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53597-69-6 | 1,3,5-Triaza-7-phosphaadamantane
CAS No: 53597-69-6 Catalog No: AG003DGD MDL No:MFCD00154905
Product Description
Catalog Number:
AG003DGD
Chemical Name:
1,3,5-Triaza-7-phosphaadamantane
CAS Number:
53597-69-6
Molecular Formula:
C6H12N3P
Molecular Weight:
157.1533
MDL Number:
MFCD00154905
IUPAC Name:
1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane
InChI:
InChI=1S/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2
InChI Key:
FXXRPTKTLVHPAR-UHFFFAOYSA-N
SMILES:
C1N2CN3CN1CP(C2)C3
NSC Number:
266642
Properties
Complexity:
123
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
157.077g/mol
Formal Charge:
0
Heavy Atom Count:
10
Hydrogen Bond Acceptor Count:
3
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
157.157g/mol
Monoisotopic Mass:
157.077g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
9.7A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0
Literature
| Title | Journal |
|---|---|
| Long-chain cationic derivatives of PTA (1,3,5-triaza-7-phosphaadamantane) as new components of potential non-viral vectors. | International journal of pharmaceutics 20120715 |
| Cellular delivery of pyrenyl-arene ruthenium complexes by a water-soluble arene ruthenium metalla-cage. | Dalton transactions (Cambridge, England : 2003) 20120628 |
| Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties. | Dalton transactions (Cambridge, England : 2003) 20111107 |
| Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes. | Inorganic chemistry 20111107 |
| The Suzuki reaction in aqueous media promoted by P, N ligands. | Molecules (Basel, Switzerland) 20110725 |
| Organometallic ruthenium(II) arene compounds with antiangiogenic activity. | Journal of medicinal chemistry 20110609 |
| Synthesis, structures and in vitro cytotoxicity of some cationic cis-platinum(II) complexes containing chelating thiocarbamates. | Journal of inorganic biochemistry 20110301 |
| Water-soluble Cp ruthenium complex containing 1,3,5-triaza-7-phosphaadamantane and 8-thiotheophylline derivatives: synthesis, characterization, and antiproliferative activity. | Inorganic chemistry 20110207 |
| In vitro antitumour activity of water soluble Cu(I), Ag(I) and Au(I) complexes supported by hydrophilic alkyl phosphine ligands. | Journal of inorganic biochemistry 20110201 |
| Copper and its complexes in medicine: a biochemical approach. | Molecular biology international 20110101 |
| Antitumor activity of new hydridotris(pyrazolyl)borate ruthenium(II) complexes containing the phosphanes PTA and 1-CH3-PTA. | Dalton transactions (Cambridge, England : 2003) 20101114 |
| Iron(II) and ruthenium(II) complexes containing P, N, and H ligands: structure, spectroscopy, electrochemistry, and reactivity. | Inorganic chemistry 20101018 |
| Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA. | Dalton transactions (Cambridge, England : 2003) 20100414 |
| Electronic and geometric effects of phosphatriazaadamantane ligands on the catalytic activity of an [FeFe] hydrogenase inspired complex. | Dalton transactions (Cambridge, England : 2003) 20100328 |
| Anticancer therapeutics that target selenoenzymes: synthesis, characterization, in vitro cytotoxicity, and thioredoxin reductase inhibition of a series of gold(I) complexes containing hydrophilic phosphine ligands. | ChemMedChem 20100101 |
| Excellent correlation between cathepsin B inhibition and cytotoxicity for a series of palladacycles. | Dalton transactions (Cambridge, England : 2003) 20091228 |
| An organometallic approach for the synthesis of water-soluble ruthenium and platinum nanoparticles. | Dalton transactions (Cambridge, England : 2003) 20091214 |
| Synthesis and structural characterization of copper(I) complexes bearing N-methyl-1,3,5-triaza-7-phosphaadamantane (mPTA): cytotoxic activity evaluation of a series of water soluble Cu(I) derivatives containing PTA, PTAH and mPTA ligands. | Journal of inorganic biochemistry 20091201 |
| Intramolecular hydrogen-bonded tertiary phosphines as 1,3,5-triaza-7-phosphaadamantane (PTA) analogues. | Inorganic chemistry 20090316 |
| Facile modification of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1(3,7)]decane phosphanes coordinated to ruthenium(II). | Inorganic chemistry 20090316 |
| Laser spectroscopy for atmospheric and environmental sensing. | Sensors (Basel, Switzerland) 20090101 |
| New water-soluble azido- and derived tetrazolato-platinum(II) complexes with PTA. Easy metal-mediated synthesis and isolation of 5-substituted tetrazoles. | Dalton transactions (Cambridge, England : 2003) 20081214 |
| Complexes of the [Re(6)(mu(3)-Se)(8)](2+) core-containing clusters with the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) ligand: unexpected ligand protonation and related studies. | Dalton transactions (Cambridge, England : 2003) 20081121 |
| Cu(I) complexes bearing the new sterically demanding and coordination flexible tris(3-phenyl-1-pyrazolyl)methanesulfonate ligand and the water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane or related ligands. | Inorganic chemistry 20081103 |
| The ruthenium(II)-arene compound RAPTA-C induces apoptosis in EAC cells through mitochondrial and p53-JNK pathways. | Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20080901 |
| DNA structural distortions induced by ruthenium-arene anticancer compounds. | Journal of the American Chemical Society 20080820 |
| Synthesis, characterization, and in vitro cytotoxicity of some gold(I) and trans platinum(II) thionate complexes containing water-soluble PTA and DAPTA ligands. X-ray crystal structures of [Au(SC4H3N2)(PTA)], trans-[Pt(SC4H3N2)2(PTA)2], trans-[Pt(SC5H4N)2(PTA)2], and trans-[Pt(SC5H4N)2(DAPTA)2]. | Inorganic chemistry 20080707 |
| Three-dimensional hydrogen-bonded supra-molecular assembly in tetrakis-(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexa-hydrate. | Acta crystallographica. Section E, Structure reports online 20080501 |
| Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: first examples of co-PTA complexes and of a metal complex with the PTA oxide ligand. | Inorganic chemistry 20080421 |
| 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane tetra-fluoro-borate. | Acta crystallographica. Section E, Structure reports online 20080301 |
| Synthesis, in vitro and in vivo characterization of (64)Cu(I) complexes derived from hydrophilic tris(hydroxymethyl)phosphane and 1,3,5-triaza-7-phosphaadamantane ligands. | Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20080201 |
| 1-Methyl-1-azonia-3,5-diaza-7-phospha-tricyclo-[3.3.1.1]decane 7-oxide triiodide. | Acta crystallographica. Section E, Structure reports online 20080201 |
| Insertion of CO2, ketones, and aldehydes into the C-Li bond of 1,3,5-triaza-7-phosphaadamantan-6-yllithium. | Inorganic chemistry 20080121 |
| Diastereomerically enriched analogues of the water-soluble phosphine PTA. Synthesis of phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.1(3,7)]dec-6-yl)methanol (PZA) and the sulfide PZA(S) and X-ray crystal structures of the oxide PZA(O) and [Cp*IrCl(2)(PZA)]. | Inorganic chemistry 20080107 |
| Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N2)(PTA-H)n(PTA)4-n]n+ (n = 0-4), the first with 1,3,5-triaza-7-phosphaadamantane. | Dalton transactions (Cambridge, England : 2003) 20080107 |
| Development of a series of P(CH(2)N=CHR)(3) and trisubstituted 1,3,5-Triaza-7-phosphaadamantane ligands. | Inorganic chemistry 20071224 |
| Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy. | Dalton transactions (Cambridge, England : 2003) 20071121 |
| Isomerization of trans-[Ru(PTA)4Cl2] to cis-[Ru(PTA)4Cl2] in water and organic solvent: revisiting the chemistry of [Ru(PTA)4Cl2]. | Inorganic chemistry 20070820 |
| Phosphinic platinum complexes with 8-thiotheophylline derivatives: synthesis, characterization, and antiproliferative activity. | Inorganic chemistry 20070514 |
| Synthesis and coordination chemistry of a novel bidentate phosphine: 6-(diphenylphosphino)-1,3,5-triaza-7-phosphaadamantane (PTA-PPh2). | Inorganic chemistry 20060821 |
| Manganese complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): the first nitrogen-bound transition-metal complex of PTA. | Inorganic chemistry 20060501 |
| Synthesis, characterization, and DNA binding of new water-soluble cyclopentadienyl ruthenium(II) complexes incorporating phosphines. | Inorganic chemistry 20060206 |
| In vitro and in vivo evaluation of ruthenium(II)-arene PTA complexes. | Journal of medicinal chemistry 20050616 |
| The hydrophilic phosphatriazaadamantane ligand in the development of H2 production electrocatalysts: iron hydrogenase model complexes. | Journal of the American Chemical Society 20040929 |
| Reactions of [Ru(H(2)O)(6)](2+) with water-soluble tertiary phosphines. | Dalton transactions (Cambridge, England : 2003) 20040807 |
| cis-Diphenylbis(1,3,5-triaza-7-phosphaadamantane-kappaP)platinum(II). | Acta crystallographica. Section C, Crystal structure communications 20040601 |
| Synthesis and structures of nickel and palladium salicylaldiminato 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. | Inorganic chemistry 20031020 |
| Trans-bis(3,5-diaza-1-azonia-7-phosphaadamantane-kappaP)bis(thiocyanato-kappaS)palladium(II) bis(thiocyanate). | Acta crystallographica. Section C, Crystal structure communications 20030901 |
| Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane). | Chemical communications (Cambridge, England) 20030121 |
| Syntheses, structure, and photoluminescence properties of the 1-dimensional chain compounds [(TPA)(2)Au][Au(CN)(2)] and (TPA)AuCl (TPA = 1,3,5-triaza-7-phosphaadamantane). | Inorganic chemistry 20021202 |
| trans-Diiodobis(1,3,5-triaza-7-phosphaadamantane)platinum(II). | Acta crystallographica. Section C, Crystal structure communications 20010501 |
| Synthesis and characterization of iridium 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. X-ray crystal and molecular structures of [Ir(PTA)4(CO)]Cl and [Ir(PTAH)3(PTAH2)(H)2]Cl6. | Inorganic chemistry 20010129 |
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