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54773-18-1

54773-18-1 | 2-[(E)-Phenylazo]pyridine

CAS No: 54773-18-1 Catalog No: AG00DSX9 MDL No:

Product Description

Catalog Number:
AG00DSX9
Chemical Name:
2-[(E)-Phenylazo]pyridine
CAS Number:
54773-18-1
IUPAC Name:
phenyl(pyridin-2-yl)diazene
InChI:
InChI=1S/C11H9N3/c1-2-6-10(7-3-1)13-14-11-8-4-5-9-12-11/h1-9H
InChI Key:
QWLSHZKQRSNZKL-UHFFFAOYSA-N

Properties

Complexity:
185  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
183.08g/mol
Formal Charge:
0
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
3  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
183.214g/mol
Monoisotopic Mass:
183.08g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
37.6A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
3  

Literature

Title Journal
Photoactive azoimine dyes: 4-(2-pyridylazo)-N,N-diethylaniline and 4-(2-pyridylazo)-N,N-dimethylaniline: computational and experimental investigation. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120201
Ruthenium nitrosyl complexes with 1,4,7-trithiacyclononane and 2,2'-bipyridine (bpy) or 2-phenylazopyridine (pap) coligands. Electronic structure and reactivity aspects. Dalton transactions (Cambridge, England : 2003) 20111214
Isomeric separation in donor-acceptor systems of Pd(II) and Pt(II) and a combined structural, electrochemical and spectroelectrochemical study. Dalton transactions (Cambridge, England : 2003) 20111014
Oxidation state analysis of a four-component redox series [Os(pap)2(Q)]n involving two different non-innocent ligands on a redox-active transition metal. Inorganic chemistry 20110801
Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazen-yl]aniline}zinc. Acta crystallographica. Section E, Structure reports online 20110701
N,N-Dimethyl-4-[(2-pyrid-yl)diazen-yl]aniline. Acta crystallographica. Section E, Structure reports online 20100801
Redox induced electron transfer in doublet azo-anion diradical rhenium(II) complexes. Characterization of complete electron transfer series. Inorganic chemistry 20100315
Photoisomerization and thermal isomerization of shuttlecock- and bowl-equipped (phenylazo)pyridines. The journal of physical chemistry. A 20100121
Sensitive valence structures of [(pap)(2)Ru(Q)](n) (n = +2, +1, 0, -1, -2) with two different redox noninnocent ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap = 2-phenylazopyridine. Inorganic chemistry 20091019
Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q = 3,5-di-tert-butyl-benzoquinone. Dalton transactions (Cambridge, England : 2003) 20090628
Ruthenium polypyridyl complexes and their modes of interaction with DNA: is there a correlation between these interactions and the antitumor activity of the compounds? Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20090301
The synthesis, chemical and biological properties of dichlorido(azpy)gold(III) chloride (azpy=2-(phenylazo)pyridine) and the gold-induced conversion of the azpy ligand to the chloride of the novel tricyclic pyrido[2,1-c][1,2,4]benzotriazin-11-ium cation. Journal of inorganic biochemistry 20071101
Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A2Ru(mu-L)RuA2]n, A = 2,4-pentanedionato or 2-phenylazopyridine, L(2-) = 2,5-bis(2-oxidophenyl)pyrazine. Dalton transactions (Cambridge, England : 2003) 20070621
Interaction of 2-aminopyrimidine with dichloro-[I-alkyl-2-(naphthylazo) imidazole]palladium(II) complexes: kinetic and mechanistic studies. Chemistry Central journal 20070101
Phenylazo-pyridine and phenylazo-pyrazole chlorido ruthenium(II) arene complexes: arene loss, aquation, and cancer cell cytotoxicity. Inorganic chemistry 20061225
Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine. Chemistry (Weinheim an der Bergstrasse, Germany) 20051223
Ligands rock & roll: stepwise twisting of two cis-coordinated lopsided N-heterocycles in an octahedral bis(2-phenylazopyridine)-ruthenium(II) complex with seven atropisomers. Chemistry (Weinheim an der Bergstrasse, Germany) 20050204
Coordination of 9-ethylguanine to the mixed-ligand compound alpha-[Ru(azpy)(bpy)Cl2] (azpy = 2-phenylazopyridine and bpy = 2,2'-bipyridine). An unprecedented ligand positional shift, correlated to the cytotoxicity of this type of [RuL2Cl2] (with L = azpy or bpy) complex. Inorganic chemistry 20040809
Structure-dependent in vitro cytotoxicity of the isomeric complexes [Ru(L)2Cl2] (L= o-tolylazopyridine and 4-methyl-2-phenylazopyridine) in comparison to [Ru(azpy)2Cl2]. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20040401
Dichlorobis(2-phenylazopyridine)ruthenium(II) complexes: characterisation, spectroscopic and structural properties of four isomers. Dalton transactions (Cambridge, England : 2003) 20040207
Crystal structure of bromo(2,2':6',2'-terpyridine)(2-(phenylazo)-pyridine)ruthenium(II) tetrafluoroborate. Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20030601
New cytotoxic and water-soluble bis(2-phenylazopyridine)ruthenium(II) complexes. Journal of medicinal chemistry 20030424
Non-covalent switch for intramolecular energy transfer. Chemical communications (Cambridge, England) 20030307
Ruthenium complexes of 2-[(4-(arylamino)phenyl)azo]pyridine formed via regioselective phenyl ring amination of coordinated 2-(phenylazo)pyridine: isolation of products, X-ray structure, and redox and optical properties. Inorganic chemistry 20030113
Metal-promoted aromatic ring amination and deamination reactions at a diazo ligand coordinated to rhodium and ruthenium. Inorganic chemistry 20021230
Chromium complexes of an isomeric N-donor ligand, 2-[(N-arylamino)phenylazo]pyridine: amination reactions, X-ray structure, and redox properties. Inorganic chemistry 20020826

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