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CAS No: 18191-59-8 Catalog No: AG00237E MDL No:
Title | Journal |
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Total synthesis of the marine toxin phorboxazole A using palladium(II)-mediated intramolecular alkoxycarbonylation for tetrahydropyran synthesis. | Organic & biomolecular chemistry 20121021 |
Facile coupling of propargylic, allylic and benzylic alcohols with allylsilane and alkynylsilane, and their deoxygenation with Et3SiH, catalyzed by Bi(OTf)3 in [BMIM][BF4] ionic liquid (IL), with recycling and reuse of the IL. | Organic & biomolecular chemistry 20120928 |
Total synthesis of natural enantiomers of heliespirones A and C via the diastereoselective intramolecular Hosomi-Sakurai reaction. | The Journal of organic chemistry 20120921 |
Stereocontrolled asymmetric synthesis of syn-E-1,4-diol-2-enes using allyl boronates and its application in the total synthesis of solandelactone F. | Organic & biomolecular chemistry 20120307 |
Allylsilanes in 'tin-free' oximation, alkenylation, and allylation of alkyl halides. | Chemistry (Weinheim an der Bergstrasse, Germany) 20111202 |
Total synthesis of (+)-SCH 351448. | Organic letters 20110902 |
Enantioselective syntheses of syn- and anti-β-hydroxyallylsilanes via allene hydroboration-aldehyde allylboration reactions. | Organic letters 20110415 |
Flexible strategy for syntheses of spirooxindoles using palladium-catalyzed carbosilylation and Sakurai-type cyclization. | Organic letters 20110401 |
Palladium-catalyzed oxidative allylic C-H silylation. | Organic letters 20110401 |
Ring-closing metathesis of allylsilanes as a flexible strategy toward cyclic terpenes. short syntheses of teucladiol, isoteucladiol, poitediol, and dactylol and an attempted synthesis of caryophyllene. | The Journal of organic chemistry 20101015 |
Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands. | Journal of the American Chemical Society 20101013 |
Nitrile assisted, Brønsted acid catalyzed regio and stereoselective diarylphosphonylation of allyl silyl ethers. | Organic & biomolecular chemistry 20100807 |
Cobalt-catalyzed 1,4-hydrovinylation of allylsilane and allylboronic esters for the synthesis of hydroxy-functionalized 1,4-dienes. | The Journal of organic chemistry 20100806 |
On the [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione: an enantio- and diastereoselective synthesis of cis-1,3-diaminocyclitols. | The Journal of organic chemistry 20100702 |
Asymmetric synthesis of allylsilanes by the borylation of lithiated carbamates: formal total synthesis of (-)-decarestrictine D. | Angewandte Chemie (International ed. in English) 20100607 |
Platinum-catalyzed nucleophilic addition of vinylsilanes at the beta-position. | Organic letters 20091105 |
Ring-closing metathesis of allylsilanes/electrophilic desilylation to prepare exo-methylidenecycloalkanes. Short syntheses of teucladiol and poitediol. | Journal of the American Chemical Society 20091028 |
One-pot synthesis of lactams using domino reactions: combination of Schmidt reaction with Sakurai and aldol reactions. | The Journal of organic chemistry 20091016 |
Recent synthetic studies leading to structural revisions of marine natural products. | Marine drugs 20090901 |
Synthesis, structure, photoluminescence and photoreactivity of 2,3-diphenyl-4-neopentyl-1-silacyclobut-2-enes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090824 |
Rhenium-catalyzed insertion of nonpolar and polar unsaturated molecules into an olefinic C-H bond. | Organic letters 20090618 |
The domino multicomponent allylation reaction for the stereoselective synthesis of homoallylic alcohols. | Accounts of chemical research 20090217 |
Palladium-catalyzed, one-pot, three-component synthesis of homoallylic amines from aldehydes, anisidine, and allyl trifluoroacetate. | Organic letters 20090115 |
A very efficient cerium(IV) ammonium nitrate catalyzed, four-component synthesis of tetrahydropyridines and its application in the concise generation of functionalized homoquinolizine frameworks. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090101 |
Applications of chiral allylmetallating agents toward the synthesis of oxygen heterocyles. | Current opinion in drug discovery & development 20081101 |
Total synthesis and proof of relative stereochemistry of (-)-aureonitol. | The Journal of organic chemistry 20081003 |
Fluorous synthesis of allylic fluorides: C-F bond formation as the detagging process. | Chemical communications (Cambridge, England) 20080821 |
Highly stereoselective and modular syntheses of 10-hydroxytrilobacin and three diastereomers via stereodivergent [3 + 2]-annulation reactions. | Organic letters 20080807 |
Temporary silicon connection strategies in intramolecular allylation of aldehydes with allylsilanes. | The Journal of organic chemistry 20080718 |
Synthesis of allylsilanes and dienylsilanes by a one-pot catalytic C-H borylation--Suzuki-Miyaura coupling sequence. | Organic letters 20080717 |
Gold-catalysed intramolecular trans-allylsilylation of alkynes forming 3-allyl-1-silaindenes. | Chemical communications (Cambridge, England) 20080628 |
Synthesis, structure, and reactivity of naphthalyne-Co2(CO)6 complexes. | Journal of the American Chemical Society 20080521 |
Stereoselective one-pot, three-component synthesis of 4-amidotetrahydropyran. | The Journal of organic chemistry 20080215 |
Total synthesis of the indolizidine alkaloid tashiromine. | Beilstein journal of organic chemistry 20080101 |
Cinchona alkaloid catalyzed enantioselective fluorination of allyl silanes, silyl enol ethers, and oxindoles. | Angewandte Chemie (International ed. in English) 20080101 |
Lewis Acid promoted tandem intermolecular Diels-Alder/intramolecular allylation reactions of silyl-substituted 1,3-butadienes leading to multisubstituted 7-norbornenones and related polycyclic compounds. | Organic letters 20071220 |
Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide. | Organic letters 20071122 |
Nucleophilic substitution reactions of alcohols with use of montmorillonite catalysts as solid Brønsted acids. | The Journal of organic chemistry 20070803 |
Cu-catalyzed asymmetric conjugate additions of dialkyl- and diarylzinc reagents to acyclic beta-silyl-alpha,beta-unsaturated ketones. Synthesis of allylsilanes in high diastereo- and enantiomeric purity. | Organic letters 20070802 |
The reactivity of epoxides with lithium 2,2,6,6-tetramethylpiperidide in combination with organolithiums or grignard reagents. | The Journal of organic chemistry 20070622 |
Desymmetrization of 1,4-cyclohexadienyltriisopropoxysilane using copper catalysis. | Organic letters 20070524 |
Alkenylsilane structure effects on mononuclear and binuclear organotitanium-mediated ethylene polymerization: scope and mechanism of simultaneous polyolefin branch and functional group introduction. | Journal of the American Chemical Society 20070314 |
[4 + 2]-annulations of chiral organosilanes: Application to the total synthesis of leucascandrolide A. | The Journal of organic chemistry 20070105 |
Tether-directed synthesis of highly substituted oxasilacycles via an intramolecular allylation employing allylsilanes. | Beilstein journal of organic chemistry 20070101 |
Pd-catalysed [3 + 3] annelations in the stereoselective synthesis of indolizidines. | Beilstein journal of organic chemistry 20070101 |
Enantioselective synthesis of allylsilanes bearing tertiary and quaternary Si-substituted carbons through Cu-catalyzed allylic alkylations with alkylzinc and arylzinc reagents. | Angewandte Chemie (International ed. in English) 20070101 |
Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy. | Beilstein journal of organic chemistry 20070101 |
Development of efficient Lewis acid catalysts for intramolecular cycloaddition reactions of ester-tethered substrates. | Chemical record (New York, N.Y.) 20070101 |
The use of silicon-based tethers for the Pauson-Khand reaction. | Beilstein journal of organic chemistry 20070101 |
A convenient allylsilane-N-acyliminium route toward indolizidine and quinolizidine alkaloids. | Beilstein journal of organic chemistry 20070101 |
Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. | Beilstein journal of organic chemistry 20070101 |
Total synthesis of amphidinolide E. | Journal of the American Chemical Society 20061220 |
Sequential desymmetrization-fluorination: enantioselective synthesis of fluorinated cyclitols. | Chemistry (Weinheim an der Bergstrasse, Germany) 20061213 |
Remote control of diastereoselectivity in intramolecular reactions of chiral allylsilanes. | Journal of the American Chemical Society 20061025 |
A stereocontrolled access to ring-fused piperidines through a formal [2+2+2] process. | Organic letters 20061012 |
Stereoselective synthesis of 2,4,5-trisubstituted tetrahydropyrans using an intramolecular allylation strategy. | Organic letters 20060928 |
Enantioselective total synthesis and stereochemical revision of communiols E and F. | The Journal of organic chemistry 20060804 |
Synthetic studies on (+)-ophiobolin A: asymmetric synthesis of the spirocyclic CD-ring moiety. | Organic letters 20060511 |
Radical-mediated 5-exo-trig cyclizations of 3-silylhepta-1,6-dienes. | The Journal of organic chemistry 20060428 |
Theoretical study of free-radical-mediated 5-exo-trig cyclizations of chiral 3-substituted hepta-1,6-dienes. | The journal of physical chemistry. A 20060316 |
Construction of an advanced tetracyclic intermediate for total synthesis of the marine alkaloid sarain A. | The Journal of organic chemistry 20060303 |
Alpha-methylene-beta-amino ketone derivatives from beta-ketoallylsilanes. | The Journal of organic chemistry 20060303 |
Dual activation in asymmetric allylsilane addition to chiral N-acylhydrazones: method development, mechanistic studies, and elaboration of homoallylic amine adducts. | The Journal of organic chemistry 20060106 |
The mechanism of photochemical 1,3-silyl migration of allylsilane. | The journal of physical chemistry. A 20051229 |
Free-radical-5-exo-trig cyclization of chiral 3-silylhepta-1,6-dienes: concise approach to the A-B-C ring core of hexacyclinic acid. | The Journal of organic chemistry 20050930 |
Synthesis of (+)-bullatacin via the highly diastereoselective [3+2] annulation reaction of a racemic aldehyde and a nonracemic allylsilane. | Organic letters 20050915 |
Synthesis and chemistry of bridgehead allylsilanes. Stereoselective reactions with aldehydes. | Organic letters 20050901 |
Silylcuprates from allene and their reaction with alpha,beta-unsaturatedd nitriles and imines. Synthesis of silylated oxo compounds leading to cyclopentane and cycloheptane ring formation. | The Journal of organic chemistry 20050819 |
Extending Pummerer reaction chemistry. development of a strategy for the regio- and stereoselective oxidative cyclization of 3-(omega-nucleophile)-tethered indoles. | The Journal of organic chemistry 20050805 |
Total synthesis of hyacinthacine A1 and 3-epi-hyacinthacine A1. | Organic letters 20050623 |
One-step synthesis of triethynylvinylmethanes and tetraethynylmethanes by GaCl(3)-promoted diethynylation of 1,4-enynes and 1,4-diynes. | Journal of the American Chemical Society 20050615 |
Tandem Sakurai-aldol addition reactions as a route to structurally complex carbocycles. | The Journal of organic chemistry 20050527 |
Preparation of multisubstituted allenes from allylsilanes. | The Journal of organic chemistry 20050513 |
Synthetic studies on (-)-lemonomycin: stereocontrolled construction of the 3,8-diazabicyclo[3.2.1] skeleton. | Chemical communications (Cambridge, England) 20050121 |
Catalytic asymmetric reactions for organic synthesis: the combined C-H activation/siloxy-cope rearrangement. | The Journal of organic chemistry 20041224 |
Anodic coupling reactions: the use of N,O-ketene acetal coupling partners. | Organic letters 20041111 |
Synthesis of the C11-C29 fragment of amphidinolide F. | Organic letters 20041014 |
Stereoselective synthesis of allyl-C-mannosyl compounds: use of a temporary silicon connection in intramolecular allylation strategies with allylsilanes. | The Journal of organic chemistry 20040917 |
Enantioselective synthesis of (-)-dendroprimine and isomers. | Journal of natural products 20040601 |
Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon. | Journal of the American Chemical Society 20040526 |
Stereocontrol in organic synthesis using silicon-containing compounds. Studies directed towards the synthesis of ebelactone A. | Organic & biomolecular chemistry 20040407 |
Ligand-controlled highly stereoselective syntheses of e- and z-allylsilanes from dienes and aldehydes using nickel complex. | Organic letters 20040401 |
Accurate determinations of the extent to which the SE2' reactions of allyl-, allenyl- and propargylsilanes are stereospecifically anti. | Organic & biomolecular chemistry 20040307 |
Investigation into the allylation reactions of aldehydes promoted by the CeCl3.7H2O-NaI system as a Lewis acid. | The Journal of organic chemistry 20040220 |
Methyl and silyl mesolytic dissociations in the radical cations and radical anions of but-1-ene, allylsilane, hexa-1,3-diene, and penta-2,4-dienylsilane. CAS-MCSCF and coupled cluster theoretical study. | The Journal of organic chemistry 20030808 |
New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to oxygen as a surrogate to the aldol reaction. | The Journal of organic chemistry 20030808 |
Total synthesis of (+)-4,5-deoxyneodolabelline. | Journal of the American Chemical Society 20030219 |
Stereoselective synthesis of tetrahydropyrans via formal [4 + 2]-cycloaddition: a comparison of allylsilane and crotylsilane. | The Journal of organic chemistry 20021101 |
Oxidative cyclization based on reversing the polarity of enol ethers and ketene dithioacetals. Construction of a tetrahydrofuran ring and application to the synthesis of (+)-nemorensic Acid. | Journal of the American Chemical Society 20020828 |
Synthesis of (+/-)-5-epi-citreoviral and (+/-)-citreoviral and the kinetic resolution of an allylic silane by a [3 + 2] annulation. | Organic letters 20020822 |
Studies directed toward the total synthesis of discodermolide: asymmetric synthesis of the C1-C14 fragment. | Organic letters 20020711 |
Stereoselective total syntheses of the racemic form and the natural enantiomer of the marine alkaloid lepadiformine via a novel N-acyliminium ion/allylsilane spirocyclization strategy. | The Journal of organic chemistry 20020614 |
A general catalytic allylation using allyltrimethoxysilane. | Journal of the American Chemical Society 20020612 |
Novel syntheses of hexahydropyrimidines and tetrahydroquinazolines. | The Journal of organic chemistry 20020503 |
The intriguing reactivity of functionalized beta-amino alcohols with glyoxal: application to a new expedient enantioselective synthesis of trans-6-alkylpipecolic acids. | The Journal of organic chemistry 20020419 |
Short total synthesis of (+)-madindolines A and B. | Organic letters 20020221 |
Efficient synthesis of tetrasubstituted alkenes by allylsilane-terminated domino-Heck double cyclisation. | Chemistry (Weinheim an der Bergstrasse, Germany) 20020118 |
Intramolecular cyclization of tert-butyldiphenylallylsilane units and carbonyl groups: allylsilane terminated cyclization versus the ene reaction. | The Journal of organic chemistry 20011116 |
Palladium-catalyzed cyclization of allylsilanes with nucleophilic displacement of the silyl group. | Chemistry (Weinheim an der Bergstrasse, Germany) 20011001 |
Formation of silazirconacyclopentenes from zirconium-silene complex and alkynes and their reactivities. | Journal of the American Chemical Society 20010509 |
Facial-selective allylation of methyl ketones for the asymmetric synthesis of alpha-substituted tertiary homoallylic ethers. | Chemistry (Weinheim an der Bergstrasse, Germany) 20010316 |
Synthesis of enantiopure homoallylic ethers by reagent controlled facial selective allylation of chiral ketones. | Chemistry (Weinheim an der Bergstrasse, Germany) 20010105 |
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