Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H

 

Heng Zhang
Aiwen Lei
College of Chemistry and Molecular Sciences, Wuhan University, 
Wuhan, Hubei 430072, P. R. of China
State Key Laboratory and Institute of Elemento-Organic Chemistry, 
Nankai University, Tianjin 300071, P. R. of China
aiwenlei@whu.edu.cn
Dedicated to Professor Xiyan Lu on the occasion of his 90th birthday
Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue

 

1 Introduction
Nitrogen-containing molecules form the cornerstone of many disciplines including medicine, material science, and agrochemicals. As a result, relevant research on C–N bondforming reactions remains at the cutting edge of organic synthesis. It is clear that transition-metal-catalyzed C–N bond-forming reactions have played an important rolem during the past several decades. The palladium-catalyzed
Buchwald–Hartwig amination reactions, the copper catalyzed Chan–Evans–Lam coupling, and Ullmann type reactions have been extensively employed in the construction of various nitrogen-containing pharmaceutical industry, organic optoelectronic materials, and so forth.1 Despite the great accomplishments that have been achieved in this realm, more efforts are still needed to make it sustainable and environmentally benign.

 

Prefunctionalized building blocks are normally the prerequisites of many C–N bond-forming protocols. However, this is a double-edged sword because the improvement of reactivity and selectivity is accompanied by a loss of atom economy. From the view point of retrosynthetic analysis, it is conspicuous that this obstacle can be overcome by the direct utilization of easily available ‘C–H’ and ‘N–H’ in the starting materials. Compared with the classical C–N coupling between electrophiles and nucleophiles, this idea is oxidative cross-coupling based on two nucleophiles: ‘C–H’ and ‘N–H’, which have been utilized extensively in bond formations.2 Formally, two hydrogen atoms must be removed to drive the reaction to proceed and therefore sacrificial oxidant is usually required in this chemistry. Although this strategy has been successfully applied in transitionmetal-catalyzed C–N bond-forming reactions, there remain some limitations; namely, the harsh reaction conditions required to compensate for the low reactivity of nonprefunctionalized substrates, and the low atom economy caused by the introduction of stoichiometric amount of oxidants.3

 

The involvement of visible light or electricity in chemical reactions is not a novel idea; indeed, the history of many reactions driven by visible light or electricity dates back to the early times of modern chemistry. In theory, the integration of optical or electrical energy with a chemical transformation can circumvent the restrictions of the second law of thermodynamics to make many unimaginably fantastic reactions feasible.

 

In addition, the renaissance of radical chemistry has drawn the attention of increasing numbers of chemists to the areas of electrosynthesis and photosynthesis.4 Photons and electrons can be deemed as traceless reagents, which can not only reduce the concomitant by-product but also simplify the work up process. Moreover, the consumption of electricity or visible light can be negligible compared
with the price of chemicals. Mild reaction conditions are characteristic features of these processes. The introduction of visible light or electricity can supply a promising avenue to the development of oxidative amination based on C–H/N–H.

 

For the visible-light-mediated aminations, many reported studies are based on photoredox catalysis. Ru/Ir-based polypyridyl complexes and organic dyes are frequently used photoredox catalysts, which supply many choices to match the needs of different substrates. Besides numerous chemical oxidants, air or oxygen can be employed as direct oxidant or terminal oxidant. This chemistry can be ameliorated with the help of dihydrogen producing catalyst, such as graphene-supported RuO2 nanocomposite5 or cobaloxime.6

 

With this modification, sacrificial external oxidant can be omitted and dihydrogen is the sole side product. In some other cases, no photosensitizer is needed as the oxidant (DDQ, K2S2O8, etc.) can be excited directly by visible light or the weak bond (C-I) can be broken just in the presence of visible light.

 

In principle, electrochemical oxidative cross coupling between C–H/N–H normally works in the anodic oxidation mode. Generally speaking, no external oxidant is needed and the surplus hydrogens are evolved in the form of dihydrogen. With the choice of appropriate anode, cathode and other reaction conditions, some transformations can be attained just through direct electrolysis. More flexible options can be provided if electrocatalytic amination is employed. Redox mediator (Br–, I–, etc.), transition-metal complexes are commonly used catalysts. Divided or undivided cells are another variable in the setup, with the more complex former being able to separate the reactive intermediates and avoid the reduction of transition-metal catalyst physically. Compared with the easily available constant-current electrolysis, constant potential electrolysis can control the activation of substrates and supply another way to inhibit the reduction of transition-metal catalyst.

 

Electrochemical or photochemical amination reactions established on the C–H and N–H nucleophiles are unquestionable hot topics nowadays. A case in point is the considerable research work summarized herein which has been published in the past one or two years, and many analogous works are reported nearly at the same time back to back.

Many insightful reviews have been published on related domains or from different perspectives.7 This short review concentrates on the C(sp2, sp3)–H/N–H oxidative cross-coupling reactions mediated by visible light or electricity (Scheme 1). The achievements of the past six years are reviewed, especially focusing on the latest progress.

2 C(sp2)–H/N–H Oxidative Cross Coupling
2.1 Oxidative Cross Coupling between Aryl C(sp2)–H and N–H

Azoles as N Nucleophiles
Photoinduced electron transfer is an efficient method to yield arene radical cations. In 2015, the Nicewicz group reported a pioneering work on a visible-light-mediated arene C–H amination reaction based on this strategy (Scheme 2).8

 

Acridinium was chosen as the photoredox catalyst, 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was the cocatalyst and dioxygen was the terminal oxidant. For substrates such as mesitylene or xylene, a stoichiometric amount of TEMPO and anaerobic conditions should be used to avoid the benzylic oxidation. Besides azoles, ammonium carbamate could also be used as nitrogen source for the synthesis of aniline. Regioisomers were observed for most of the transformations, which may be due to the complex interplay between electronic and steric effects.

The oxidative cross coupling between electron-rich arenes and azoles were also realized based on photoredox catalysis (Scheme 3).9 9-Mesityl-10-methylacridinium perchlorate (Acr+-MesClO4–) was used as the photoredox catalyst. No external oxidant was required in the presence of cobaloxime catalyst, which was proposed to replenish the photoredox catalyst, oxidize radical adduct intermediate and release dihydrogen. This assembly was superior to the combination of photoredox catalyst plus dioxygen because low yield and concomitant aldehyde formation were observed for the latter.

Pandey et al. reported the visible-light-mediated amination between electron-rich arenes and benzotriazole (Scheme 4).10 In this case, Selectfluor was chosen as oxidant and 2,6-lutidine was used as base after screening. The delicate match between the Ru photoredox catalyst and the arenes was crucial for the success of this transformation.

2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ), a well-known organic oxidant, can also be used as photosensitizer. The Lei group realized the amination of thiophene by using a catalytic amount of DDQ and tert-butyl nitrite (TBN) (Scheme 5).11 TBN could be considered as a bridge to connect DDQ and terminal oxidant O2. The scope of the reaction with respect to nitrogen sources was limited to various azoles.

Heteroaryl C(sp2)–H/N–H dehydrogenative cross coupling was reported with and without external oxidant in sequence. Acr+-MesClO4– was chosen as the photoredox catalyst for both works. Adimurthy and coworkers used K2S2O8 as oxidant (Scheme 6a).12 The cobaloxime catalyst was used by Lei, Zhang and coworkers to make this transformation external-oxidant free (Scheme 6b).13 Both protocols were
limited by the substrate scope of both heteroarenes and nitrogen sources.

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CAS No. 101164-88-9 Adenosine, N-[1-(hydroxymethyl)-2-phenylethyl]-, (S)- (9CI) Catalog No.:AG0003VR MDL No.: MF:C19H23N5O5 MW:401.4164	CAS No. 101165-44-0 6-Dodecene, 6-methyl-, (6Z)- Catalog No.:AG0003VQ MDL No.: MF:C13H26 MW:182.3455	CAS No. 101166-50-1 Benzenesulfonamide, N-(1,1-dimethylethyl)-N-fluoro- Catalog No.:AG0003VP MDL No.: MF:C10H14FNO2S MW:231.2871
CAS No. 101166-65-8 Silane, (1,1-dimethylethyl)(2-iodoethoxy)dimethyl- Catalog No.:AG0003VO MDL No.:MFCD09909940 MF:C8H19IOSi MW:286.2258	CAS No. 101166-73-8 3-Pyridineacetonitrile, 2-methyl- Catalog No.:AG0003VN MDL No.:MFCD09923760 MF:C8H8N2 MW:132.1625	CAS No. 101166-81-8 1-Cyclooctene-1-carbonyl chloride Catalog No.:AG0003VM MDL No.: MF:C9H13ClO MW:172.6519
CAS No. 101167-01-5 Benzenamine, 5-chloro-N-(1-methylethyl)-2-nitro- Catalog No.:AG0003VL MDL No.: MF:C9H11ClN2O2 MW:214.6488	CAS No. 101167-02-6 Acetamide, N-[[4-(aminosulfonyl)phenyl]methyl]-2-chloro- Catalog No.:AG0003VK MDL No.:MFCD03393879 MF:C9H11ClN2O3S MW:262.7132	CAS No. 101167-08-2 Benzene, 1-chloro-4-(propylsulfonyl)- Catalog No.:AG0003VJ MDL No.: MF:C9H11ClO2S MW:218.7004
CAS No. 101167-13-9 2-Naphthalenamine, 1,2,3,4-tetrahydro-7-nitro- Catalog No.:AG0003VI MDL No.:MFCD06739161 MF:C10H12N2O2 MW:192.2145	CAS No. 101168-47-2 2-Propanone, 1-ethoxy-3-(2-pyridinyl)- Catalog No.:AG0003VH MDL No.:MFCD15474997 MF:C10H13NO2 MW:179.2157	CAS No. 101168-88-1 Benzenemethanol, 4,4'-(1,2-ethenediyl)bis- Catalog No.:AG0003VG MDL No.: MF:C16H16O2 MW:240.2970
CAS No. 101169-75-9 2H-1-Benzopyran-2-one, 5,7-bis(acetyloxy)-4-propyl- Catalog No.:AG0003VF MDL No.: MF:C16H16O6 MW:304.2946	CAS No. 10117-03-0 Carbonic acid, ethyl 2-fluoroethyl ester Catalog No.:AG0003VX MDL No.: MF:C5H9FO3 MW:136.1216	CAS No. 10117-10-9 Propanoic acid, 3-fluoro-, ethyl ester Catalog No.:AG0003VW MDL No.: MF:C5H9FO2 MW:120.1222
CAS No. 10117-38-1 Sulfurous acid, potassium salt (1:2) Catalog No.:AG0003VV MDL No.:MFCD00011387 MF:K2O3S MW:158.2598	CAS No. 101170-43-8 1,3-Cyclohexanedione, 5,5-dimethyl-2-(3-methylbutyl)- Catalog No.:AG0003VE MDL No.: MF:C13H22O2 MW:210.3126	CAS No. 1011711-52-6 Ethanone, 1-(4-chloro-1H-pyrrolo[2,3-b]pyridin-3-yl)- Catalog No.:AG0003VD MDL No.:MFCD12828645 MF:C9H7ClN2O MW:194.6177
CAS No. 1011711-57-1 1H-Pyrrolo[2,3-b]pyridine, 4-ethoxy- Catalog No.:AG0003VC MDL No.:MFCD12924343 MF:C9H10N2O MW:162.1885	CAS No. 1011711-58-2 1H-Pyrrolo[2,3-b]pyridine, 4-propoxy- Catalog No.:AG0003VB MDL No.:MFCD20669035 MF:C10H12N2O MW:176.2151	CAS No. 1011711-59-3 Ethanone, 1-(4-methoxy-1H-pyrrolo[2,3-b]pyridin-3-yl)- Catalog No.:AG0003W8 MDL No.: MF:C10H10N2O2 MW:190.1986
CAS No. 1011711-60-6 Ethanone, 1-(6-broMo-1H-pyrrolo[2,3-b]pyridin-3-yl)- Catalog No.:AG0003W7 MDL No.: MF:C9H7BrN2O MW:239.0687	CAS No. 1011716-95-2 1H-Pyrrole-3-carboxylic acid, 2-aMino-5-[4-(Methoxycarbonyl)phenyl]-, ethyl ester Catalog No.:AG0003W6 MDL No.: MF:C15H16N2O4 MW:288.2985	CAS No. 1011716-97-4 Benzoic acid, 4-(4,7-dihydro-4-oxo-3H-pyrrolo[2,3-d]pyriMidin-6-yl)-, Methyl ester Catalog No.:AG0003W5 MDL No.: MF:C14H11N3O3 MW:269.2554
CAS No. 1011717-00-2 Benzoic acid, 4-(4-chloro-7H-pyrrolo[2,3-d]pyriMidin-6-yl)-, Methyl ester Catalog No.:AG0003W4 MDL No.: MF:C14H10ClN3O2 MW:287.7011	CAS No. 1011722-07-8 Boronic acid, B-(6-cyano-3-pyridinyl)- Catalog No.:AG0003W3 MDL No.:MFCD10696633 MF:C6H5BN2O2 MW:147.9271	CAS No. 1011736-00-7 1H-Phosphepin, 1-(1,1-dimethylethyl)-2,3,6,7-tetrahydro-, tetrafluoroborate(1-) (1:1) Catalog No.:AG0003W2 MDL No.: MF: MW:
CAS No. 10118-35-1 Piperidine, 2-(2,2-dicyclohexylethyl)-, (2Z)-2-butenedioate (9CI) Catalog No.:AG0003WN MDL No.: MF:C23H39NO4 MW:393.5601	CAS No. 10118-54-4 1H-Pyrrole-3-carboxylic acid, 5-[[4-(ethoxycarbonyl)-3,5-dimethyl-1H-pyrrol-2-yl][4-(ethoxycarbonyl)-3,5-dimethyl-2H-pyrrol-2-ylidene]methyl]-2,4-dimethyl-, ethyl ester (9CI) Catalog No.:AG0003WM MDL No.: MF:C28H35N3O6 MW:509.5940	CAS No. 1011800-93-3 Thiophene, 3-[(4-bromophenyl)(2,5-dimethylphenyl)methyl]-2,5-dimethyl- Catalog No.:AG0003W1 MDL No.: MF:C21H21BrS MW:385.3604
CAS No. 1011801-59-4 1H-Pyrazole, 1-(2-bromoethyl)-4-chloro- Catalog No.:AG0003W0 MDL No.:MFCD03727250 MF:C5H6BrClN2 MW:209.4715	CAS No. 101181-43-5 Acetamide, 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)-, mixt. with 6-(ethylthio)-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine (9CI) Catalog No.:AG0003WK MDL No.: MF: MW:	CAS No. 101181-87-7 Nonanoic acid, 9-bromo-2-oxo- Catalog No.:AG0003WJ MDL No.: MF:C9H15BrO3 MW:251.1176
CAS No. 101183-79-3 Bicyclo[4.1.0]heptane, 7,7-dibromo-2-methyl- Catalog No.:AG0003WI MDL No.: MF:C8H12Br2 MW:267.9889	CAS No. 101183-80-6 2-Propen-1-one, 1-(1-cyclohexen-1-yl)-3-phenyl-, (2E)- Catalog No.:AG0003WH MDL No.: MF:C15H16O MW:212.2869	CAS No. 101183-81-7 2-Propen-1-one, 1-(1-cyclohexen-1-yl)-3-(4-methylphenyl)-, (2E)- Catalog No.:AG0003WG MDL No.: MF:C16H18O MW:226.3135
CAS No. 101183-99-7 2H-Imidazol-2-one, 4-ethyl-1,3-dihydro-5-[4-(1H-imidazol-1-yl)benzoyl]- Catalog No.:AG0003WF MDL No.: MF:C15H14N4O2 MW:282.2973	CAS No. 101184-08-1 Benzoic acid, 4-(1H-imidazol-1-yl)-, methyl ester Catalog No.:AG0003WE MDL No.:MFCD00127080 MF:C11H10N2O2 MW:202.2093	CAS No. 101184-09-2 1H-Imidazole-4-carboxylic acid, 2,3-dihydro-5-methyl-2-oxo- Catalog No.:AG0003WD MDL No.:MFCD08458296 MF:C5H6N2O3 MW:142.1127
CAS No. 101184-10-5 1H-Imidazole-4-carboxylic acid, 5-ethyl-2,3-dihydro-2-oxo- Catalog No.:AG0003WC MDL No.: MF:C6H8N2O3 MW:156.1393	CAS No. 101184-51-4 3-Pyridinecarboxylic acid, 5-cyano-1,6-dihydro-2-methyl-6-oxo- Catalog No.:AG0003WB MDL No.:MFCD16556120 MF:C8H6N2O3 MW:178.1448	CAS No. 101184-73-0 Benzeneacetonitrile, 4-bromo-α,α-dimethyl- Catalog No.:AG0003WA MDL No.:MFCD02684219 MF:C10H10BrN MW:224.0971
CAS No. 101184-85-4 1,4-Thiazepine, hexahydro- Catalog No.:AG0003W9 MDL No.:MFCD15209531 MF:C5H11NS MW:117.2125	CAS No. 101184-87-6 2-Propenoic acid, 2-methyl-, 3-[(carboxymethyl)(phenylmethyl)amino]-2-hydroxypropyl ester Catalog No.:AG0003XA MDL No.: MF:C16H21NO5 MW:307.3416	CAS No. 101185-20-0 Lithium, [1,3-bis(phenylthio)-2-cyclohexen-1-yl]- Catalog No.:AG0003X9 MDL No.: MF:C18H17LiS2 MW:304.3986
CAS No. 101185-81-3 Morpholine, 2,6-dimethyl-4-octyl-, cis- (9CI) Catalog No.:AG0003X8 MDL No.: MF:C14H29NO MW:227.3862	CAS No. 101186-04-3 Hexanoic acid, 3-hydroxy-5-methyl-2-methylene-, 1-methylethyl ester Catalog No.:AG0003X7 MDL No.: MF:C11H20O3 MW:200.2747	CAS No. 101186-10-1 Butanedioic acid, 2-(2-methylpropylidene)-, 1,4-dimethyl ester, (2E)- Catalog No.:AG0003X6 MDL No.: MF:C10H16O4 MW:200.2316
CAS No. 101186-14-5 Butanedioic acid, (2-methylpropylidene)-, dimethyl ester, (2Z)- (9CI) Catalog No.:AG0003X5 MDL No.: MF:C10H16O4 MW:200.2316	CAS No. 101186-18-9 2-Tridecanol, (2S)- Catalog No.:AG0003X4 MDL No.: MF:C13H28O MW:200.3608	CAS No. 101186-93-0 Benzenamine, 4,4'-(1,2-ethenediyl)bis[N-(4-methoxyphenyl)-N-phenyl- Catalog No.:AG0003X3 MDL No.: MF:C40H34N2O2 MW:574.7102
CAS No. 101187-39-7 Ethane, 1,1'-oxybis[2-(2-azidoethoxy)- Catalog No.:AG0003X2 MDL No.:MFCD03425545 MF:C8H16N6O3 MW:244.2510	CAS No. 101187-40-0 5,8,11-Trioxa-2-azatridecanoic acid, 13-amino-, 1,1-dimethylethyl ester Catalog No.:AG0003X1 MDL No.:MFCD16619220 MF:C13H28N2O5 MW:292.3718	CAS No. 101187-97-7 2-Naphthalenecarboxylic acid, 6,6'-[1,2-ethanediylbis(oxy)]bis- Catalog No.:AG0003X0 MDL No.: MF:C24H18O6 MW:402.3961
CAS No. 10119-99-0 Ethanamine, 2,2-dinitro- Catalog No.:AG0003XB MDL No.: MF:C2H5N3O4 MW:135.0788	CAS No. 101190-70-9 Guanidine, N-cyano-N'-[(4-methoxyphenyl)methyl]- Catalog No.:AG0003WZ MDL No.: MF:C10H12N4O MW:204.2285	CAS No. 101190-78-7 Thiourea, N-[imino(pentylamino)methyl]- Catalog No.:AG0003WY MDL No.: MF:C7H16N4S MW:188.2937
CAS No. 101191-83-7 Monensin, 16-deethyl-3-O-demethyl-16-methyl-3-O-(1-oxopropyl)-, 26-(phenylcarbamate) (9CI) Catalog No.:AG0003WX MDL No.: MF:C44H67NO13 MW:818.0017	CAS No. 101192-17-0 Propanedioic acid, 2-[1-ethoxy-2-(2-quinolinyl)ethyl]-, 1,3-diethyl ester Catalog No.:AG0003WW MDL No.: MF:C20H25NO5 MW:359.4162	CAS No. 101192-30-7 1H-Benzo[c]quinolizine-2-carboxylic acid, 1-oxo-, ethyl ester Catalog No.:AG0003WV MDL No.: MF:C16H13NO3 MW:267.2793
CAS No. 101192-78-3 4H-Quinolizine-3-carboxylic acid, 7-butoxy-4-oxo-1-phenyl-, ethyl ester Catalog No.:AG0003WU MDL No.: MF:C22H23NO4 MW:365.4223	CAS No. 101193-76-4 4-Imidazolidinecarboxylic acid, 1,3-dimethyl-4-(methylamino)-2,5-dioxo- Catalog No.:AG0003WT MDL No.: MF:C7H11N3O4 MW:201.1799	CAS No. 101195-46-4 2-Cyclohexene-1-acetamide, N-(2-chlorophenyl)- Catalog No.:AG0003WS MDL No.: MF:C14H16ClNO MW:249.7359
CAS No. 101195-61-3 Imidazo[1,5-b]isoquinoline-1,3(2H,5H)-dione, 10,10a-dihydro-2-propyl- Catalog No.:AG0003WR MDL No.:MFCD12076962 MF:C14H16N2O2 MW:244.2890	CAS No. 101195-67-9 3-Pentyn-1-amine, 5-(trimethylsilyl)- Catalog No.:AG0003WQ MDL No.: MF:C8H17NSi MW:155.3128	CAS No. 101195-68-0 4-Hexyn-1-amine, 6-(trimethylsilyl)- Catalog No.:AG0003WP MDL No.: MF:C9H19NSi MW:169.3394
CAS No. 101195-69-1 3-Pentyn-1-amine, N-(phenylmethylene)-5-(trimethylsilyl)- Catalog No.:AG0003WO MDL No.: MF:C15H21NSi MW:243.4194	CAS No. 101195-72-6 Acetamide, N-(ethoxyphenylmethyl)-N-[5-(trimethylsilyl)-3-pentyn-1-yl]- Catalog No.:AG0003XJ MDL No.: MF:C19H29NO2Si MW:331.5246	CAS No. 101196-25-2 Methanamine, N-ethoxy-N-methyl- Catalog No.:AG0003XI MDL No.: MF:C4H11NO MW:89.1362
CAS No. 101196-26-3 1-Propanamine, N-methoxy- Catalog No.:AG0003XH MDL No.: MF:C4H11NO MW:89.1362	CAS No. 101198-10-1 Ethanamine, N-(2-bromoethyl)-2-fluoro-, hydrochloride (1:1) Catalog No.:AG0003XG MDL No.: MF:C4H10BrClFN MW:206.4843	CAS No. 101198-16-7 1,3-Dioxane, 6-methyl-2,2,4,4-tetrakis(trifluoromethyl)- Catalog No.:AG0003XF MDL No.: MF:C9H6F12O2 MW:374.1236
CAS No. 101199-38-6 10H-Phenothiazine-10-propanesulfonic acid, sodium salt (1:1) Catalog No.:AG0003XE MDL No.:MFCD08275674 MF:C15H14NNaO3S2 MW:343.3963	CAS No. 101199-74-0 Benzoic acid, 2-(2-diazoacetyl)-, 3-buten-1-yl ester Catalog No.:AG0003XD MDL No.: MF:C13H12N2O3 MW:244.2460	CAS No. 1012-01-7 3-Pyrrolidinone, 1-(phenylmethyl)-, hydrochloride (1:1) Catalog No.:AG0003Y0 MDL No.:MFCD00757024 MF:C11H14ClNO MW:211.6880
CAS No. 1012-05-1 Benzenebutanoic acid, α-amino- Catalog No.:AG0003XZ MDL No.:MFCD00063092 MF:C10H13NO2 MW:179.2157	CAS No. 1012-12-0 Benzaldehyde, 4-[(trimethylsilyl)oxy]- Catalog No.:AG0003XY MDL No.:MFCD00040723 MF:C10H14O2Si MW:194.3025	CAS No. 1012-18-6 Benzene, 1-(2-methyl-1-propen-1-yl)-4-nitro- Catalog No.:AG0003XX MDL No.: MF:C10H11NO2 MW:177.1998
CAS No. 1012-25-5 1H-Pyrrole, 2,5-dibutyl- Catalog No.:AG0003XW MDL No.: MF:C12H21N MW:179.3018	CAS No. 1012-29-9 Pyrrolidine, 1,1'-(1,3-propanediyl)bis- Catalog No.:AG0003XV MDL No.: MF:C11H22N2 MW:182.3058	CAS No. 1012-36-8 1,3,8-Triazaspiro[4.5]decan-4-one, 1-(1-methylethyl)- Catalog No.:AG0003XU MDL No.: MF:C10H19N3O MW:197.2774
CAS No. 1012-59-5 4(1H)-Quinazolinone, 2-ethyl-2,3-dihydro-2-methyl- Catalog No.:AG0003XT MDL No.:MFCD00171144 MF:C11H14N2O MW:190.2417	CAS No. 1012-62-0 Phosphorodithioic acid, O,O-dimethyl S-[(2-methyl-1,3-dithiolan-2-yl)methyl] ester Catalog No.:AG0003XS MDL No.: MF:C7H15O2PS4 MW:290.4266	CAS No. 1012-69-7 2-Propenenitrile, 3-[(3-methylphenyl)sulfonyl]- Catalog No.:AG0003XR MDL No.: MF:C10H9NO2S MW:207.2490
CAS No. 1012-72-2 Benzene, 1,4-bis(1,1-dimethylethyl)- Catalog No.:AG0003XQ MDL No.:MFCD00008836 MF:C14H22 MW:190.3245	CAS No. 1012-73-3 Stannane, 1,1'-(1,4-phenylene)bis[1,1,1-trimethyl- Catalog No.:AG0003XP MDL No.: MF:C12H22Sn2 MW:403.7051	CAS No. 1012-81-3 2,5-Pyrrolidinedione, 1-(2-aminophenyl)- Catalog No.:AG0003XO MDL No.:MFCD00022591 MF:C10H10N2O2 MW:190.1986
CAS No. 1012-82-4 1H-Purine-2,6-dione, 3,7-dihydro-7-hydroxy-1,3-dimethyl- Catalog No.:AG0003XN MDL No.: MF:C7H8N4O3 MW:196.1634	CAS No. 1012-84-6 Benzoic acid, 2,3,4,5,6-pentachloro- Catalog No.:AG0003XM MDL No.:MFCD00092425 MF:C7HCl5O2 MW:294.3466	CAS No. 1012-87-9 2,4-Oxazolidinedione, 5-methyl-3-phenyl- Catalog No.:AG0003XL MDL No.: MF:C10H9NO3 MW:191.1834
CAS No. 1012-91-5 Piperazine, 1-(2,6-dimethylphenyl)- Catalog No.:AG0003XK MDL No.:MFCD00038009 MF:C12H18N2 MW:190.2847	CAS No. 1012-97-1 2H-1,2,3-Benzothiadiazine, 4-hydrazinyl-, 1,1-dioxide Catalog No.:AG0003YP MDL No.: MF:C7H8N4O2S MW:212.2290	CAS No. 10120-28-2 Cyclohexane-1,1,2,2,3,3,4,4,5,5,6-d11, 6-(methyl-d3)- Catalog No.:AG0003YO MDL No.:MFCD00001498 MF:C7D14 MW:112.2723
CAS No. 10120-31-7 10H-Phenothiazin-3-ol, 10-[3-(methylamino)propyl]- Catalog No.:AG0003YN MDL No.: MF:C16H18N2OS MW:286.3919	CAS No. 101200-05-9 Calcium, bis(1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)- Catalog No.:AG0003YM MDL No.: MF:C20H30Ca MW:310.5302	CAS No. 101203-18-3 Phosphonium, tetrabutyl-, benzoate (1:1) Catalog No.:AG0003YK MDL No.: MF:C23H41O2P MW:380.5442
CAS No. 101203-31-0 [1,1'-Biphenyl]-2,2'-diol, 3,3'-bis(1,1-dimethylethyl)-5,5',6,6'-tetramethyl- Catalog No.:AG0003YJ MDL No.: MF:C24H34O2 MW:354.5256	CAS No. 101204-35-7 Benzoic acid, 4-[2-[3,4-bis(1-methylethyl)phenyl]diazenyl]- Catalog No.:AG0003YI MDL No.: MF:C19H22N2O2 MW:310.3902	CAS No. 101204-88-0 Pyrido[2,3-d]pyrimidin-4(3H)-one, 2-methyl-3-(1-piperidinylmethyl)- Catalog No.:AG0003YH MDL No.: MF:C14H18N4O MW:258.3189
CAS No. 101204-98-2 Phosphinous acid, P,P'-anhydride Catalog No.:AG0003YG MDL No.: MF:H4OP2 MW:81.9787	CAS No. 1012042-02-2 Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-(2-phenylethyl)-2-oxazolyl]- Catalog No.:AG0003YB MDL No.: MF:C27H27N3O2 MW:425.5222	CAS No. 101205-03-2 3-Furanmethanol, 5-(1,3-benzodioxol-5-yl)-α-(3,4-dimethoxyphenyl)tetrahydro-4-methyl-, (αR,3R,4S,5S)- Catalog No.:AG0003YE MDL No.: MF:C21H24O6 MW:372.4117
CAS No. 101205-17-8 1H-Indole-1-propanenitrile, 5-methyl-3-phenyl- Catalog No.:AG0003YD MDL No.: MF:C18H16N2 MW:260.3330	CAS No. 101205-76-9 Benzonitrile, 4-[(1E)-2-(4-methylphenyl)ethenyl]- Catalog No.:AG0003YC MDL No.: MF:C16H13N MW:219.2811	CAS No. 1012051-90-9 Thiourea, N,N''-[(1R,2R)-1,2-diphenyl-1,2-ethanediyl]bis[N'-[3,5-bis(trifluoromethyl)phenyl]- Catalog No.:AG0003YA MDL No.: MF:C32H22F12N4S2 MW:754.6547
CAS No. 1012054-59-9 Heptanamide, 7-[[4-[(3-ethynylphenyl)amino]-7-methoxy-6-quinazolinyl]oxy]-N-hydroxy- Catalog No.:AG0003Y9 MDL No.:MFCD15528940 MF:C24H26N4O4 MW:434.4876	CAS No. 1012057-22-5 Benzoic acid, 3-[(7-ethoxy-7-oxoheptyl)oxy]-4-methoxy-, ethyl ester Catalog No.:AG0003Y8 MDL No.:MFCD16877546 MF:C19H28O6 MW:352.4220	CAS No. 1012057-25-8 Heptanoic acid, 7-[(3,4-dihydro-7-methoxy-4-oxo-6-quinazolinyl)oxy]-, ethyl ester Catalog No.:AG0003Y7 MDL No.:MFCD16877550 MF:C18H24N2O5 MW:348.3936
CAS No. 1012057-26-9 Heptanoic acid, 7-[(4-chloro-7-methoxy-6-quinazolinyl)oxy]-, ethyl ester Catalog No.:AG0003Y6 MDL No.:MFCD23135642 MF:C18H23ClN2O4 MW:366.8392	CAS No. 1012057-47-4 4(3H)-Quinazolinone, 7-methoxy-6-nitro- Catalog No.:AG0003Y5 MDL No.: MF:C9H7N3O4 MW:221.1696	CAS No. 1012057-52-1 4,6-Quinazolinediamine, N4-(3-ethynylphenyl)-7-methoxy- Catalog No.:AG0003Y4 MDL No.:MFCD16877567 MF:C17H14N4O MW:290.3193
CAS No. 1012058-77-3 2-Pyridinecarboxylic acid, 4-(4-aMinophenoxy)- Catalog No.:AG0003Y3 MDL No.:MFCD23378603 MF:C12H10N2O3 MW:230.2194	CAS No. 1012059-49-2 2H-IMidazo[4,5-c]pyridine-2-thione, 4-chloro-1,3-dihydro-1-[(4-Methoxyphenyl)Methyl]- Catalog No.:AG0003Y2 MDL No.: MF:C14H12ClN3OS MW:305.7826	CAS No. 1012059-50-5 2H-IMidazo[4,5-c]pyridine-2-thione, 4-aMino-1,3-dihydro-1-[(4-Methoxyphenyl)Methyl]- Catalog No.:AG0003Y1 MDL No.: MF:C14H14N4OS MW:286.3522
CAS No. 1012059-95-8 Carbamic acid, N-[(1R)-1-(hydroxymethyl)-3-(methylamino)-3-oxopropyl]-, phenylmethyl ester Catalog No.:AG0003Z2 MDL No.: MF:C13H18N2O4 MW:266.2930	CAS No. 1012059-96-9 CarbaMic acid, N-[(1R)-3-(MethylaMino)-3-oxo-1-[(phenylthio)Methyl]propyl]-, phenylMethyl ester Catalog No.:AG0003Z1 MDL No.: MF:C19H22N2O3S MW:358.4546	CAS No. 1012059-97-0 ButanaMide, 3-aMino-N-Methyl-4-(phenylthio)-, (3R)- Catalog No.:AG0003Z0 MDL No.: MF:C11H16N2OS MW:224.3225
CAS No. 1012060-12-6 Benzoic acid, 3-nitro-4-(1-piperazinyl)-, 1,1-diMethylethyl ester Catalog No.:AG0003YZ MDL No.: MF:C15H21N3O4 MW:307.3449	CAS No. 1012060-13-7 Benzoic acid, 4-[4-[(2-broMophenyl)Methyl]-1-piperazinyl]-3-nitro-, 1,1-diMethylethyl ester Catalog No.:AG0003YY MDL No.: MF:C22H26BrN3O4 MW:476.3635	CAS No. 1012067-91-2 4-Pyridinemethanamine, α-methyl-, hydrochloride (1:1), (αR)- Catalog No.:AG0003YX MDL No.:MFCD16622130 MF:C7H12Cl2N2 MW:195.0896
CAS No. 1012067-92-3 Benzoic acid, 5-[(7-ethoxy-7-oxoheptyl)oxy]-4-methoxy-2-nitro-, ethyl ester Catalog No.:AG0003YW MDL No.:MFCD16877547 MF:C19H27NO8 MW:397.4196	CAS No. 1012067-93-4 Benzoic acid, 2-amino-5-[(7-ethoxy-7-oxoheptyl)oxy]-4-methoxy-, ethyl ester Catalog No.:AG0003YV MDL No.:MFCD16877548 MF:C19H29NO6 MW:367.4367	CAS No. 101208-17-7 2H-Cyclopenta[b]furan-2-one, 5-(benzoyloxy)hexahydro-4-[(triphenylmethoxy)methyl]-, (3aR,4S,5R,6aS)- Catalog No.:AG0003ZB MDL No.: MF:C34H30O5 MW:518.5990
CAS No. 1012084-53-5 3-Pyridinol, 5-bromo-2-fluoro- Catalog No.:AG0003YU MDL No.:MFCD11040265 MF:C5H3BrFNO MW:191.9858	CAS No. 1012084-55-7 Boronic acid, B-(5-methyl-4-isoxazolyl)- Catalog No.:AG0003YT MDL No.: MF:C4H6BNO3 MW:126.9063	CAS No. 1012084-56-8 Pyridine, 2-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- Catalog No.:AG0003YS MDL No.:MFCD08669594 MF:C12H18BNO2 MW:219.0878
CAS No. 1012085-48-1 Boronic acid, B,B'-3,5-pyridinediylbis- Catalog No.:AG0003YR MDL No.:MFCD06253455 MF:C5H7B2NO4 MW:166.7354	CAS No. 1012085-50-5 Pyridine, 3,5-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- Catalog No.:AG0003YQ MDL No.:MFCD12923191 MF:C17H27B2NO4 MW:331.0226	CAS No. 101209-08-9 Acetamide, N-(4-acetyl-2-bromophenyl)- Catalog No.:AG0003ZA MDL No.:MFCD00051781 MF:C10H10BrNO2 MW:256.0959
CAS No. 101209-83-0 1-Propanol, 2-(2-methoxyethoxy)- Catalog No.:AG0003Z9 MDL No.: MF:C6H14O3 MW:134.1736	CAS No. 10121-26-3 1-Butanone, 1-(2,6-dihydroxyphenyl)- Catalog No.:AG0003ZE MDL No.:MFCD00564165 MF:C10H12O3 MW:180.2005	CAS No. 10121-78-5 Anthracene, 9-[[(2-chloroethyl)thio]methyl]-10-methyl- Catalog No.:AG0003ZD MDL No.: MF:C18H17ClS MW:300.8456
CAS No. 10121-91-2 1-Naphthalenesulfonamide, N-(5-aminopentyl)-5-(dimethylamino)- Catalog No.:AG0003ZC MDL No.:MFCD00042704 MF:C17H25N3O2S MW:335.4643	CAS No. 101210-56-4 1,4,7,10,13,16,19-Heptaoxa-22-azacyclotetracosane Catalog No.:AG0003Z8 MDL No.: MF:C16H33NO7 MW:351.4357	CAS No. 101211-94-3 1H-Pyrrolesulfonic acid (9CI) Catalog No.:AG0003Z7 MDL No.: MF:C4H5NO3S MW:147.1524
CAS No. 101211-96-5 Carbamic acid, N-(3-isocyanatomethylphenyl)-, octyl ester Catalog No.:AG0003Z6 MDL No.: MF:C17H24N2O3 MW:304.3841	CAS No. 101212-36-6 1-Propanol, 2-methyl-3-(phenylthio)-, (2R)- Catalog No.:AG0003Z5 MDL No.: MF:C10H14OS MW:182.2826	CAS No. 101212-39-9 1(3H)-Isobenzofuranone, 5-methoxy-3,6-dimethyl-3-(2-propen-1-yl)- Catalog No.:AG0003Z4 MDL No.: MF:C14H16O3 MW:232.2750
CAS No. 101212-50-4 Guanosine 5'-(tetrahydrogen triphosphate), 8-amino- (9CI) Catalog No.:AG0003Z3 MDL No.: MF:C10H17N6O14P3 MW:538.1951	CAS No. 101212-86-6 Benzene, 2-butoxy-4-methyl-1-nitro- Catalog No.:AG000401 MDL No.: MF:C11H15NO3 MW:209.2417	CAS No. 101213-09-6 Acetamide, 2-(2,4-dipentylphenoxy)-N,N-diethyl- Catalog No.:AG000400 MDL No.: MF:C22H37NO2 MW:347.5347
CAS No. 101213-71-2 Trisilane, 1,1,1,2,3,3,3-heptaphenyl- Catalog No.:AG0003ZZ MDL No.: MF:C42H36Si3 MW:624.9917	CAS No. 101214-43-1 L-Phenylalanine, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, 2,5-dioxo-1-pyrrolidinyl ester Catalog No.:AG0003ZY MDL No.:MFCD00062204 MF:C28H24N2O6 MW:484.5000	CAS No. 101216-59-5 12,14-PENTACOSADIYNOIC ACID Catalog No.:AG0003ZX MDL No.: MF:C25H42O2 MW:374.5998
CAS No. 101216-61-9 7,9-Tetracosadiynoic acid Catalog No.:AG0003ZW MDL No.: MF:C24H40O2 MW:360.5732	CAS No. 101217-93-0 4H-Quinolizine-3-carboxylic acid, 4-oxo- Catalog No.:AG0003ZV MDL No.: MF:C10H7NO3 MW:189.1675	CAS No. 101219-10-7 1,2,3-Triazine, 2,5-dihydro-5-methyl- Catalog No.:AG0003ZU MDL No.: MF:C4H7N3 MW:97.1185
CAS No. 101219-68-5 Benzenemethanol, 4-fluoro-α-methyl-, (αR)- Catalog No.:AG0003ZT MDL No.:MFCD03092997 MF:C8H9FO MW:140.1549	CAS No. 101219-69-6 Benzonitrile, 4-[(1R)-1-hydroxyethyl]- Catalog No.:AG0003ZS MDL No.:MFCD09952583 MF:C9H9NO MW:147.1739	CAS No. 101219-71-0 Benzonitrile, 4-[(1S)-1-hydroxyethyl]- Catalog No.:AG0003ZR MDL No.:MFCD08702986 MF:C9H9NO MW:147.1739
CAS No. 101219-73-2 Benzenemethanol, 4-fluoro-α-methyl-, (αS)- Catalog No.:AG0003ZQ MDL No.:MFCD03092998 MF:C8H9FO MW:140.1549	CAS No. 101219-76-5 Benzene, 1-[2-(methylthio)ethoxy]-2,4-dinitro- Catalog No.:AG0003ZP MDL No.: MF:C9H10N2O5S MW:258.2511	CAS No. 10122-95-9 Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaen-5-amine Catalog No.:AG000403 MDL No.: MF:C16H17N MW:223.3129
CAS No. 10122-98-2 Phosphinic acid, diphenyl-, 2-methylpropyl ester (9CI) Catalog No.:AG000402 MDL No.: MF:C16H19O2P MW:274.2946	CAS No. 101220-45-5 Spiro[cyclopropane-1,9'-[9H]thioxanthene], 2-phenyl-, 10',10'-dioxide Catalog No.:AG0003ZO MDL No.: MF:C21H16O2S MW:332.4155	CAS No. 101221-23-2 2-Oxabicyclo[2.2.2]octan-5-one, 1,3,3-trimethyl- Catalog No.:AG0003ZN MDL No.: MF:C10H16O2 MW:168.2328
CAS No. 101221-45-8 Ethanol, 2-[(2,3-dihydro-1,4-benzodioxin-2-yl)ethylamino]- Catalog No.:AG0003ZM MDL No.: MF:C12H17NO3 MW:223.2683	CAS No. 101221-46-9 Ethanol, 2-[[2-(2,3-dihydro-1,4-benzodioxin-2-yl)ethyl]methylamino]- Catalog No.:AG0003ZL MDL No.: MF:C13H19NO3 MW:237.2949	CAS No. 101221-47-0 Ethanol, 2-[[3-(2,3-dihydro-1,4-benzodioxin-2-yl)propyl]methylamino]- Catalog No.:AG0003ZK MDL No.: MF:C14H21NO3 MW:251.3214
CAS No. 101221-50-5 Ethanol, 2-[[(6,7-dichloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl]methylamino]- Catalog No.:AG0003ZJ MDL No.: MF:C12H15Cl2NO3 MW:292.1584	CAS No. 101221-55-0 [1,1'-Biphenyl]-4-carboxylic acid, 2-[[1-methyl-2-[3-(trifluoromethyl)phenyl]ethyl]amino]ethyl ester Catalog No.:AG0003ZI MDL No.: MF:C25H24F3NO2 MW:427.4588	CAS No. 101221-66-3 1-Butanone, 4,4,4-trifluoro-3-hydroxy-1-phenyl-3-(trifluoromethyl)-, 2-[4,4,4-trifluoro-3-hydroxy-1-phenyl-3-(trifluoromethyl)butylidene]hydrazone Catalog No.:AG0003ZH MDL No.: MF:C22H16F12N2O2 MW:568.3555
CAS No. 101223-02-3 2-Hexenal, 4-(acetyloxy)-5-hydroxy-, (2E,4R,5S)- Catalog No.:AG0003ZG MDL No.: MF:C8H12O4 MW:172.1785	CAS No. 101224-30-0 Phenol, 4-[(trimethylsilyl)methyl]- Catalog No.:AG0003ZF MDL No.: MF:C10H16OSi MW:180.3189	CAS No. 101224-43-5 5-Hexynoic acid, 6-(trimethylsilyl)- Catalog No.:AG00040R MDL No.: MF:C9H16O2Si MW:184.3076
CAS No. 101225-95-0 1H-Isoindole-1,3(2H)-dione, 2-(3-bromo-1-methylpropyl)- Catalog No.:AG00040Q MDL No.:MFCD27940842 MF:C12H12BrNO2 MW:282.1332	CAS No. 101226-40-8 1H-Imidazole-2-carbonitrile, 1-[[2-(trimethylsilyl)ethoxy]methyl]- Catalog No.:AG00040P MDL No.: MF:C10H17N3OSi MW:223.3470	CAS No. 101226-42-0 1H-Imidazole-2-carboxaldehyde, 1-[[2-(trimethylsilyl)ethoxy]methyl]- Catalog No.:AG00040O MDL No.: MF:C10H18N2O2Si MW:226.3476
CAS No. 101226-86-2 2-Heptenoic acid, 7-hydroxy-2-methyl-, methyl ester, (E)- (9CI) Catalog No.:AG00040N MDL No.: MF:C9H16O3 MW:172.2215	CAS No. 101228-53-9 9-Anthracenamine, N-1-naphthalenyl- Catalog No.:AG00040M MDL No.: MF:C24H17N MW:319.3985	CAS No. 10123-62-3 Phosphonic acid, P-(2-cyanoethyl)-, diethyl ester Catalog No.:AG00040S MDL No.:MFCD00013825 MF:C7H14NO3P MW:191.1647
CAS No. 1012305-33-7 Benzenemethanamine, 3-chloro-4-fluoro-α-methyl-, (αR)- Catalog No.:AG00040B MDL No.:MFCD06761889 MF:C8H9ClFN MW:173.6152	CAS No. 1012317-71-3 L-Lysinamide, N2-(1-oxohexyl)-L-lysylglycyl-L-histidyl-, acetate (1:?) Catalog No.:AG00040A MDL No.: MF:C28H51N9O7 MW:625.7606	CAS No. 101232-44-4 Benzene, methyl-1,3-bis(phenylmethyl)- (9CI) Catalog No.:AG00040L MDL No.: MF:C21H20 MW:272.3835
CAS No. 101234-76-8 1H-Cyclopenta[b]pyridine-1-acetic acid, 4,5,6,7-tetrahydro-4-thioxo- Catalog No.:AG00040K MDL No.: MF:C10H11NO2S MW:209.2648	CAS No. 101234-85-9 5H-Cyclopenta[b]pyridine, 4-chloro-6,7-dihydro-, 1-oxide Catalog No.:AG00040J MDL No.: MF:C8H8ClNO MW:169.6082	CAS No. 101234-96-2 4(1H)-Pyridinone, 1-(2,2,2-trifluoroethyl)- Catalog No.:AG00040I MDL No.: MF:C7H6F3NO MW:177.1238
CAS No. 1012341-50-2 [1,1'-Biphenyl]-4-pentanoic acid, γ-[[(1,1-dimethylethoxy)carbonyl]amino]-α-methyl-, (αR,γS)- Catalog No.:AG000409 MDL No.: MF:C23H29NO4 MW:383.4807	CAS No. 1012341-52-4 [1,1'-Biphenyl]-4-pentanoic acid, γ-[[(1,1-dimethylethoxy)carbonyl]amino]-α-methyl-, (αS,γS)- Catalog No.:AG000408 MDL No.: MF:C23H29NO4 MW:383.4807	CAS No. 1012341-54-6 [1,1'-Biphenyl]-4-pentanoic acid, γ-[[(1,1-dimethylethoxy)carbonyl]amino]-α-methyl-, (αS,γR)- Catalog No.:AG000407 MDL No.: MF:C23H29NO4 MW:383.4807
CAS No. 1012341-56-8 [1,1'-Biphenyl]-4-pentanoic acid, γ-[[(1,1-dimethylethoxy)carbonyl]amino]-α-methyl-, (αR,γR)- Catalog No.:AG000406 MDL No.: MF:C23H29NO4 MW:383.4807	CAS No. 1012342-23-2 Benzoic acid, 3-(1-cyanoethyl)-, ethyl ester Catalog No.:AG000405 MDL No.: MF:C12H13NO2 MW:203.2371	CAS No. 1012343-72-4 Imidazo[1,2-b]pyridazine, 3-bromo-6-(4-morpholinyl)- Catalog No.:AG000404 MDL No.:MFCD11520886 MF:C10H11BrN4O MW:283.1245
CAS No. 101236-50-4 4H-1-Benzopyran-4-one, 2-(2,4-dihydroxyphenyl)-2,3-dihydro-3,5,7-trihydroxy-6,8-bis(3-methyl-2-buten-1-yl)-, (2R,3R)- Catalog No.:AG00040H MDL No.: MF:C25H28O7 MW:440.4856	CAS No. 101236-95-7 1H-Benzimidazole, 7-nitro-2-(trichloromethyl)- Catalog No.:AG00040G MDL No.: MF:C8H4Cl3N3O2 MW:280.4953	CAS No. 101236-98-0 1H-Benzimidazole, 2-[(4-chlorophenoxy)methyl]-7-nitro- Catalog No.:AG00040F MDL No.: MF:C14H10ClN3O3 MW:303.7005
CAS No. 101237-16-5 2,1,3-Benzoxadiazol-4-amine, N-hexadecyl-7-nitro- Catalog No.:AG00040E MDL No.: MF:C22H36N4O3 MW:404.5462	CAS No. 101237-18-7 2,1,3-Benzoxadiazol-4-amine, 7-nitro-N-2-propen-1-yl- Catalog No.:AG00040D MDL No.: MF:C9H8N4O3 MW:220.1848	CAS No. 101238-01-1 Dodecanoic acid, 2,2,6,6-tetramethyl-4-piperidinyl ester Catalog No.:AG00040C MDL No.: MF:C21H41NO2 MW:339.5557
CAS No. 10124-27-3 Aluminum chloride (AlCl3), hydrate (1:?) Catalog No.:AG00041G MDL No.:MFCD00149135 MF:AlCl3H5O MW:154.3796	CAS No. 10124-41-1 Thiosulfuric acid (H2S2O3), calcium salt (1:1) Catalog No.:AG00041D MDL No.: MF: MW:	CAS No. 10124-53-5 Thiosulfuric acid (H2S2O3), magnesium salt (1:1) Catalog No.:AG000419 MDL No.:MFCD00169871 MF: MW:
CAS No. 10124-56-8 Metaphosphoric acid (H6P6O18), sodium salt (1:6) Catalog No.:AG000418 MDL No.:MFCD00136045 MF: MW:	CAS No. 10124-62-6 Disilane, 1,2-dimethoxy-1,1,2,2-tetramethyl- Catalog No.:AG000417 MDL No.: MF:C6H18O2Si2 MW:178.3769	CAS No. 10124-65-9 Dodecanoic acid, potassium salt (1:1) Catalog No.:AG000416 MDL No.:MFCD00045925 MF:C12H23KO2 MW:238.4081
CAS No. 10124-68-2 2-Propenamide, N-octyl- Catalog No.:AG000415 MDL No.:MFCD24231063 MF:C11H21NO MW:183.2905	CAS No. 10124-78-4 Naphthalene, 2-isocyano- Catalog No.:AG000414 MDL No.:MFCD06200692 MF:C11H7N MW:153.1800	CAS No. 10124-98-8 1,4,9-Decatriene Catalog No.:AG000413 MDL No.: MF:C10H16 MW:136.2340
CAS No. 101241-40-1 Benzene, 1-chloro-4-[(4-methylphenyl)sulfinyl]-2-nitro- Catalog No.:AG000411 MDL No.: MF:C13H10ClNO3S MW:295.7414	CAS No. 101241-44-5 Benzene, 1-chloro-4-nitro-2-(phenylsulfinyl)- Catalog No.:AG000410 MDL No.: MF:C12H8ClNO3S MW:281.7148	CAS No. 101241-52-5 Benzene, 1-ethoxy-2-nitro-4-(phenylsulfinyl)- Catalog No.:AG00040Z MDL No.: MF:C14H13NO4S MW:291.3223
CAS No. 101242-14-2 1H-Isoindole-1,3(2H)-dione, 2-[5-chloro-4-(dichloromethyl)-2-thiazolyl]- Catalog No.:AG00040Y MDL No.: MF:C12H5Cl3N2O2S MW:347.6043	CAS No. 101242-18-6 4-Thiazolecarboxaldehyde, 2-amino-5-chloro-, oxime Catalog No.:AG00040X MDL No.: MF:C4H4ClN3OS MW:177.6121	CAS No. 101242-22-2 4-Thiazolecarboxylic acid, 2-aMino-5-chloro- Catalog No.:AG00040W MDL No.:MFCD03011570 MF:C4H3ClN2O2S MW:178.5968
CAS No. 101244-49-9 Benzeneacetyl chloride, 3-[2-chloro-4-(trifluoromethyl)phenoxy]- Catalog No.:AG00040V MDL No.: MF:C15H9Cl2F3O2 MW:349.1320	CAS No. 101244-51-3 Benzeneacetic acid, 3-[2-chloro-4-(trifluoromethyl)phenoxy]- Catalog No.:AG00040U MDL No.: MF:C15H10ClF3O3 MW:330.6863	CAS No. 101245-15-2 Bicyclo[4.1.0]hept-2-ene-3-acetonitrile, 7,7-dimethyl-, (1R)- (9CI) Catalog No.:AG00040T MDL No.: MF:C11H15N MW:161.2435
CAS No. 101246-06-4 Benzene, 1,1'-(3,3-dibromo-1,2-cyclopropanediyl)bis- Catalog No.:AG00041Y MDL No.: MF:C15H12Br2 MW:352.0638	CAS No. 101246-24-6 Isoxazole, 3-methyl-5-(2-methyl-1-propen-1-yl)- Catalog No.:AG00041X MDL No.: MF:C8H11NO MW:137.1790	CAS No. 101246-34-8 2-Propanone, 1-chloro-1-[(4-methylphenyl)sulfonyl]- Catalog No.:AG00041W MDL No.: MF:C10H11ClO3S MW:246.7105
CAS No. 101246-45-1 Phosphonium, 2-butyne-1,4-diylbis[triphenyl-, diiodide (9CI) Catalog No.:AG00041V MDL No.: MF:C40H34I2P2 MW:830.4544	CAS No. 101246-66-6 Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, 5-(N-phenylcarbamate), (3aS,8aR)- Catalog No.:AG00041U MDL No.: MF:C20H23N3O2 MW:337.4155	CAS No. 101246-71-3 Methanethione, [4-(dimethylamino)phenyl](4-methylphenyl)- Catalog No.:AG00041T MDL No.: MF:C16H17NS MW:255.3779
CAS No. 101246-72-4 Methanone, bis[4-(ethylamino)phenyl]- Catalog No.:AG00041S MDL No.: MF:C17H20N2O MW:268.3535	CAS No. 101246-80-4 Methanone, bis[3,5-bis(diethylamino)phenyl]- Catalog No.:AG00041R MDL No.: MF:C29H46N4O MW:466.7017	CAS No. 101247-77-2 Ethanol, 2-[[3-[4-(phenoxymethyl)phenyl]propyl]amino]- Catalog No.:AG00041Q MDL No.: MF:C18H23NO2 MW:285.3807
CAS No. 101249-88-1 Glycinamide, 1-[(1,1-dimethylethoxy)carbonyl]-L-prolyl-L-arginyl- (9CI) Catalog No.:AG00041P MDL No.: MF:C18H33N7O5 MW:427.4985	CAS No. 10125-07-2 2,5-Piperazinedione, 3-(phenylmethyl)-, (3S)- Catalog No.:AG000426 MDL No.:MFCD00190926 MF:C11H12N2O2 MW:204.2252	CAS No. 10125-11-8 2,5-Piperazinedione, 3,6-bis[(4-hydroxyphenyl)methyl]-, (3S,6S)- Catalog No.:AG000425 MDL No.: MF:C18H18N2O4 MW:326.3465
CAS No. 10125-13-0 Copper chloride (CuCl2), dihydrate (8CI,9CI) Catalog No.:AG000424 MDL No.:MFCD00149674 MF:Cl2CuO2 MW:166.4508	CAS No. 10125-28-7 Piperazine, 1-(1,1-dimethylethyl)-4-methyl- Catalog No.:AG000423 MDL No.: MF:C9H20N2 MW:156.2685	CAS No. 10125-76-5 1,1'-Biphenyl, 4-nitroso- Catalog No.:AG000422 MDL No.: MF:C12H9NO MW:183.2060
CAS No. 10125-79-8 Piperazine, 1-(1,1-dimethylethyl)-4-ethyl- Catalog No.:AG000421 MDL No.: MF:C10H22N2 MW:170.2951	CAS No. 10125-84-5 Piperidinium, 1-methyl-1-(1-methylethyl)-4-phenyl-, iodide (1:1) Catalog No.:AG000420 MDL No.: MF:C15H24IN MW:345.2622	CAS No. 10125-85-6 Piperidinium, 1,1-dimethyl-4-phenyl-, iodide (1:1) Catalog No.:AG00041Z MDL No.: MF:C13H20IN MW:317.2091
CAS No. 101250-44-6 3-Morpholinone, 5-(2-methylpropyl)-, (5S)- Catalog No.:AG00041O MDL No.:MFCD27940846 MF:C8H15NO2 MW:157.2102	CAS No. 101250-48-0 3-Morpholinone, 5-(phenylmethyl)-, (5S)- Catalog No.:AG00041N MDL No.: MF:C11H13NO2 MW:191.2264	CAS No. 101250-69-5 2-Pyrrolidinecarboxaldehyde, 1-[(4-methylphenyl)sulfonyl]-, (2S)- Catalog No.:AG00041M MDL No.: MF:C12H15NO3S MW:253.3174
CAS No. 101250-90-2 Carbamic acid, N-[(5S)-5-amino-6-hydroxyhexyl]-, phenylmethyl ester Catalog No.:AG00041L MDL No.:MFCD00671688 MF:C14H22N2O3 MW:266.3361	CAS No. 101250-96-8 Imidodicarbonimidic diamide, N-(4-bromophenyl)- Catalog No.:AG00041K MDL No.:MFCD00464642 MF:C8H10BrN5 MW:256.1025	CAS No. 101250-97-9 Guanidine, N,N'-dimethyl-N''-nitro- (9CI) Catalog No.:AG00041J MDL No.: MF:C3H8N4O2 MW:132.1212
CAS No. 101251-09-6 Boronic acid, B-[4-(acetylamino)phenyl]- Catalog No.:AG00041I MDL No.:MFCD02179451 MF:C8H10BNO3 MW:178.9809	CAS No. 101252-66-8 Benzenemethanol, 2-chloro-5-methoxy- Catalog No.:AG00042G MDL No.:MFCD12024393 MF:C8H9ClO2 MW:172.6089	CAS No. 101252-73-7 Benzenemethanamine, 2-chloro-6-nitro- Catalog No.:AG00042F MDL No.: MF:C7H7ClN2O2 MW:186.5957
CAS No. 101252-84-0 Pyridine, 4,6-dichloro-2,3-dimethyl- Catalog No.:AG00042E MDL No.:MFCD26743449 MF:C7H7Cl2N MW:176.0432	CAS No. 101252-97-5 1-Azabicyclo[3.2.1]octane, 2-methyl- Catalog No.:AG00042D MDL No.:MFCD18806573 MF:C8H15N MW:125.2114	CAS No. 101253-30-9 L-Proline, 1-propyl- Catalog No.:AG00042C MDL No.:MFCD08442908 MF:C8H15NO2 MW:157.2102
CAS No. 101253-50-3 6-Benzothiazolamine, 5-chloro-2-methyl- Catalog No.:AG00042B MDL No.:MFCD18826625 MF:C8H7ClN2S MW:198.6726	CAS No. 101253-70-7 Ethanedioic acid, 1,2-bis(3-cyclohexen-1-ylmethyl) ester Catalog No.:AG00042A MDL No.: MF:C16H22O4 MW:278.3435	CAS No. 101256-79-5 1-Propanone, 3-(4-morpholinyl)-1-(3,4,5-trimethoxyphenyl)- Catalog No.:AG000429 MDL No.: MF:C16H23NO5 MW:309.3575
CAS No. 101256-98-8 4-Thiazolol, 2-methyl- Catalog No.:AG000428 MDL No.:MFCD12033228 MF:C4H5NOS MW:115.1536	CAS No. 101256-99-9 Hydrazinecarboxamide, 2-(3-methylhexylidene)- Catalog No.:AG000427 MDL No.: MF:C8H17N3O MW:171.2401	CAS No. 37339-60-9 2-Pyridinecarboxylic acid, 4-amino-3,5,6-trichloro-, mixt. with (2,4-dichlorophenoxy)acetic acid Catalog No.:AG000412 MDL No.: MF: MW: