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25005-97-4 | Pyrazine, 2,3,5,6-tetra-2-pyridinyl-
CAS No: 25005-97-4 Catalog No: AG002Q5V MDL No:
Product Description
Catalog Number:
AG002Q5V
Chemical Name:
Pyrazine, 2,3,5,6-tetra-2-pyridinyl-
CAS Number:
25005-97-4
Molecular Formula:
C24H16N6
Molecular Weight:
388.4240
IUPAC Name:
2,3,5,6-tetrapyridin-2-ylpyrazine
InChI:
InChI=1S/C24H16N6/c1-5-13-25-17(9-1)21-22(18-10-2-6-14-26-18)30-24(20-12-4-8-16-28-20)23(29-21)19-11-3-7-15-27-19/h1-16H
InChI Key:
UOJZYBFRNITHCX-UHFFFAOYSA-N
SMILES:
c1ccc(nc1)c1nc(c2ccccn2)c(nc1c1ccccn1)c1ccccn1
Properties
Complexity:
440
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
388.144g/mol
Formal Charge:
0
Heavy Atom Count:
30
Hydrogen Bond Acceptor Count:
6
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
388.434g/mol
Monoisotopic Mass:
388.144g/mol
Rotatable Bond Count:
4
Topological Polar Surface Area:
77.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
2.3
Literature
| Title | Journal |
|---|---|
| Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(μ-tppz)Ru(L)Cl]+, L = β-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. | Dalton transactions (Cambridge, England : 2003) 20121121 |
| Natural analcime zeolite modified with 2,3,5,6-tetra(2-pyridyl)pyrazine for preconcentration and determination of trace amounts of cadmium by flame atomic absorption spectrometry. | Toxicology and industrial health 20121001 |
| Diaqua-iodido(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)manganese(II) iodide monohydrate. | Acta crystallographica. Section E, Structure reports online 20111001 |
| 2,5-Bis(pyridinium-2-yl)-3,6-bis-(2-pyrid-yl)pyrazine bis-[tetra-chlorido-aurate(III)]. | Acta crystallographica. Section E, Structure reports online 20111001 |
| Bis(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)nickel(II) dithio-cyanate dihydrate. | Acta crystallographica. Section E, Structure reports online 20110101 |
| Diiodido(2,3,5,6-tetrapyridin-2-yl-pyrazine-κN,N,N)zinc(II). | Acta crystallographica. Section E, Structure reports online 20101201 |
| [μ-2,3,5,6-Tetra-kis(2-pyrid-yl)pyrazine-κN,N,N:N,N,N]bis-[diaqua(dihydrogen m-phenylene-diphospho-nato-κO)nickel(II)] dihydrate. | Acta crystallographica. Section E, Structure reports online 20101101 |
| Dibromido(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)zinc(II). | Acta crystallographica. Section E, Structure reports online 20100801 |
| Carboxylate tolerance of the redox-active platform [Ru(mu-tppz)Ru](n), where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine, in the electron-transfer series [(L)ClRu(mu-tppz)RuCl(L)](n), n = 2+, +, 0, -, 2-, with 2-picolinato, quinaldato, and 8-quinolinecarboxylato ligands (L(-)). | Inorganic chemistry 20100719 |
| Trinuclear nickel(II) complex through a 2,3,5,6-tetrakis(2-pyridyl)pyrazine ligand with a linear exchange pathway. | Inorganic chemistry 20100621 |
| Bis(2,3,5,6-tetra-2-pyridylpyrazine-κN,N,N)iron(II) bis-(dicyanamidate) 4.5-hydrate. | Acta crystallographica. Section E, Structure reports online 20100301 |
| Ligand-based modification of the structures and optical properties of new silver(I)-rhenate(VII) oxide/organic hybrid solids. | Inorganic chemistry 20091207 |
| Redox chemistry and electronic properties of 2,3,5,6-tetrakis(2-pyridyl)pyrazine-bridged diruthenium complexes controlled by N,C,N'-biscyclometalated ligands. | Inorganic chemistry 20090706 |
| A five-center redox system: molecular coupling of two noninnocent imino-o-benzoquinonato-ruthenium functions through a pi acceptor bridge. | Journal of the American Chemical Society 20090701 |
| Aqua-(dicyanamido-κN)(nitrato-κO,O')(2,3,5,6-tetra-2-pyridylpyrazine-κN,N,N)manganese(II). | Acta crystallographica. Section E, Structure reports online 20090101 |
| (Croconato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II). | Acta crystallographica. Section E, Structure reports online 20081201 |
| Proton dynamics and room-temperature ferroelectricity in anilate salts with a proton sponge. | Journal of the American Chemical Society 20081008 |
| μ-2,3,5,6-Tetra-2-pyridylpyrazine-κN,N,N:κN,N,N-bis-[(methanol-κO)(nitrato-κO,O')(nitrato-κO)cadmium(II)]. | Acta crystallographica. Section E, Structure reports online 20080801 |
| Synthesis and study of the spectroscopic and redox properties of Ru(II),Pt(II) mixed-metal complexes bridged by 2,3,5,6-tetrakis(2-pyridyl)pyrazine. | Inorganic chemistry 20080721 |
| Catalytic phenylborylation reaction by iridium(0) nanoparticles produced from hydridoiridium carborane. | Inorganic chemistry 20080707 |
| Molybdophosphonate clusters as building blocks in the oxomolybdate-organodiphosphonate/cobalt(II)-organoimine system: structural influences of secondary metal coordination preferences and diphosphonate tether lengths. | Inorganic chemistry 20080204 |
| OFF-OFF-ON switching of fluorescence and electron transfer depending on stepwise complex formation of a host ligand with guest metal ions. | Journal of the American Chemical Society 20080116 |
| An OFF-OFF-ON fluorescence sensor for metal ions in stepwise complex formation of 2,3,5,6-tetrakis(2-pyridyl)pyrazine with metal ions. | Journal of the American Chemical Society 20061220 |
| 2,2'-Dipyridylketone (dpk) as ancillary acceptor and reporter ligand in complexes [(dpk)(Cl)Ru(mu-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. | Inorganic chemistry 20060918 |
| Self-assembled multilayers of transition-metal-terpyridinyl complexes; formation, and characterization. | Langmuir : the ACS journal of surfaces and colloids 20060829 |
| Ytterbocene charge-transfer molecular wire complexes. | Journal of the American Chemical Society 20060607 |
| Synthesis and characterization of highly conjugated, chiral bridging ligands. | The Journal of organic chemistry 20041210 |
| Mono-, di- and trinuclear 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz)-containing copper(II) complexes: syntheses, crystal structures and magnetic properties. | Dalton transactions (Cambridge, England : 2003) 20041207 |
| Solid-state coordination chemistry of the oxomolybdate-organodiphosphonate/nickel-organoimine system: structural influences of the secondary metal coordination cation and diphosphonate tether lengths. | Inorganic chemistry 20041101 |
| Mixed valence aspects of diruthenium complexes [((L)ClRu)2(mu-tppz)]n+ incorporating 2-(2-pyridyl)azoles (L) as ancillary functions and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (Tppz) as bis-tridentate bridging ligand. | Inorganic chemistry 20040809 |
| Crystal structures and magnetic properties of 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz)-containing copper(II) complexes. | Inorganic chemistry 20031229 |
| Solid state coordination chemistry: one-, two-, and three-dimensional materials constructed from molybdophosphonate subunits linked through binuclear copper tetra-2-pyridylpyrazine groups. | Inorganic chemistry 20031020 |
| Toward new paradigms in mixed-valency: ytterbocene-terpyridine charge-transfer complexes. | Chemical communications (Cambridge, England) 20030921 |
| A building block approach to the synthesis of organic-inorganic oxide materials: the hydrothermal synthesis and network structure of [[Ni4(tpypyz)3][Mo5O15(O3PCH2CH2PO3)]2] x 23H2O (tpypyz = tetra-2-pyridylpyrazine). | Chemical communications (Cambridge, England) 20030907 |
| Direct measurement of excited-state intervalence transfer in [(tpy)Ru(III)(tppz(*-))Ru(II)(tpy)](4+) by time-resolved near-infrared spectroscopy. | Journal of the American Chemical Society 20020508 |
| The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal-organic derivatives of polyoxometalates: [(Cu(bpy)2)(Cu(bpy)(H2O))(Mo5O15)(O3P(CH2)4PO3)].H2O and [(u2(tpypyz)(H2O)2)(Mo5O15)(O3PCH2CH2PO3)].5.5H2O [bpy = 2,2'-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]. | Chemical communications (Cambridge, England) 20010921 |
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