3 MDL No.: MF:C10H12N2O5 MW:240.2127
CAS No. 1017789-49-9 2-Propenoic acid, 4-(2,4-dinitrophenyl)butyl ester Catalog No.:AG0005K2 MDL No.: MF:C13H14N2O6 MW:294.2601	CAS No. 1017789-50-2 2-Propenamide, N-[2-(3,5-dinitrophenyl)ethyl]- Catalog No.:AG0005K1 MDL No.: MF:C11H11N3O5 MW:265.2221	CAS No. 1017789-55-7 1-Piperidineacetic acid, α-(4-fluorophenyl)-4-oxo-, ethyl ester Catalog No.:AG0005K0 MDL No.: MF:C15H18FNO3 MW:279.3067
CAS No. 1017789-57-9 Benzeneacetic acid, α-acetyl-4-fluoro-2-nitro-, ethyl ester Catalog No.:AG0005JZ MDL No.: MF:C12H12FNO5 MW:269.2258	CAS No. 1017789-63-7 Benzenemethanol, 3-methoxy-4-(4-methyl-1H-imidazol-1-yl)- Catalog No.:AG0005JY MDL No.:MFCD09991721 MF:C12H14N2O2 MW:218.2518	CAS No. 1017789-65-9 Cyclopropanecarboxamide, N-(methoxymethyl)-1-(trifluoromethyl)- Catalog No.:AG0005JX MDL No.: MF:C7H10F3NO2 MW:197.1550
CAS No. 1017789-66-0 Carbamic acid, N-(1-methyl-3-azetidinyl)-, 1,1-dimethylethyl ester Catalog No.:AG0005JW MDL No.: MF:C9H18N2O2 MW:186.2514	CAS No. 1017789-68-2 Benzenepropanoic acid, 3-bromo-β-[(2-phenylacetyl)amino]- Catalog No.:AG0005JV MDL No.: MF:C17H16BrNO3 MW:362.2178	CAS No. 1017789-70-6 Benzoic acid, 2,3,5,6-tetrafluoro-4-[(6-hydroxyhexyl)oxy]- Catalog No.:AG0005JU MDL No.: MF:C13H14F4O4 MW:310.2415
CAS No. 1017789-71-7 Benzoic acid, 2,3,5,6-tetrafluoro-4-[(8-hydroxyoctyl)oxy]- Catalog No.:AG0005JT MDL No.: MF:C15H18F4O4 MW:338.2946	CAS No. 1017789-74-0 1H-Pyrrole-3-acetic acid, 1-[(4-methylphenyl)sulfonyl]- Catalog No.:AG0005JS MDL No.: MF:C13H13NO4S MW:279.3116	CAS No. 1017791-37-5 2H-1,4-Benzoxazine-6-sulfonyl chloride, 4-acetyl-3,4-dihydro- Catalog No.:AG0005JR MDL No.:MFCD09972061 MF:C10H10ClNO4S MW:275.7087
CAS No. 1017793-08-6 Pyridazine, 3-ethynyl- Catalog No.:AG0005JQ MDL No.:MFCD16988473 MF:C6H4N2 MW:104.1094	CAS No. 1017793-12-2 1H-Indazole-4-carboxylic acid, 1-acetyl- Catalog No.:AG0005KK MDL No.: MF:C10H8N2O3 MW:204.1821	CAS No. 1017793-20-2 Pyridine, 2,5-difluoro-4-iodo- Catalog No.:AG0005KJ MDL No.:MFCD11040606 MF:C5H2F2IN MW:240.9774
CAS No. 1017793-21-3 Pyridine, 4-bromo-3-chloro-2-fluoro- Catalog No.:AG0005KI MDL No.:MFCD11040607 MF:C5H2BrClFN MW:210.4315	CAS No. 1017793-59-7 1,6-NAPHTHYRIDINE-3-CARBOXYLIC ACID Catalog No.:AG0005KH MDL No.:MFCD07366468 MF:C9H6N2O2 MW:174.1561	CAS No. 1017794-49-8 2-Thiophenecarboxylic acid, 5-(1H-pyrazol-4-yl)- Catalog No.:AG0005KG MDL No.:MFCD08056305 MF:C8H6N2O2S MW:194.2104
CAS No. 1017798-34-3 1-Piperidinecarboxylic acid, 3-mercapto-, 1,1-dimethylethyl ester Catalog No.:AG0005KF MDL No.:MFCD10566038 MF:C10H19NO2S MW:217.3284	CAS No. 10178-13-9 Cyclohexanone, 2,6-dimethyl-2-phenyl- Catalog No.:AG0005L3 MDL No.: MF:C14H18O MW:202.2921	CAS No. 10178-53-7 Benzene, 1-bromo-2-[(2-methyl-2-propen-1-yl)oxy]- Catalog No.:AG0005L2 MDL No.: MF:C10H11BrO MW:227.0977
CAS No. 10178-55-9 Benzofuran, 7-chloro-2,3-dihydro-2,2-dimethyl- Catalog No.:AG0005L1 MDL No.:MFCD11858104 MF:C10H11ClO MW:182.6467	CAS No. 101781-84-4 Benzeneethanamine, N-[(3-ethoxy-4-methoxyphenyl)methyl]- Catalog No.:AG0005KT MDL No.: MF:C18H23NO2 MW:285.3807	CAS No. 101782-07-4 Benzenemethanol, α-[4-(4-amino-2-methoxyphenoxy)butyl]- Catalog No.:AG0005KS MDL No.: MF:C18H23NO3 MW:301.3801
CAS No. 101782-20-1 1H-Indole-3-carboxylic acid, 1-cyclohexyl-5-hydroxy-2-methyl-, ethyl ester Catalog No.:AG0005KR MDL No.:MFCD00408072 MF:C18H23NO3 MW:301.3801	CAS No. 101782-77-8 1H-Pyrazol-5-amine, 1,4-diphenyl-3-propyl- Catalog No.:AG0005KQ MDL No.: MF:C18H19N3 MW:277.3636	CAS No. 101783-96-4 Benzene, 1,1'-(1,6-hexanediyl)bis[4-bromo- Catalog No.:AG0005KP MDL No.: MF:C18H20Br2 MW:396.1594
CAS No. 101784-86-5 Acetamide, 2-(diethylamino)-N,N-diphenyl- Catalog No.:AG0005KO MDL No.: MF:C18H22N2O MW:282.3801	CAS No. 101787-58-0 1,4-Butanediol, 2,3-bis(phenylmethyl)- Catalog No.:AG0005KN MDL No.: MF:C18H22O2 MW:270.3661	CAS No. 101789-77-9 Benzoic acid, 2-[4-(2-methylpropyl)benzoyl]- Catalog No.:AG0005KM MDL No.: MF:C18H18O3 MW:282.3337
CAS No. 10179-54-1 Benzenamine, 4-(4,5-dihydro-1,3-diphenyl-1H-pyrazol-5-yl)- Catalog No.:AG0005L0 MDL No.: MF:C21H19N3 MW:313.3957	CAS No. 10179-72-3 Acetamide, N-[4-(4,5-dihydro-1,3-diphenyl-1H-pyrazol-5-yl)phenyl]- Catalog No.:AG0005KZ MDL No.: MF:C23H21N3O MW:355.4323	CAS No. 10179-83-6 3H-1,2,3-Triazolo[4,5-d]pyrimidine, 7-methyl- Catalog No.:AG0005KY MDL No.: MF:C5H5N5 MW:135.1267
CAS No. 10179-84-7 3H-1,2,3-Triazolo[4,5-d]pyrimidin-5-amine Catalog No.:AG0005KX MDL No.:MFCD20616954 MF:C4H4N6 MW:136.1148	CAS No. 10179-89-2 9H-Purin-2-amine, 8-(trifluoromethyl)- Catalog No.:AG0005KW MDL No.:MFCD08275968 MF:C6H4F3N5 MW:203.1247	CAS No. 10179-91-6 9H-Purine, 8-(methylsulfonyl)- Catalog No.:AG0005KV MDL No.: MF:C6H6N4O2S MW:198.2024
CAS No. 10179-95-0 9H-Purine, 2,8-bis(methylthio)- Catalog No.:AG0005KU MDL No.: MF:C7H8N4S2 MW:212.2952	CAS No. 101791-26-8 Undecanoic acid, 11-(hexylsulfinyl)- Catalog No.:AG0005KL MDL No.: MF:C17H34O3S MW:318.5151	CAS No. 101791-78-0 Nonane, 1-[2-(2-butoxyethoxy)ethoxy]- Catalog No.:AG0005LI MDL No.: MF:C17H36O3 MW:288.4659
CAS No. 101791-79-1 Nonane, 1-[2-[2-(2-methylpropoxy)ethoxy]ethoxy]- Catalog No.:AG0005LH MDL No.: MF:C17H36O3 MW:288.4659	CAS No. 101792-66-9 2H-Imidazol-2-one, 1-(diphenylmethyl)-3-ethyl-1,3-dihydro- Catalog No.:AG0005LG MDL No.: MF:C18H18N2O MW:278.3483	CAS No. 101793-61-7 Ethanone, 2-(4-morpholinyl)-1-(10H-phenoxazin-10-yl)- Catalog No.:AG0005LF MDL No.: MF:C18H18N2O3 MW:310.3471
CAS No. 101796-28-5 Uridine, 5-methyl-5'-O-(triphenylmethyl)- Catalog No.:AG0005LE MDL No.: MF:C29H28N2O6 MW:500.5424	CAS No. 1017969-32-2 4-Quinolinecarboxylic acid, 7-hydroxy- Catalog No.:AG0005L5 MDL No.:MFCD11847889 MF:C10H7NO3 MW:189.1675	CAS No. 1017969-33-3 8-Isoquinolinecarboxylic acid, 2,3-dihydro-3-oxo-, methyl ester Catalog No.:AG0005L4 MDL No.: MF:C11H9NO3 MW:203.1941
CAS No. 101798-10-1 Benzamide, N,N'-(2-hydroxy-1,3-propanediyl)bis- Catalog No.:AG0005LD MDL No.: MF:C17H18N2O3 MW:298.3364	CAS No. 101798-15-6 Benzothiazole, 2-(4'-chloro[1,1'-biphenyl]-4-yl)- Catalog No.:AG0005LC MDL No.: MF:C19H12ClNS MW:321.8233	CAS No. 101798-19-0 1,1':3',1''-Terphenyl, 4-phenoxy- (9CI) Catalog No.:AG0005LB MDL No.: MF:C24H18O MW:322.3991
CAS No. 101798-64-5 Piperidine, 4-[(4-chlorophenyl)thio]-, hydrochloride (1:1) Catalog No.:AG0005LA MDL No.:MFCD03840148 MF:C11H15Cl2NS MW:264.2145	CAS No. 101798-66-7 Piperidine, 4-(phenylthio)-, hydrochloride (1:1) Catalog No.:AG0005L9 MDL No.:MFCD03840144 MF:C11H16ClNS MW:229.7694	CAS No. 101798-75-8 Piperidine, 4-[(4-fluorophenyl)thio]- Catalog No.:AG0005L8 MDL No.:MFCD16076688 MF:C11H14FNS MW:211.2990
CAS No. 101798-76-9 Piperidine, 4-[(4-fluorophenyl)thio]-, hydrochloride (1:1) Catalog No.:AG0005L7 MDL No.:MFCD04117760 MF:C11H15ClFNS MW:247.7599	CAS No. 101799-77-3 3H-Pyrazol-3-one, 1,2-dihydro-4-phenyl-2-(2-pyridinyl)- Catalog No.:AG0005L6 MDL No.: MF:C14H11N3O MW:237.2566	CAS No. 1018-18-4 Benzoic acid, triethylgermyl ester Catalog No.:AG0005LS MDL No.: MF:C13H20GeO2 MW:280.9367
CAS No. 1018-24-2 Phosphonic acid, P-(2-phenylethenyl)-, diethyl ester Catalog No.:AG0005LR MDL No.: MF:C12H17O3P MW:240.2353	CAS No. 1018-34-4 Pyrrolidinium, 1,1-dimethyl-2-[[2-(trimethylammonio)ethoxy]carbonyl]-, iodide (1:2) Catalog No.:AG0005LQ MDL No.: MF:C12H26I2N2O2 MW:484.1560	CAS No. 1018-36-6 1H-Pyrazol-3-amine, 2,5-dihydro-1-[(4-methylphenyl)sulfonyl]- Catalog No.:AG0005LP MDL No.: MF:C10H13N3O2S MW:239.2941
CAS No. 1018-47-9 1H,3H-Naphtho[1,8-cd]pyran-1-one, 6-(chloromethyl)- Catalog No.:AG0005LO MDL No.:MFCD00683109 MF:C13H9ClO2 MW:232.6624	CAS No. 1018-54-8 1H-Purine-2,6-dione, 3,7-dihydro-7-methoxy-1,3,8-trimethyl- Catalog No.:AG0005LN MDL No.: MF:C9H12N4O3 MW:224.2166	CAS No. 1018-74-2 3-Pyrazolidinone, 5-methoxy-4,4-dimethyl-1-phenyl- Catalog No.:AG0005LM MDL No.: MF:C12H16N2O2 MW:220.2676
CAS No. 1018-78-6 2,3-Naphthalenedicarbonitrile, 1,4-dihydro-1,4-dioxo- Catalog No.:AG0005LL MDL No.: MF:C12H4N2O2 MW:208.1724	CAS No. 1018-79-7 2,3-Naphthalenedicarbonitrile, 1,4-dihydroxy- Catalog No.:AG0005LK MDL No.:MFCD00192049 MF:C12H6N2O2 MW:210.1882	CAS No. 1018-90-2 5H-Thiazolo[3,2-a]quinazolin-5-one, 2-(bromomethyl)-1,2-dihydro- Catalog No.:AG0005LJ MDL No.: MF:C11H9BrN2OS MW:297.1710
CAS No. 101803-06-9 Pyrimidine, 5-iodo-2-methoxy- Catalog No.:AG0005M6 MDL No.:MFCD18412677 MF:C5H5IN2O MW:236.0105	CAS No. 101803-22-9 Phosphorous acid, bis(2,2,2-trifluoroethyl) trimethylsilyl ester Catalog No.:AG0005M5 MDL No.: MF:C7H13F6O3PSi MW:318.2260	CAS No. 101803-63-8 2-Undecanol, 11-fluoro- Catalog No.:AG0005M4 MDL No.: MF:C11H23FO MW:190.2981
CAS No. 101803-94-5 Pentanedioic acid, 2,2,3-trimethyl-, 1,5-dimethyl ester Catalog No.:AG0005M3 MDL No.: MF:C10H18O4 MW:202.2475	CAS No. 101804-01-7 Phosphonic acid, P-(1-amino-1,2-dimethylpropyl)- Catalog No.:AG0005M2 MDL No.: MF:C5H14NO3P MW:167.1433	CAS No. 1018053-71-8 3-Isoxazolecarboxylic acid, 5-(1-methylethyl)-, methyl ester Catalog No.:AG0005LY MDL No.:MFCD09701707 MF:C8H11NO3 MW:169.1778
CAS No. 10181-98-3 Benzene, 5-(2,6-dimethylphenoxy)-2-methoxy-1,3-dimethyl- Catalog No.:AG0005M8 MDL No.: MF:C17H20O2 MW:256.3395	CAS No. 101810-64-4 1,2-Dioxolane, 3-(4-methoxyphenyl)-4-methylene-3-phenyl- Catalog No.:AG0005M1 MDL No.: MF:C17H16O3 MW:268.3071	CAS No. 101810-73-5 Pyrido[2,3-d]pyrimidine-6-carbonitrile, 2,4-diamino-5-methyl- Catalog No.:AG0005M0 MDL No.: MF:C9H8N6 MW:200.2000
CAS No. 101810-74-6 Pyrido[2,3-d]pyrimidine-6-carboxaldehyde, 2,4-diamino-5-methyl- Catalog No.:AG0005LZ MDL No.: MF:C9H9N5O MW:203.2007	CAS No. 1018125-39-7 6-Aminopyrazolo[1,5-a]pyrimidine Catalog No.:AG0005LX MDL No.:MFCD09701813 MF:C6H6N4 MW:134.1386	CAS No. 1018127-99-5 3-Quinolinecarboxylic acid, 4-amino-8-methoxy- Catalog No.:AG0005LW MDL No.:MFCD11058008 MF:C11H10N2O3 MW:218.2087
CAS No. 1018128-18-1 Isoxazole, 3-(chloromethyl)-5-(1-methylethyl)- Catalog No.:AG0005LV MDL No.:MFCD09859196 MF:C7H10ClNO MW:159.6134	CAS No. 1018135-49-3 3-Quinolinecarboxylic acid, 6-amino-4-hydroxy- Catalog No.:AG0005LU MDL No.:MFCD11058007 MF:C10H8N2O3 MW:204.1821	CAS No. 1018166-61-4 1H-Pyrazolo[3,4-b]pyridine-4-carboxylic acid, 6,7-dihydro-3-methyl-6-oxo-, ethyl ester Catalog No.:AG0005LT MDL No.: MF:C10H11N3O3 MW:221.2126