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74087-85-7 | Dioxirane, dimethyl-
CAS No: 74087-85-7 Catalog No: AG005HLY MDL No:
Product Description
Catalog Number:
AG005HLY
Chemical Name:
Dioxirane, dimethyl-
CAS Number:
74087-85-7
Molecular Formula:
C3H6O2
Molecular Weight:
74.0785
IUPAC Name:
3,3-dimethyldioxirane
InChI:
InChI=1S/C3H6O2/c1-3(2)4-5-3/h1-2H3
InChI Key:
FFHWGQQFANVOHV-UHFFFAOYSA-N
SMILES:
CC1(C)OO1
UNII:
R5RAT196DJ
Properties
Complexity:
42.9
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
74.037g/mol
Formal Charge:
0
Heavy Atom Count:
5
Hydrogen Bond Acceptor Count:
2
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
74.079g/mol
Monoisotopic Mass:
74.037g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
25.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.6
Literature
| Title | Journal |
|---|---|
| Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands. | Inorganic chemistry 20120716 |
| Tandem post-synthetic modification for functionalized metal-organic frameworks via epoxidation and subsequent epoxide ring-opening. | Chemical communications (Cambridge, England) 20120318 |
| Synthesis and characterization of energetic 3-nitro-1,2,4-oxadiazoles. | Chemistry (Weinheim an der Bergstrasse, Germany) 20120213 |
| tRNA structural and functional changes induced by oxidative stress. | Cellular and molecular life sciences : CMLS 20111201 |
| New crystalline aluminum alkoxide oxide fluorides: evidence of the mechanism of the fluorolytic sol-gel reaction. | Dalton transactions (Cambridge, England : 2003) 20110914 |
| Bypass of aflatoxin B1 adducts by the Sulfolobus solfataricus DNA polymerase IV. | Journal of the American Chemical Society 20110817 |
| Use of dimethyldioxirane in the epoxidation of the main constituents of the essential oils obtained from Tagetes lucida, Cymbopogon citratus, Lippia alba and Eucalyptus citriodora. | Natural product communications 20110701 |
| Preparation, X-ray structure, and reactivity of 2-iodylpyridines: recyclable hypervalent iodine(V) reagents. | The Journal of organic chemistry 20110520 |
| Developing a diastereoselective intramolecular [4+3] cycloaddition of nitrogen-stabilized oxyallyl cations derived from N-sulfonyl-substituted allenamides. | The Journal of organic chemistry 20110506 |
| Stereoelectronic factors in the stereoselective epoxidation of glycals and 4-deoxypentenosides. | The Journal of organic chemistry 20110415 |
| Substrate and product analogues as human O-GlcNAc transferase inhibitors. | Amino acids 20110301 |
| Extracts and constituents of Rubus chingii with 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activity. | International journal of molecular sciences 20110101 |
| Analysis of residual chemicals on filtering facepiece respirators after decontamination. | Journal of occupational and environmental hygiene 20100801 |
| Reactions of 7,8-dithiabicyclo[4.2.1]nona-2,4-diene 7-exo-oxide with dodecacarbonyl triiron Fe3(CO)12: a novel type of sulfenato thiolato diiron hexacarbonyl complexes. | Chemistry, an Asian journal 20100705 |
| Effect of the substrate and catalyst chirality on the diastereoselective epoxidation of limonene using Jacobsen-type catalysts. | Chirality 20100505 |
| Regioselective control in the oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides by dimethyldioxirane. | The Journal of organic chemistry 20100305 |
| A submarine journey: the pyrrole-imidazole alkaloids. | Marine drugs 20091201 |
| Structural perturbations induced by the alpha-anomer of the aflatoxin B(1) formamidopyrimidine adduct in duplex and single-strand DNA. | Journal of the American Chemical Society 20091111 |
| Preparation, X-ray structure, and oxidative reactivity of N-(2-iodylphenyl)tosylamides and 2-iodylphenyl tosylate: iodylarenes stabilized by ortho-substitution with a sulfonyl group. | The Journal of organic chemistry 20091106 |
| Spirodiepoxides: synthesis of epoxomicinoids. | The Journal of organic chemistry 20091016 |
| Silyl-substituted spirodiepoxides: stereoselective formation and regioselective opening. | Organic letters 20091015 |
| Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation. | Chemical communications (Cambridge, England) 20090728 |
| Palladium-catalysed enantioselective alpha-hydroxylation of beta-ketoesters. | Chemical communications (Cambridge, England) 20090714 |
| DMD mediated formal synthesis of (+/-)-coerulescine. | Natural product communications 20090601 |
| Iminohydantoin lesion induced in DNA by peracids and other epoxidizing oxidants. | Journal of the American Chemical Society 20090506 |
| A facile synthesis of C-24 and C-25 oxysterols by in situ generated ethyl(trifluoromethyl)dioxirane. | Steroids 20090101 |
| Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole. | Chemical communications (Cambridge, England) 20081214 |
| Oxidation of diiron and triiron sulfurdithiolato complexes: mimics for the active site of [FeFe]-hydrogenase. | Chemistry & biodiversity 20081001 |
| Theoretical investigations of substituent effects in dimethyldioxirane epoxidation reactions. | The Journal of organic chemistry 20080718 |
| Synthesis of (+)-cortistatin A. | Journal of the American Chemical Society 20080611 |
| Reactive intermediates from DMDO oxidation of ynamides. Trapping of a de novo chiral push-pull carbene via cyclopropanation. | Organic letters 20080221 |
| An investigation by means of correlation analysis into the mechanisms of oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane in various solvents. | Organic & biomolecular chemistry 20080221 |
| Kinetic studies on the oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane; absolute rate constants and activation parameters for 4-nitrophenyl methyl sulfide and sulfoxide. | Organic & biomolecular chemistry 20080221 |
| Concerning the reactivity of dioxiranes. Observations from experiments and theory. | Journal of the American Chemical Society 20080130 |
| Chemical and enzymatic oxidation of furosemide: formation of pyridinium salts. | Chemical research in toxicology 20071201 |
| Peroxidation enhances the biogas production in the anaerobic digestion of biosolids. | Journal of hazardous materials 20070731 |
| Oxidation of some cage hydrocarbons by dioxiranes. Nature of the transition structure for the reaction of C-H bonds with dimethyldioxirane: a comparison of B3PW91 density functional theory with experiment. | Organic & biomolecular chemistry 20070721 |
| On the effect of 1,4-diazabicyclo[2.2.2]octane on the singlet-oxygen dimol emission: chemical generation of 1O2)2 in peroxide reactions. | The journal of physical chemistry. A 20070524 |
| Bicyclic beta-Hydroxytetrahydrofurans as precursors of medium ring keto-lactones. | The Journal of organic chemistry 20070413 |
| Synthesis of a stereochemically defined 1,2-diazetine N,N'-dioxide and a study of its thermal decomposition. | The Journal of organic chemistry 20070216 |
| Oxyfunctionalization products of terpenoids with dimethyldioxirane and their biological activity. | Chemical & pharmaceutical bulletin 20070201 |
| Rearrangement of a (dithiolato)platinum(II) complex formed by reaction of cyclic disulfide 7,8-dithiabicyclo[4.2.1]nona-2,4-diene with a platinum(0) complex: oxidation of the rearranged (dithiolato)platinum(II) complex. | Chemistry (Weinheim an der Bergstrasse, Germany) 20070101 |
| An alternative synthetic method for 4'-C-ethynylstavudine by means of nucleophilic substitution of 4'-benzoyloxythymine nucleoside. | Nucleosides, nucleotides & nucleic acids 20070101 |
| Direct epoxidation of D-glucal and D-galactal derivatives with in situ generated DMDO. | Carbohydrate research 20061127 |
| Mechanisms of killing of spores of Bacillus subtilis by dimethyldioxirane. | Journal of applied microbiology 20061101 |
| 2-iodylphenol ethers: preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents. | The Journal of organic chemistry 20061027 |
| Characterization of the amino acid adducts of the enedial derivative of teucrin A. | Chemical research in toxicology 20061001 |
| Stereoselective epoxidation of 4-deoxypentenosides: a polarized-pi model. | Organic letters 20060928 |
| Reaction of thioketones with propiolic acids. | Organic & biomolecular chemistry 20060721 |
| The role of asynchronous bond formation in the diastereoselective epoxidation of cyclic enol ethers: a density functional theory study. | The Journal of organic chemistry 20060721 |
| A 2-iminohydantoin from the oxidation of guanine. | Chemical research in toxicology 20060401 |
| Anti versus syn opening of epoxides derived from 9-(3-deoxy-beta-D-glycero-pent-3-enofuranosyl)adenine with Me3Al: factors controlling the stereoselectivity. | The Journal of organic chemistry 20060203 |
| Transition state effects in the acid-catalyzed hydrolysis of 5-methoxyacenaphthylene 1,2-oxide: implications for the mechanism of acid-catalyzed hydrolysis of cyclopenta[cd]pyrene 3,4-oxide. | Chemical research in toxicology 20060201 |
| Synthesis and properties of a dithiirane trans-1,2-dioxide, a three-membered vic-disulfoxide. | Organic letters 20060105 |
| Two generalizable routes to terminal carbido complexes. | Journal of the American Chemical Society 20051207 |
| Functionalized nanodiamonds part I. An experimental assessment of diamantane and computational predictions for higher diamondoids. | Chemistry (Weinheim an der Bergstrasse, Germany) 20051118 |
| Determination of in situ-generated dimethyldioxirane from an aqueous matrix using selected ion monitoring. | Journal of chromatography. A 20050930 |
| Use of in situ-generated dimethyldioxirane for inactivation of biological agents. | Environmental science & technology 20050815 |
| Esters of 2-iodoxybenzoic acid: hypervalent iodine oxidizing reagents with a pseudobenziodoxole structure. | The Journal of organic chemistry 20050805 |
| The dimethyldioxirane-mediated oxidation of phenylethyne. | Organic & biomolecular chemistry 20050621 |
| Synthesis of a 4,6-disubstituted dibenzofuran beta-sheet initiator by reductive radical arylation of benzene. | The Journal of organic chemistry 20050318 |
| Late-stage intermolecular CH activation for lead diversification: a highly chemoselective oxyfunctionalization of the C-9 position of potent bryostatin analogues. | Organic letters 20050106 |
| Evidence for the preventive effect of the polyunsaturated phytol side chain in tocotrienols on 17beta-estradiol epoxidation. | Cancer detection and prevention 20050101 |
| A new approach to the synthesis of 4'-carbon-substituted nucleosides: development of a highly active anti-HIV agent 2', 3'-didehydro-3'-deoxy-4'-ethynylthymidine. | Nucleosides, nucleotides & nucleic acids 20050101 |
| Synthesis of the 1,6,8-trioxadispiro[4.1.5.2]tetradec-11-ene ring system present in the spirolide family of shellfish toxins and its conversion into a 1,6,8-trioxadispiro[4.1.5.2]-tetradec-9-en-12-ol via base-induced rearrangement of an epoxide. | Organic & biomolecular chemistry 20041221 |
| Concerning the efficient conversion of epoxy alcohols into epoxy ketones using dioxiranes. | The Journal of organic chemistry 20041126 |
| Studies on the chemopreventive potentials of vegetable oils and unsaturated fatty acids against breast cancer carcinogenesis at initiation. | European journal of cancer prevention : the official journal of the European Cancer Prevention Organisation (ECP) 20040801 |
| Reversible disulfur monoxide (S2O)-forming retro-Diels-Alder reaction. disproportionation of S2O to trithio-ozone (S3) and sulfur dioxide (SO2) and reactivities of S2O and S3. | Journal of the American Chemical Society 20040728 |
| First isolation of eclipsed vic-disulfoxide: 7,8-dithiabicyclo[4.2.1]nona-2,4-diene 7-exo,8-exo-dioxide. | Organic letters 20040722 |
| Synthesis, crystal structure, and reactivity of a D-xylose based oxepine. | Carbohydrate research 20040428 |
| A concise total synthesis of (+)-FR900482 and (+)-FR66979. | The Journal of organic chemistry 20040416 |
| Ring opening of nucleoside 1',2'-epoxides with organoaluminum reagents: stereoselective entry to ribonucleosides branched at the anomeric position. | The Journal of organic chemistry 20040319 |
| Oxidation of cis- and trans-3,5-di-tert-butyl-3,5-diphenyl-1,2,4-trithiolanes: isolation and properties of the 1-oxides and the 1,2-dioxides. | The Journal of organic chemistry 20040305 |
| Enecarbamates as selective substrates in oxidations: chiral-auxiliary-controlled mode selectivity and diastereoselectivity in the [2+2] cycloaddition and ene reaction of singlet oxygen and in the epoxidation by DMD and mCPBA. | The Journal of organic chemistry 20040305 |
| Oxidative rearrangement of imidazoles with dimethyldioxirane. | Organic letters 20040304 |
| Synthesis of 3alpha,7alpha,14alpha-trihydroxy-5beta-cholan-24-oic acid: a potential primary bile acid in vertebrates. | Chemical & pharmaceutical bulletin 20040301 |
| Kinetics of the epoxidation of geraniol and model systems by dimethyldioxirane. | Molecules (Basel, Switzerland) 20040227 |
| Singlet-oxygen generation in the catalytic reaction of dioxiranes with nucleophilic anions. | Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20040201 |
| Stereoselective synthesis of 4'-carbon-substituted xylofuranosyladenines. | Nucleic acids symposium series (2004) 20040101 |
| Stereoselective intramolecular [4 + 3] cycloadditions of nitrogen-stabilized chiral oxyallyl cations via epoxidation of N-tethered allenamides. | Journal of the American Chemical Society 20031022 |
| Oxyfunctionalization of non-natural targets by dioxiranes. 5. Selective oxidation of hydrocarbons bearing cyclopropyl moieties. | The Journal of organic chemistry 20031003 |
| One-pot conversion of glycals to cis-1,2-isopropylidene-alpha-glycosides. | The Journal of organic chemistry 20030919 |
| New oxidative tools for the functionalization of the cephalostatin north 1 hemisphere. | Organic letters 20030626 |
| Asymmetric total synthesis of pseurotin A. | Organic letters 20030626 |
| Ring opening of 4',5'-epoxynucleosides: a novel stereoselective entry to 4'-C-branched nucleosides. | Organic letters 20030501 |
| Cyclododecatetraene tetraepoxide: highly diastereofacial epoxidation of all-(Z)-1,4,7,10-cyclododecatetraene and selective synthesis of bridged bis-oxocanes. | The Journal of organic chemistry 20030418 |
| Synthesis of the mitomycin and FR900482 ring systems via dimethyldioxirane oxidation. | Organic letters 20030320 |
| Functionalization of unactivated carbons in 3alpha,6- and 3alpha,24-dihydroxy-5beta-cholane derivatives by dimethyldioxirane. | Lipids 20030301 |
| Novel pathways for oxygen insertion into unactivated C-H bonds by dioxiranes. Transition structures for stepwise routes via radical pairs and comparison with the concerted pathway. | The Journal of organic chemistry 20030207 |
| Relative reactivity of peracids versus dioxiranes (DMDO and TFDO) in the epoxidation of alkenes. A combined experimental and theoretical analysis. | Journal of the American Chemical Society 20030129 |
| Total synthesis of (-)-fumiquinazolines A, B, C, E, H, and I. Approaches to the synthesis of fiscalin A. | The Journal of organic chemistry 20030124 |
| Oxidation of guanine nucleosides to 4-amidinocarbamoyl-5-hydroxyimidazoles by dimethyldioxirane. | Nucleosides, nucleotides & nucleic acids 20030101 |
| Prevention of chemical carcinogen DNA binding and inhibition of nuclear RNA polymerase activity by organosulfur compounds as the possible mechanisms for their anticancer initiation and proliferation effects. | Cancer detection and prevention 20030101 |
| Concise enantioselective synthesis of (+)-FR66979 and (+)-FR900482: dimethyldioxirane-mediated construction of the hydroxylamine hemiketal. | Angewandte Chemie (International ed. in English) 20021216 |
| Potential bile acid metabolites. 25. Synthesis and chemical properties of stereoisomeric 3alpha,7alpha,16- and 3alpha,7alpha,15-trihydroxy-5beta-cholan-24-oic acids. | Chemical & pharmaceutical bulletin 20021001 |
| Mechanism of the oxidation of sulfides by dioxiranes. 1. Intermediacy of a 10-S-4 hypervalent sulfur adduct. | Journal of the American Chemical Society 20020807 |
| Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane. | The Journal of organic chemistry 20020531 |
| The effect of substitutents on the strain energies of small ring compounds. | The Journal of organic chemistry 20020419 |
| On the chemiluminescence in the oxidation of tetravalent uranium to the uranyl ion by dimethyldioxirane. | Luminescence : the journal of biological and chemical luminescence 20020101 |
| Reaction of 4',5'-epoxynucleosides with carbon nucleophiles: stereoselective synthesis of 4'-C-carbon-substituted nucleosides. | Nucleic acids research. Supplement (2001) 20020101 |
| Molecule-induced alkane homolysis with dioxiranes. | Journal of the American Chemical Society 20011114 |
| Conversions by dimethyldioxirane of 1-alkylbenzotriazoles into their N-oxides and of 2-alkylbenzotriazoles into 2-alkyl-trans-4,5,6,7-diepoxy-4,5,6,7-tetrahydrobenzotriazoles. | The Journal of organic chemistry 20010810 |
| Efficient control of the diastereoselectivity and regioselectivity in the singlet-oxygen ene reaction of chiral oxazolidine-substituted alkenes by a remote urea NH functionality: comparison with dimethyldioxirane and m-chloroperbenzoic acid epoxidations. | Journal of the American Chemical Society 20010801 |
| Oxidation of nitrobenzylic carbanions with dimethyldioxirane. new synthesis of quinomethanes and nitrobenzylic carbinols. First examples of methylation of carbanions with dimethyldioxirane. | The Journal of organic chemistry 20010727 |
| Synthesis of alpha-keto esters and amides via oxidative cleavage of cyanoketophosphoranes by dimethyldioxirane. | The Journal of organic chemistry 20010518 |
| Approaches to the synthesis of some tyrosine-derived marine sponge metabolites: synthesis of verongamine and purealidin N. | The Journal of organic chemistry 20010504 |
| Aldehydic lipid peroxidation products derived from linoleic acid. | Biochimica et biophysica acta 20010430 |
| Chemo- and diastereoselectivity in the dimethyldioxirane oxidation of 2,3-dihydro-4H-1-benzothiopyran-4-ones and 4H-1-benzothiopyran-4-ones. Unusual reactivity of 4H-1-benzothiopyran-4-one 1-oxides. | The Journal of organic chemistry 20010406 |
| Total synthesis of the epidermal growth factor inhibitor (-)-reveromycin B. | The Journal of organic chemistry 20010406 |
| The application of dimethyldioxirane for the selective oxidation of polyfunctional steroids. | Chemistry and physics of lipids 20010201 |
| Diastereoselective epoxidation of oxazolidine-substituted alkenes by dimethyldioxirane and m-chloroperbenzoic acid: pi-facial control through hydrogen bonding by the urea functionality. | Organic letters 20010111 |
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