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994-05-8 | Tert-Amyl Methyl Ether
CAS No: 994-05-8 Catalog No: AG003UIN MDL No:MFCD00010186
Product Description
Catalog Number:
AG003UIN
Chemical Name:
Tert-Amyl Methyl Ether
CAS Number:
994-05-8
Molecular Formula:
C6H14O
Molecular Weight:
102.1748
MDL Number:
MFCD00010186
IUPAC Name:
2-methoxy-2-methylbutane
InChI:
InChI=1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
InChI Key:
HVZJRWJGKQPSFL-UHFFFAOYSA-N
SMILES:
CCC(OC)(C)C
EC Number:
213-611-4
UNII:
94525J1AP8
RTECS Number:
EK4421000
UN Number:
3271
Properties
Complexity:
48.1
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
102.104g/mol
Formal Charge:
0
Heavy Atom Count:
7
Hydrogen Bond Acceptor Count:
1
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
102.177g/mol
Monoisotopic Mass:
102.104g/mol
Rotatable Bond Count:
2
Topological Polar Surface Area:
9.2A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.6
Literature
| Title | Journal |
|---|---|
| Craniofacial abnormalities and altered wnt and mmp mRNA expression in zebrafish embryos exposed to gasoline oxygenates ETBE and TAME. | Aquatic toxicology (Amsterdam, Netherlands) 20120915 |
| Oxidative degradation of alternative gasoline oxygenates in aqueous solution by ultrasonic irradiation: mechanistic study. | The Science of the total environment 20120715 |
| Critical evaluation of the 2D-CSIA scheme for distinguishing fuel oxygenate degradation reaction mechanisms. | Environmental science & technology 20120501 |
| Adsorption of BTEX, MTBE and TAME on natural and modified diatomite. | Journal of hazardous materials 20120315 |
| Removal of BTEX, MTBE and TAME from aqueous solutions by adsorption onto raw and thermally treated lignite. | Journal of hazardous materials 20120315 |
| Biofilm formation and microbial activity in a biofilter system in the presence of MTBE, ETBE and TAME. | Chemosphere 20111001 |
| Chronic carcinogenicity study of gasoline vapor condensate (GVC) and GVC containing methyl tertiary-butyl ether in F344 rats. | Journal of toxicology and environmental health. Part A 20110515 |
| ETBE (ethyl tert butyl ether) and TAME (tert amyl methyl ether) affect microbial community structure and function in soils. | Journal of hazardous materials 20110315 |
| Cytochromes P450-mediated degradation of fuel oxygenates by environmental isolates. | FEMS microbiology ecology 20100501 |
| MTBE, TBA, and TAME attenuation in diverse hyporheic zones. | Ground water 20100101 |
| Stable carbon and hydrogen isotope analysis of methyl tert-butyl ether and tert-amyl methyl ether by purge and trap-gas chromatography-isotope ratio mass spectrometry: method evaluation and application. | Journal of environmental monitoring : JEM 20100101 |
| Odour and flavour thresholds of gasoline additives (MTBE, ETBE and TAME) and their occurrence in Dutch drinking water collection areas. | Chemosphere 20090701 |
| Single-walled carbon nanotubes as an effective adsorbent in solid-phase microextraction of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether from human urine. | Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20090515 |
| Isotopic fractionation of methyl tert-butyl ether suggests different initial reaction mechanisms during aerobic biodegradation. | Environmental science & technology 20090415 |
| Mineralization of methyl tert-butyl ether and other gasoline oxygenates by Pseudomonads using short n-alkanes as growth source. | Biodegradation 20090401 |
| Direct screening of ground water samples for fuel oxygenates by headspace liquid phase microextraction-gas chromatography. | Environmental monitoring and assessment 20081201 |
| Selection and identification of bacterial strains with methyl-tert-butyl ether, ethyl-tert-butyl ether, and tert-amyl methyl ether degrading capacities. | Environmental toxicology and chemistry 20081101 |
| Quantification of fuel oxygenate ethers in human blood using solid-phase microextraction coupled with gas chromatography-high-resolution mass spectrometry. | Journal of analytical toxicology 20080501 |
| Degradation of fuel oxygenates and their main intermediates by Aquincola tertiaricarbonis L108. | Microbiology (Reading, England) 20080501 |
| Measurement of fuel oxygenates in tap water using solid-phase microextraction gas chromatography-mass spectrometry. | Journal of chromatographic science 20080101 |
| Simultaneous determination of gasoline oxygenates and benzene, toluene, ethylbenzene and xylene in water samples using headspace-programmed temperature vaporization-fast gas chromatography-mass spectrometry. | Journal of chromatography. A 20071214 |
| Toxicokinetics of methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) in humans, and implications to their biological monitoring. | Journal of occupational and environmental hygiene 20071001 |
| Comprehensive experimental and theoretical study of chemical equilibria in the reacting system of the tert-amyl methyl ether synthesis. | The journal of physical chemistry. B 20070920 |
| Effects of environmental settings on MTBE removal for a mixed culture and its monoculture isolation. | Applied microbiology and biotechnology 20070201 |
| Determination of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether in human urine by HS-SPME gas chromatography/mass spectrometry. | Analytica chimica acta 20070102 |
| Interactive effects of methyl tertiary-butyl ether (MTBE) and tertiary-amyl methyl ether (TAME), ethanol and some drugs: Triglyceridemia, liver toxicity and induction of CYP (2E1, 2B1) and phase II enzymes in female Wistar rats. | Environmental toxicology and pharmacology 20070101 |
| Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography-mass spectrometry. | Journal of chromatography. A 20061103 |
| Formation of iodoacetic acids during cooking: interaction of iodized table salt with chlorinated drinking water. | Food additives and contaminants 20061001 |
| Exposure to MTBE, TAME and aromatic hydrocarbons during gasoline pump maintenance, repair and inspection. | Journal of occupational health 20060901 |
| Bioremediation of groundwater contaminated with gasoline hydrocarbons and oxygenates using a membrane-based reactor. | Environmental science & technology 20060315 |
| Fate of gasoline oxygenates in conventional and multilevel wells of a contaminated groundwater table in Düsseldorf, Germany. | Environmental toxicology and chemistry 20051101 |
| Carbon isotopic fractionation during anaerobic biotransformation of methyl tert-butyl ether and tert-amyl methyl ether. | Environmental science & technology 20050101 |
| Air-water transfer of MTBE, its degradation products, and alternative fuel oxygenates: the role of temperature. | Environmental science & technology 20041015 |
| Optimizing the determination of haloacetic acids in drinking waters. | Journal of chromatography. A 20040430 |
| Determination of fuel dialkyl ethers and BTEX in water using headspace solid-phase microextraction and gas chromatography-flame ionization detection. | Journal of chromatography. A 20040416 |
| Evaluation of the impact of fuel hydrocarbons and oxygenates on groundwater resources. | Environmental science & technology 20040101 |
| Avoiding hydrolysis of fuel ether oxygenates during static headspace analysis. | Environmental science & technology 20031101 |
| Simultaneous determination of methyl tert.-butyl ether and its degradation products, other gasoline oxygenates and benzene, toluene, ethylbenzene and xylenes in Catalonian groundwater by purge-and-trap-gas chromatography-mass spectrometry. | Journal of chromatography. A 20030502 |
| Developmental toxicity evaluation of inhaled tertiary amyl methyl ether in mice and rats. | Journal of applied toxicology : JAT 20030101 |
| Two-generation reproductive toxicity study of inhaled tertiary amyl methyl ether (TAME) vapor in CD rats. | Journal of applied toxicology : JAT 20030101 |
| Characterization of metabolites and disposition of tertiary amyl methyl ether in male F344 rats following inhalation exposure. | Journal of applied toxicology : JAT 20030101 |
| Blood pharmacokinetics of tertiary amyl methyl ether in male and female F344 rats and CD-1 mice after nose-only inhalation exposure. | Journal of applied toxicology : JAT 20030101 |
| Species and gender differences in the metabolism and distribution of tertiary amyl methyl ether in male and female rats and mice after inhalation exposure or gavage administration. | Journal of applied toxicology : JAT 20030101 |
| Results of long-term carcinogenicity bioassays on tert-amyl-methyl-ether (TAME) and di-isopropyl-ether (DIPE) in rats. | Annals of the New York Academy of Sciences 20021201 |
| Aerobic degradation of ethyl-tert-butyl ether by a microbial consortium: selection and evaluation of biodegradation ability. | Environmental toxicology and chemistry 20021001 |
| Simultaneous determination of fuel oxygenates and BTEX using direct aqueous injection gas chromatography mass spectrometry (DAI-GC/MS). | Environmental science & technology 20020501 |
| Influence of oxygenated fuel additives and their metabolites on the binding of a convulsant ligand of the gamma-aminobutyric acid(A) (GABA(A)) receptor in rat brain membrane preparations. | Toxicology letters 20020328 |
| Toxicokinetics of ethers used as fuel oxygenates. | Toxicology letters 20011015 |
| Human cytochrome P450 2A6 is the major enzyme involved in the metabolism of three alkoxyethers used as oxyfuels. | Toxicology letters 20011015 |
| Toxicology and human health effects following exposure to oxygenated or reformulated gasoline. | Toxicology letters 20010915 |
| Microbial degradation and fate in the environment of methyl tert-butyl ether and related fuel oxygenates. | Applied microbiology and biotechnology 20010801 |
| Methyl tert-butyl ether (MTBE) degradation by a microbial consortium. | Environmental microbiology 20010601 |
| Aerobic biodegradation of an oxygenates mixture: ETBE, MTBE and TAME in an upflow fixed-bed reactor. | Water research 20010501 |
| Biotransformation of MTBE, ETBE, and TAME after inhalation or ingestion in rats and humans. | Research report (Health Effects Institute) 20010501 |
| Human cytochrome P450 isozymes in metabolism and health effects of gasoline ethers. | Research report (Health Effects Institute) 20010501 |
| Isolation and characterization of two aerobic bacterial strains that completely degrade ethyl tert-butyl ether (ETBE). | Applied microbiology and biotechnology 20010401 |
| Biodegradation of ethyl t-butyl ether (ETBE), methyl t-butyl ether (MTBE) and t-amyl methyl ether (TAME) by Gordonia terrae. | Applied microbiology and biotechnology 20010101 |
| Biodegradation of the gasoline oxygenates methyl tert-butyl ether, ethyl tert-butyl ether, and tert-amyl methyl ether by propane-oxidizing bacteria. | Applied and environmental microbiology 19971101 |
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