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7688-25-7 | 1,4-Bis(Diphenylphosphino)Butane
CAS No: 7688-25-7 Catalog No: AG0032MA MDL No:MFCD00003051
Product Description
Catalog Number:
AG0032MA
Chemical Name:
1,4-Bis(Diphenylphosphino)Butane
CAS Number:
7688-25-7
Molecular Formula:
C28H28P2
Molecular Weight:
426.4694
MDL Number:
MFCD00003051
IUPAC Name:
4-diphenylphosphanylbutyl(diphenyl)phosphane
InChI:
InChI=1S/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2
InChI Key:
BCJVBDBJSMFBRW-UHFFFAOYSA-N
SMILES:
C(CP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1
EC Number:
231-698-7
UNII:
35HP6LTD2D
Properties
Complexity:
362
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
426.167g/mol
Formal Charge:
0
Heavy Atom Count:
30
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
426.48g/mol
Monoisotopic Mass:
426.167g/mol
Rotatable Bond Count:
9
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
6.6
Literature
| Title | Journal |
|---|---|
| Mechanism of the Pd-catalyzed decarboxylative allylation of α-imino esters: decarboxylation via free carboxylate ion. | Chemistry (Weinheim an der Bergstrasse, Germany) 20121105 |
| Direct substitution of primary allylic amines with sulfinate salts. | Journal of the American Chemical Society 20120912 |
| Synthesis, spectral, thermal, X-ray single crystal of new RuCl₂(dppb)diamine complexes and their application in hydrogenation of Cinnamic aldehyde. | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120901 |
| Correlation between photophysical parameters and gold-gold distances in gold(I) (4-pyridyl)ethynyl complexes. | Inorganic chemistry 20120716 |
| cis-[1,4-Bis(diphenyl-phosphan-yl)butane-κ(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-κ(2)N,N')ruthenium(II) dichloro-methane monosolvate. | Acta crystallographica. Section E, Structure reports online 20120501 |
| Ruthenium(II) phosphine/diimine/picolinate complexes: inorganic compounds as agents against tuberculosis. | European journal of medicinal chemistry 20111001 |
| Gold(I) complexes bearing mixed-donor ligands derived from N-heterocyclic carbenes. | Dalton transactions (Cambridge, England : 2003) 20110707 |
| Syntheses and structures of ruthenium(II) N,S-heterocyclic carbene diphosphine complexes and their catalytic activity towards transfer hydrogenation. | Chemistry, an Asian journal 20110606 |
| [1,4-Bis(diphenyl-phosphan-yl)butane-κP,P']chlorido(η-inden-yl)ruthenium(II). | Acta crystallographica. Section E, Structure reports online 20110501 |
| Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands. | Dalton transactions (Cambridge, England : 2003) 20110121 |
| Synthesis of symmetrical and unsymmetrical diarylalkynes from propiolic acid using palladium-catalyzed decarboxylative coupling. | The Journal of organic chemistry 20100917 |
| Ruthenium-catalyzed oxidation of alcohols into amides. | Organic letters 20090618 |
| Palladium-catalyzed decarboxylative coupling of alkynyl carboxylic acids and aryl halides. | The Journal of organic chemistry 20090206 |
| μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV). | Acta crystallographica. Section E, Structure reports online 20080601 |
| Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates. | Dalton transactions (Cambridge, England : 2003) 20071221 |
| Mixed-ligand organometallic polymers containing the 'Pd(2)(dmb)2(2+)' fragment: properties of the [Pd2(dmb)2(diphos)2+](n) polymers/oligomers in solution and in the solid state. | Inorganic chemistry 20040823 |
| Preparation and solid-state characterization of mixed-ligand coordination/organometallic oligomers and polymers of copper(I) and silver(I) using diphosphine and mono- and diisocyanide ligands. | Inorganic chemistry 20040517 |
| A trichloro-bridged binuclear ruthenium complex with 1,1,1-tris(diphenylphosphinomethyl)ethane. | Acta crystallographica. Section C, Crystal structure communications 20031101 |
| Progress in the palladium-catalyzed cyanation of aryl chlorides. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030414 |
| Gold(I) macrocycles and topologically chiral [2]catenanes. | Journal of the American Chemical Society 20020417 |
| Self-assembly of rings, catenanes, and a doubly braided catenane containing gold(I): the hinge-group effect in diacetylide ligands. | Chemistry (Weinheim an der Bergstrasse, Germany) 20010817 |
| Rate and mechanism of the reversible formation of cationic (eta3-allyl)-palladium complexes in the oxidative addition of allylic acetate to palladium(0) complexes ligated by diphosphanes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20010316 |
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