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Home > Other Heterocycles > 21810-44-6
21810-44-6 | Bicyclo[2.2.1]hept-1-ene
CAS No: 21810-44-6 Catalog No: AG006Z9G MDL No:
Product Description
Catalog Number:
AG006Z9G
Chemical Name:
Bicyclo[2.2.1]hept-1-ene
CAS Number:
21810-44-6
Molecular Formula:
C7H10
Molecular Weight:
94.1543
IUPAC Name:
bicyclo[2.2.1]hept-1-ene
InChI:
InChI=1S/C7H10/c1-2-7-4-3-6(1)5-7/h1,7H,2-5H2
InChI Key:
VGUXWSJVGWCTEC-UHFFFAOYSA-N
SMILES:
C1CC2=CCC1C2
Properties
Complexity:
111
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
94.078g/mol
Formal Charge:
0
Heavy Atom Count:
7
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
94.157g/mol
Monoisotopic Mass:
94.078g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
1
Undefined Bond Stereocenter Count:
0
XLogP3:
1.8
Literature
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| Regioselective ring-opening/cross-metathesis reactions of norbornene derivatives with electron-rich olefins. | Organic letters 20050106 |
| Tuning the hemolytic and antibacterial activities of amphiphilic polynorbornene derivatives. | Journal of the American Chemical Society 20041208 |
| On the addition of 4-(N,N-dimethylamino)phenyl cation to norbornene. | Organic & biomolecular chemistry 20041207 |
| Polynorbornene polycationic polymers as gene transfer agents. Influence of the counterion for in vitro transfection. | International journal of pharmaceutics 20041105 |
| Vinyl sulfoxides as stereochemical controllers in intermolecular Pauson-Khand reactions: applications to the enantioselective synthesis of natural cyclopentanoids. | Chemistry (Weinheim an der Bergstrasse, Germany) 20041025 |
| A ring-rearrangement metathesis approach toward the synthesis of cyclopenta- and cyclohexa[c]indene systems. | Organic letters 20041014 |
| Living copolymerization of ethylene with norbornene catalyzed by bis(pyrrolide-imine) titanium complexes with MAO. | Journal of the American Chemical Society 20040929 |
| Ruthenium(II) dipyridoquinoxaline-norbornene: synthesis, properties, crystal structure, and use as a ROMP monomer. | Inorganic chemistry 20040809 |
| Reversible disulfur monoxide (S2O)-forming retro-Diels-Alder reaction. disproportionation of S2O to trithio-ozone (S3) and sulfur dioxide (SO2) and reactivities of S2O and S3. | Journal of the American Chemical Society 20040728 |
| TiCl4-catalyzed intermolecular hydroamination reactions of norbornene. | Organic letters 20040722 |
| Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes. | Organic letters 20040722 |
| Enantiodivergent synthesis of pyrrolo[2,1-a]isoquinolines based on diastereoselective Parham cyclization and alpha-amidoalkylation reactions. | The Journal of organic chemistry 20040528 |
| Development of a monoclonal immunoassay selective for chlorinated cyclodiene insecticides. | Journal of agricultural and food chemistry 20040519 |
| Suspension ring-opening metathesis polymerization: the preparation of norbornene-based resins for application in organic synthesis. | The Journal of organic chemistry 20040514 |
| Reactions of Diels-Alder adducts of a sugar-derived dihydropyranone leading to fused polycyclic compounds. | Carbohydrate research 20040428 |
| Metallocene-catalyzed C7-linkage in the hydrooligomerization of norbornene by sigma-bond metathesis: insight into the microstructure of polynorbornene. | Angewandte Chemie (International ed. in English) 20040426 |
| Synthesis of polymer dielectric layers for organic thin film transistors via surface-initiated ring-opening metathesis polymerization. | Journal of the American Chemical Society 20040407 |
| Mechanism and activity of ruthenium olefin metathesis catalysts: the role of ligands and substrates from a theoretical perspective. | Journal of the American Chemical Society 20040324 |
| Biindanylidenes: role of central bond torsion in nonvertical triplet excitation transfer to the stilbenes. | Journal of the American Chemical Society 20031231 |
| Polymeric phosphine ligand from ring-opening metathesis polymerization of a norbornene derivative. Applications in the Heck, Sonogashira, and Negishi reactions. | The Journal of organic chemistry 20031212 |
| Hydrovinylation of norbornene. Ligand-dependent selectivity and asymmetric variations. | Organic letters 20031113 |
| Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. | Journal of the American Chemical Society 20031112 |
| Cine-substitution in the Stille coupling: evidence for the carbenoid reactivity of sp3-gem-organodimetallic iodopalladio-trialkylstannylalkane intermediates. | Journal of the American Chemical Society 20031022 |
| New catalyst design for polymerization of norbornene esters by reducing intramolecular interaction. | Journal of molecular modeling 20031001 |
| Solventless polymerization: spatial migration of a catalyst to form polymeric thin films in microchannels. | Journal of the American Chemical Society 20030806 |
| Formation of nanostructured polymer filaments in nanochannels. | Journal of the American Chemical Society 20030806 |
| A molecular mechanics and semiempirical molecular orbital study on the conformation of polynorbornene chains. | Journal of molecular modeling 20030801 |
| Pi-face-selective Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide and 1-imide and formation of 1,2-thiazetidines. | Journal of the American Chemical Society 20030709 |
| Synthesis of a hyaluronan neoglycopolymer by ring-opening metathesis polymerization. | Chemical communications (Cambridge, England) 20030707 |
| Highly efficient and selective epoxidation of alkenes by photochemical oxygenation sensitized by a ruthenium(II) porphyrin with water as both electron and oxygen donor. | Journal of the American Chemical Society 20030514 |
| Altering the allowed/forbidden gap in cyclobutene electrocyclic reactions: experimental and theoretical evaluations of the effect of planarity constraints. | Journal of the American Chemical Society 20030514 |
| Ethene/norbornene copolymerization with palladium(II) alpha-diimine catalysts: from ligand screening to discrete catalyst species. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030414 |
| Direct episulfidation of alkenes and allenes with elemental sulfur and thiiranes as sulfur sources, catalyzed by molybdenum oxo complexes. | Journal of the American Chemical Society 20030402 |
| Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization. | Chemical communications (Cambridge, England) 20030321 |
| Addition of the ortho-C-H bonds of phenol across an olefin catalysed by a chiral iridium(I) diphosphine complex. | Chemical communications (Cambridge, England) 20030321 |
| Towards a universal polymer backbone: design and synthesis of polymeric scaffolds containing terminal hydrogen-bonding recognition motifs at each repeating unit. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030217 |
| Aerobic oxidations catalyzed by chromium corroles. | Journal of the American Chemical Society 20030205 |
| The role of amine in the mechanism of pentathiepin (polysulfur) antitumor agents. | Journal of the American Chemical Society 20030115 |
| Ethene/norbornene copolymerization by [MeSi(3-(tert)BuCp) (N(tert)Bu)]TiCl2/MAO-catalyst. | Journal of Zhejiang University. Science 20030101 |
| [HIV-inhibiting activity of polyanion matrices and related substances containing adamantane and norbornene pharmacophores]. | Antibiotiki i khimioterapiia = Antibiotics and chemoterapy [sic] 20030101 |
| Preparation and functionalisation of emulsion-derived microcellular polymeric foams (polyHIPEs) by ring-opening metathesis polymerisation (ROMP). | Chemical communications (Cambridge, England) 20021207 |
| Planar transition structures in the epoxidation of alkenes. A DFT study on the reaction of peroxyformic acid with norbornene derivatives. | The Journal of organic chemistry 20021129 |
| A silica gel-supported ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane as recyclable catalyst for chemoselective oxidation of alcohols and alkenes by tert-butyl hydroperoxide. | The Journal of organic chemistry 20021101 |
| The 1-norbornene skeleton by carbene rearrangement. | Chemistry (Weinheim an der Bergstrasse, Germany) 20021004 |
| 'H/Vinyl' and 'Alkyl/Vinyl' conical intersections leading to carbene formation from the excited states of cyclohexene and norbornene. | Journal of the American Chemical Society 20020918 |
| 2-(exo-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-endo-yl)acetaldehyde 2,4-dinitrophenylhydrazone. | Acta crystallographica. Section C, Crystal structure communications 20020701 |
| Diastereoselective formation of indanes from arylboronate esters catalyzed by rhodium(I) in aqueous media. | Organic letters 20020613 |
| Palladium-catalyzed sequential alkylation-alkenylation reactions. Application to the synthesis of 2-substituted-4-benzoxepines and 2,5-disubstituted-4-benzoxepines. | The Journal of organic chemistry 20020531 |
| Cationic complexes of iridium: diiodobenzene chelation, electrophilic behavior with olefins, and fluxionality of an Ir(I) ethylene complex. | Inorganic chemistry 20020422 |
| New 2,N6-disubstituted adenosines: potent and selective A1 adenosine receptor agonists. | Bioorganic & medicinal chemistry 20020401 |
| Palladium-catalyzed sequential alkylation-alkenylation reactions and their application to the synthesis of fused aromatic rings. | The Journal of organic chemistry 20011130 |
| A novel palladium-catalyzed synthesis of phenanthrenes from ortho-substituted aryl iodides and diphenyl- or alkylphenylacetylenes. | Organic letters 20011115 |
| Mizoroki-Heck type reaction of organoboron reagents with alkenes and alkynes. A Pd(II)-catalyzed pathway with Cu(OAc)2 as an oxidant. | Organic letters 20011018 |
| Density functional study of the retrocyclization of norbornadiene and norbornene catalyzed by Fe(+). | Journal of the American Chemical Society 20010926 |
| Asymmetric Pauson-Khand reactions using camphor-derived chelating thiols as chiral controllers. | The Journal of organic chemistry 20010921 |
| The 2-norbornyl cation via the fragmentations of exo- and endo-2-norbornyloxychlorocarbenes: distinction without much difference. | Journal of the American Chemical Society 20010822 |
| [Challenges in chemistry: color reactions, cycloadditions and cycloreversions]. | Acta pharmaceutica Hungarica 20010801 |
| Electron ionisation induced fragmentation of fused norbornene analogues containing SiMe2 or GeMe2 and oxygen bridges. Migration of SiMe2 and GeMe2 groups. | Rapid communications in mass spectrometry : RCM 20010101 |
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