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64297-64-9 | 2-Iodylbenzoic acid
CAS No: 64297-64-9 Catalog No: AG00E8TH MDL No:MFCD00024166
Product Description
Catalog Number:
AG00E8TH
Chemical Name:
2-Iodylbenzoic acid
CAS Number:
64297-64-9
MDL Number:
MFCD00024166
IUPAC Name:
2-iodylbenzoic acid
InChI:
InChI=1S/C7H5IO4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)
InChI Key:
FIYYMXYOBLWYQO-UHFFFAOYSA-N
EC Number:
264-773-8
Properties
Complexity:
232
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
279.923g/mol
Formal Charge:
0
Heavy Atom Count:
12
Hydrogen Bond Acceptor Count:
4
Hydrogen Bond Donor Count:
1
Isotope Atom Count:
0
Molecular Weight:
280.017g/mol
Monoisotopic Mass:
279.923g/mol
Rotatable Bond Count:
1
Topological Polar Surface Area:
71.4A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.6
Literature
| Title | Journal |
|---|---|
| o-Iodoxybenzoic acid mediated oxidative desulfurization initiated domino reactions for synthesis of azoles. | The Journal of organic chemistry 20120420 |
| Nitromethane with IBX/TBAF as a nitrosating agent: synthesis of nitrosamines from secondary or tertiary amines under mild conditions. | The Journal of organic chemistry 20120106 |
| High-yielding oxidation of β-hydroxyketones to β-diketones using o-iodoxybenzoic acid. | The Journal of organic chemistry 20111202 |
| Regioselective oxidation of cholic acid and its 7β epimer by using o-iodoxybenzoic acid. | Steroids 20111101 |
| An effective and catalytic oxidation using recyclable fluorous IBX. | Chemical communications (Cambridge, England) 20110214 |
| Room-temperature aromatization of tetrahydro-β-carbolines by 2-iodoxybenzoic acid: utility in a total synthesis of eudistomin U. | Organic letters 20100917 |
| New lipophilic piceatannol derivatives exhibiting antioxidant activity prepared by aromatic hydroxylation with 2-iodoxybenzoic acid (IBX). | Molecules (Basel, Switzerland) 20091117 |
| A selective de-O-methylation of guaiacyl lignans to corresponding catechol derivatives by 2-iodoxybenzoic acid (IBX). The role of the catechol moiety on the toxicity of lignans. | Organic & biomolecular chemistry 20090607 |
| A direct and efficient total synthesis of the tubulin-binding agents ceratamine A and B; use of IBX for a remarkable heterocycle dehydrogenation. | Organic letters 20090521 |
| Oxidation of the primary hydroxyl group of galactose of galactaosyl ceramide analogue by chemical method-precursors for the synthesis of labeled conjugates. | Carbohydrate research 20090310 |
| Oxidative conversion of alpha,alpha-disubstituted acetamides to corresponding one-carbon-shorter ketones using hypervalent iodine (lambda5) reagents in combination with tetraethylammonium bromide. | The Journal of organic chemistry 20081205 |
| Total synthesis of wasabidienones B1 and B0 via SIBX-mediated hydroxylative phenol dearomatization. | Organic letters 20081120 |
| Convenient synthesis of hydroxytyrosol and its lipophilic derivatives from tyrosol or homovanillyl alcohol. | Journal of agricultural and food chemistry 20081008 |
| One-pot three-component synthesis of alpha-iminonitriles by IBX/TBAB-mediated oxidative Strecker reaction. | Organic letters 20080417 |
| The effect of papaverine on ion channels in rat basilar smooth muscle cells. | Neurological research 20070901 |
| Efficient access to orthoquinols and their [4 + 2] cyclodimers via SIBX-mediated hydroxylative phenol dearomatization. | The Journal of organic chemistry 20070803 |
| o-Iodoxybenzoic acid- and tetraethylammonium bromide-mediated oxidative transformation of primary carboxamides to one-carbon dehomologated nitriles. | The Journal of organic chemistry 20070119 |
| Neuregulin-1 isoform induces mitogenesis, KCa and Ca2+ currents in PC12 cells. A comparison with sciatic nerve conditioned medium. | Brain research 20060919 |
| Esters of 2-iodoxybenzoic acid: hypervalent iodine oxidizing reagents with a pseudobenziodoxole structure. | The Journal of organic chemistry 20050805 |
| Synthesis of the catechols of natural and synthetic estrogens by using 2-iodoxybenzoic acid (IBX) as the oxidizing agent. | Steroids 20050301 |
| Oxidative dearomatization of phenols and anilines via lambda(3)- and lambda(5)-iodane-mediated phenylation and oxygenation. | Molecules (Basel, Switzerland) 20050131 |
| o-Iodoxybenzoic acid (IBX) as a viable reagent in the manipulation of nitrogen- and sulfur-containing substrates: scope, generality, and mechanism of IBX-mediated amine oxidations and dithiane deprotections. | Journal of the American Chemical Society 20040428 |
| The modulation of action potential generation by calcium-induced calcium release is enhanced by mitochondrial inhibitors in mudpuppy parasympathetic neurons. | Neuroscience 20040101 |
| New reactions of IBX: oxidation of nitrogen- and sulfur-containing substrates to afford useful synthetic intermediates. | Angewandte Chemie (International ed. in English) 20030905 |
| Mild oxidation of alcohols with o-iodoxybenzoic acid (IBX) in water/acetone mixture in the presence of beta-cyclodextrin. | The Journal of organic chemistry 20030307 |
| A simple and advantageous protocol for the oxidation of alcohols with O-iodoxybenzoic acid (IBX). | Organic letters 20020822 |
| Facile cleavage of triethylsilyl (TES) ethers using o-iodoxybenzoic acid (IBX) without affecting tert-butyldimethylsilyl (TBS) ethers. | Organic letters 20020627 |
| Iodine(V) reagents in organic synthesis. Part 3. New routes to heterocyclic compounds via o-iodoxybenzoic acid-mediated cyclizations: generality, scope, and mechanism. | Journal of the American Chemical Society 20020313 |
| Iodine(V) reagents in organic synthesis. Part 4. o-Iodoxybenzoic acid as a chemospecific tool for single electron transfer-based oxidation processes. | Journal of the American Chemical Society 20020313 |
| Regioselective oxidation of phenols to o-quinones with o-iodoxybenzoic acid (IBX). | Organic letters 20020124 |
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