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23582-03-8 | Phosphine, tris[2-(diphenylphosphino)ethyl]-
CAS No: 23582-03-8 Catalog No: AG002NQO MDL No:
Product Description
Catalog Number:
AG002NQO
Chemical Name:
Phosphine, tris[2-(diphenylphosphino)ethyl]-
CAS Number:
23582-03-8
Molecular Formula:
C42H42P4
Molecular Weight:
670.6779
IUPAC Name:
tris(2-diphenylphosphanylethyl)phosphane
InChI:
InChI=1S/C42H42P4/c1-7-19-37(20-8-1)44(38-21-9-2-10-22-38)34-31-43(32-35-45(39-23-11-3-12-24-39)40-25-13-4-14-26-40)33-36-46(41-27-15-5-16-28-41)42-29-17-6-18-30-42/h1-30H,31-36H2
InChI Key:
TVLNGWSWPKIYAO-UHFFFAOYSA-N
SMILES:
c1ccc(cc1)P(c1ccccc1)CCP(CCP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1
EC Number:
245-754-3
NSC Number:
164875
Properties
Complexity:
623
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
670.224g/mol
Formal Charge:
0
Heavy Atom Count:
46
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
670.693g/mol
Monoisotopic Mass:
670.224g/mol
Rotatable Bond Count:
15
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
8.4
Literature
| Title | Journal |
|---|---|
| Hydrogen storage and delivery: the carbon dioxide - formic acid couple. | Chimia 20110101 |
| Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium(II) and platinum(II) compounds. The X-ray crystal structure of two derivatives containing dangling phosphorus. | Dalton transactions (Cambridge, England : 2003) 20100307 |
| Novel chelate ring-opening induced by silver(I) of five-coordinate palladium(II) and platinum(II) complexes containing tripodal polyphosphines. | Inorganic chemistry 20080707 |
| Bis(1-{bis-[2-(diphenyl-phosphino-yl)eth-yl]phosphan-yl}-2-(diphenyl-phosphan-yl)ethane)dinitratoplatinum(II) methanol tetra-solvate. | Acta crystallographica. Section E, Structure reports online 20080701 |
| Gold(I) and silver(I) complexes containing a tripodal tetraphosphine ligand: influence of the halogen and stoichiometry on the properties. The X-ray crystal structure of two gold(I) dimeric aggregates. | Dalton transactions (Cambridge, England : 2003) 20080521 |
| Stereoselective preparation, structures, and reactivities of phosphine-bridged mixed-metal trinuclear and pentanuclear complexes with tris[2-(diphenylphosphino)ethyl]phosphine. | Inorganic chemistry 20060612 |
| Preparation and structural characterization of ionic five-coordinate palladium(II) and platinum(II) complexes of the ligand tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl(2) into M-Cl bonds (M = Pd, Pt) and hydroformylation activity of the Pt-SnCl(3) systems. | Inorganic chemistry 20020826 |
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