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6737-42-4 | 1,3-Bis(diphenylphosphino)propane
CAS No: 6737-42-4 Catalog No: AG0032LA MDL No:MFCD00003050
Product Description
Catalog Number:
AG0032LA
Chemical Name:
1,3-Bis(diphenylphosphino)propane
CAS Number:
6737-42-4
Molecular Formula:
C27H26P2
Molecular Weight:
412.4429
MDL Number:
MFCD00003050
IUPAC Name:
3-diphenylphosphanylpropyl(diphenyl)phosphane
InChI:
InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChI Key:
LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES:
C(CP(c1ccccc1)c1ccccc1)CP(c1ccccc1)c1ccccc1
EC Number:
229-791-2
UNII:
44R56E2C68
NSC Number:
193753
Properties
Complexity:
350
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
412.151g/mol
Formal Charge:
0
Heavy Atom Count:
29
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
412.453g/mol
Monoisotopic Mass:
412.151g/mol
Rotatable Bond Count:
8
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
6.2
Literature
| Title | Journal |
|---|---|
| Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III). | Acta crystallographica. Section E, Structure reports online 20120701 |
| Charge retention by gold clusters on surfaces prepared using soft landing of mass selected ions. | ACS nano 20120124 |
| A selective intramolecular 5-exo-dig or 6-endo-dig cyclization en route to 2-furanone or 2-pyrone containing tricyclic scaffolds. | The Journal of organic chemistry 20111202 |
| [1,3-Bis(diphenyl-phosphan-yl)propane-κP,P'](1,10-phenanthroline-κN,N')copper(I) perchlorate. | Acta crystallographica. Section E, Structure reports online 20111201 |
| Synthesis of functionalized cinnamaldehyde derivatives by an oxidative Heck reaction and their use as starting materials for preparation of Mycobacterium tuberculosis 1-deoxy-D-xylulose-5-phosphate reductoisomerase inhibitors. | The Journal of organic chemistry 20111104 |
| Poly[bis-[μ-1,3-bis-(diphenyl-phosphan-yl)propane-κP:P']-di-μ-thio-cyanato-κS:N;κN:S-disilver(I)]. | Acta crystallographica. Section E, Structure reports online 20111101 |
| Reaction mechanism governing formation of 1,3-bis(diphenylphosphino)propane-protected gold nanoclusters. | Inorganic chemistry 20111017 |
| Preparation of η2-complexes of fullerenes by reduction. Crystal structure and optical properties of {Ni(dppp)·(η2-C70)}·(C6H4Cl2)0.5. | Dalton transactions (Cambridge, England : 2003) 20110928 |
| catena-Poly[[[μ-1,3-bis(diphenylphosphanyl)propane-κ2P:P'][O-ethyl (4-methoxyphenyl)phosphonodithioato-κ2S,S']silver(I)] chloroform monosolvate]. | Acta crystallographica. Section C, Crystal structure communications 20110901 |
| Multimetallic complexes of group 10 and 11 metals based on polydentate dithiocarbamate ligands. | Dalton transactions (Cambridge, England : 2003) 20110614 |
| Nickel-catalyzed cross-coupling of phenols and arylboronic acids through an in situ phenol activation mediated by PyBroP. | Chemistry (Weinheim an der Bergstrasse, Germany) 20110328 |
| Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands. | Dalton transactions (Cambridge, England : 2003) 20110121 |
| Diversity-oriented synthesis based on the DPPP-catalyzed mixed double-Michael reactions of electron-deficient acetylenes and β-amino alcohols. | Molecules (Basel, Switzerland) 20110101 |
| Synthesis and spectrosopic identification of hybrid 3-(triethoxysilyl)propylamine phosphine ruthenium(II) complexes. | Molecules (Basel, Switzerland) 20100517 |
| Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers. | Organic & biomolecular chemistry 20100507 |
| Synthesis, characterization and cytotoxic activities of the [RuCl2(NO)(dppp)(L)]PF6 complexes. | Journal of inorganic biochemistry 20100501 |
| Diphosphine-catalyzed mixed double-Michael reaction: a unified synthesis of indolines, dihydropyrrolopyridines, benzimidazolines, tetrahydroquinolines, tetrahydroisoquinolines, dihydrobenzo-1,4-oxazines, and dihydrobenzo-3,1-oxazines. | Organic letters 20100305 |
| Tertiary carbinamine synthesis by rhodium-catalyzed [3+2] annulation of N-unsubstituted aromatic ketimines and alkynes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20100222 |
| Sterically-directed consecutive and size-selective self-assembly of palladium diphosphane complexes with an Ar-BIAN ligand: unexpected formation of pentameric and hexameric aggregates. | Chemistry (Weinheim an der Bergstrasse, Germany) 20091012 |
| Externally initiated regioregular P3HT with controlled molecular weight and narrow polydispersity. | Journal of the American Chemical Society 20090916 |
| Aromatic C-F activation by complexes containing the {Pt2S2} core via nucleophilic substitution: a combined experimental and theoretical study. | Dalton transactions (Cambridge, England : 2003) 20090814 |
| Regioselective Heck vinylation of electron-rich olefins with vinyl halides: is the neutral pathway in operation? | The Journal of organic chemistry 20090403 |
| Iron-catalysed Negishi coupling of benzyl halides and phosphates. | Chemical communications (Cambridge, England) 20090207 |
| Mechanistic insights into the rhodium-catalyzed intramolecular ketone hydroacylation. | Journal of the American Chemical Society 20090128 |
| Characterization of self-assembled metallodendrimers in solution, in the gas phase, and at air/solid interfaces. | Small (Weinheim an der Bergstrasse, Germany) 20081001 |
| [1,3-Bis(diphenyl-phosphino)propane-κP,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate. | Acta crystallographica. Section E, Structure reports online 20081001 |
| Metallo-supramolecular self-assembly: the case of triangle-square equilibria. | Inorganic chemistry 20080901 |
| Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV). | Acta crystallographica. Section E, Structure reports online 20080501 |
| Reaction chemistry of complexes containing Pt--H, Pt--SH, or Pt--S fragments: from their apparent simplicity to the maze of reactions underlying their interconversion. | Chemistry (Weinheim an der Bergstrasse, Germany) 20070101 |
| Development of potential manufacturing routes for substituted thiophenes--preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-dihaloaryl 1,2,4-triazole insecticides. | Beilstein journal of organic chemistry 20070101 |
| Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid. | Chemical communications (Cambridge, England) 20060914 |
| Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2. | Journal of the American Chemical Society 20060712 |
| Structural variations and spectroscopic properties of luminescent mono- and multinuclear silver(I) and copper(I) complexes bearing phosphine and cyanide ligands. | Inorganic chemistry 20050307 |
| Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions. | Chemistry (Weinheim an der Bergstrasse, Germany) 20041105 |
| Self-assembly of flexible supramolecular metallacyclic ensembles: structures and adsorption properties of their nanoporous crystalline frameworks. | Journal of the American Chemical Society 20040901 |
| Palladium-catalyzed alkylation of vinyl oxiranes with substituted allenes. Direct access to bifunctionalized allylic alcohols. | The Journal of organic chemistry 20040709 |
| Hydrosilylation of alkynes with a cationic rhodium species formed in an anionic micellar system. | Organic letters 20040624 |
| Facile palladium-catalysed synthesis of 1-aryl-1H-indazoles from 2-bromobenzaldehydes and arylhydrazines. | Chemical communications (Cambridge, England) 20040107 |
| Square-planar coordinated polyanions of palladium, platinum, and gold stannaborate [SnB11H11]2- coordination chemistry. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030922 |
| A new regioselective Heck vinylation with enamides. Synthesis and investigation of fluorous-tagged bidentate ligands for fast separation. | The Journal of organic chemistry 20030822 |
| A novel palladium-catalyzed synthesis of 1,2-dihydroquinoxalines and 3,4-dihydroquinoxalinones. | Organic letters 20020418 |
| Gold(I) macrocycles and topologically chiral [2]catenanes. | Journal of the American Chemical Society 20020417 |
| Aryl-aryl coupling reaction using a novel and highly active palladium reagent prepared from Pd(OAc)2, 1,3-bis[diphenylphosphino]propane (DPPP), and Bu3P. | Chemical & pharmaceutical bulletin 20020401 |
| [Bis(diphenylphosphino)methane][1,3-bis(diphenylphosphino)propane]platinum(II) dibromide. | Acta crystallographica. Section C, Crystal structure communications 20011101 |
| A meso-helical coordination polymer from achiral dinuclear [Cu2(H3CCN)2(micro-pydz)3][PF6]2 and 1,3-bis(diphenylphosphanyl)propane-synthesis and crystal structure of 1 to infinity Cu(mu-pydz)2][PF6 (pydz=pyridazine). | Chemistry (Weinheim an der Bergstrasse, Germany) 20010917 |
| Iridium-catalyzed transfer hydrogenation of alpha,beta-unsaturated and saturated carbonyl compounds with 2-propanol. | The Journal of organic chemistry 20010629 |
| Heterobimetallic, cubane-like Mo(3)S(4)M' cluster cores containing the noble metals M' = Ru, Os, Rh, Ir. Unprecedented tri(mu-carbonyl) bridge between ruthenium atoms in [(eta(5)-Cp')(3)Mo(3)S(4)Ru)2(mu-CO)3]2+. | Inorganic chemistry 20010618 |
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