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14187-32-7 | Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, 6,7,9,10,17,18,20,21-octahydro-
CAS No: 14187-32-7 Catalog No: AG001HAF MDL No:MFCD00005098
Product Description
Catalog Number:
AG001HAF
Chemical Name:
Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, 6,7,9,10,17,18,20,21-octahydro-
CAS Number:
14187-32-7
Molecular Formula:
C20H24O6
Molecular Weight:
360.4010
MDL Number:
MFCD00005098
IUPAC Name:
2,5,8,15,18,21-hexaoxatricyclo[20.4.0.09,14]hexacosa-1(26),9,11,13,22,24-hexaene
InChI:
InChI=1S/C20H24O6/c1-2-6-18-17(5-1)23-13-9-21-11-15-25-19-7-3-4-8-20(19)26-16-12-22-10-14-24-18/h1-8H,9-16H2
InChI Key:
YSSSPARMOAYJTE-UHFFFAOYSA-N
SMILES:
O1CCOc2ccccc2OCCOCCOc2c(OCC1)cccc2
EC Number:
238-041-3
UNII:
0A7W45JCS9
NSC Number:
147771
Properties
Complexity:
300
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
360.157g/mol
Formal Charge:
0
Heavy Atom Count:
26
Hydrogen Bond Acceptor Count:
6
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
360.406g/mol
Monoisotopic Mass:
360.157g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
55.4A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
2.2
Literature
| Title | Journal |
|---|---|
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| Binding selectivity of dibenzo-18-crown-6 for alkali metal cations in aqueous solution: A density functional theory study using a continuum solvation model. | Chemistry Central journal 20120101 |
| A molecular chalice with hydrophobic walls and a hydrophilic rim: self-assembly and complexation properties. | Chemical communications (Cambridge, England) 20111228 |
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| Preparation of 4,4'-bis-(carboxyl phenylazo)-dibenzo-18-crown-6 dye and its application on ratiometric colorimetric recognition to Hg2+. | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110801 |
| Could LogP be a principal determinant of biological activity in 18-crown-6 ethers? Synthesis of biologically active adamantane-substituted diaza-crowns. | European journal of medicinal chemistry 20110801 |
| Structure of host-guest complexes between dibenzo-18-crown-6 and water, ammonia, methanol, and acetylene: evidence of molecular recognition on the complexation. | Physical chemistry chemical physics : PCCP 20110421 |
| Supramolecular cations of the m-fluoroanilinium(dibenzo[18]crown-6) in ferromagnetic salt. | Dalton transactions (Cambridge, England : 2003) 20110221 |
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| Electrochemical study of dopamine and noradrenaline at the water/1,6-dichlorohexane interface. | Physical chemistry chemical physics : PCCP 20101214 |
| Hydro-nium perchlorate-dibenzo-18-crown-6 (1/1): monoclinic polymorph. | Acta crystallographica. Section E, Structure reports online 20101201 |
| Ultraviolet photodepletion spectroscopy of dibenzo-18-crown-6-ether complexes with alkaline Earth metal divalent cations. | The journal of physical chemistry. A 20101028 |
| 4-Methoxyanilinium tetrafluoroborate-dibenzo-18-crown-6 (1/1). | Acta crystallographica. Section C, Crystal structure communications 20100801 |
| {Ba[Au(SCN)(2)](2)}(n): a three-dimensional net comprised of monomeric and trimeric gold(I) units. | Acta crystallographica. Section E, Structure reports online 20100701 |
| Conformational polymorph of o-aminoanilinium(dibenzo[18]crown-6) supramolecules in [Ni(dmit)2]- salts. | Chemistry, an Asian journal 20100301 |
| Solvation of dichlorocarbene: complexation with aryl ethers. | The journal of physical chemistry. A 20100114 |
| Synergistic effect of 18-crown-6 derivatives on chelate extraction of lanthanoids(III) into an ionic liquid with 2-thenoyltrifluoroacetone. | Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20100101 |
| Structures and encapsulation motifs of functional molecules probed by laser spectroscopic and theoretical methods. | Sensors (Basel, Switzerland) 20100101 |
| 18-Crown-6 and dibenzo-18-crown-6 assisted extraction of cesium from water into room temperature ionic liquids and its correlation with stability constants for cesium complexes. | Molecules (Basel, Switzerland) 20091202 |
| Effect of cation driven loading of dibenzo-18-crown-6 in Nafion-117 membrane on the diffusion and transport behavior of alkali metal ions. | The journal of physical chemistry. B 20091001 |
| Bilayer lipid membrane (BLM) based ion selective electrodes at the meso-, micro-, and nano-scales. | Biosensors & bioelectronics 20090315 |
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| Dibenzo-18-crown-6. | Acta crystallographica. Section E, Structure reports online 20081001 |
| Electrochemical detection of oligopeptides at silicon-fabricated micro-liquid/liquid interfaces. | Analytical chemistry 20080801 |
| Syntheses of cis- and trans-dibenzo-30-crown-10 derivatives via regioselective routes and their complexations with paraquat and diquat. | The Journal of organic chemistry 20080801 |
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| The solvation of carbenes: π and O-ylidic complexes of p-nitrophenylchlorocarbene. | The journal of physical chemistry. A 20080522 |
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| Biphasic electrospray ionization for the study of interfacial complexes. | Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20080101 |
| Solubilization of single-wall carbon nanotubes in Organic solvents without sidewall functionalization. | Journal of nanoscience and nanotechnology 20071001 |
| Laser spectroscopic study on the conformations and the hydrated structures of benzo-18-crown-6-ether and dibenzo-18-crown-6-ether in supersonic jets. | Physical chemistry chemical physics : PCCP 20070828 |
| EIS multianalyte sensing with an automated SIA system-An electronic tongue employing the impedimetric signal. | Talanta 20070430 |
| Studies on the structure and miscibility of mixed Langmuir-Blodgett films of a double-armed dibenzo-18-crown-6 ether with stearic acid. | Journal of colloid and interface science 20070315 |
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| Ion-selective electrodes for determination of organic ammonium ions: Ways for selectivity control. | Talanta 20061215 |
| Prediction of estrogen receptor agonists and characterization of associated molecular descriptors by statistical learning methods. | Journal of molecular graphics & modelling 20061101 |
| Sterically crowded azulene-based dication salts as novel guests: synthesis and complexation studies with crown ethers and calixarenes in solution and in the gas phase. | Organic & biomolecular chemistry 20060821 |
| Facilitated transfer of alkali-metal cations by dibenzo-18-crown-6 across the electrochemically polarized interface between an aqueous solution and a hydrophobic room-temperature ionic liquid. | Analytical chemistry 20060815 |
| Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies. | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060515 |
| Quantitative analysis of the structure-hydrophobicity relationship for di- and tripeptides based on voltammetric measurements with an oil/water interface. | Physical chemistry chemical physics : PCCP 20060227 |
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| Electronic and infrared spectral and thermal studies on the molecular complex of dibenzo-18-crown-6 and iodine. | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050601 |
| Low-coordinate chromium siloxides: the 'box' [Cr(mu-Cl)(mu-OSitBu3)]4, distorted trigonal [(tBu3SiO)3Cr][Na(benzene)] and [(tBu3SiO)3Cr][Na(dibenzo-18-c-6)], and trigonal (tBu3SiO)3Cr. | Inorganic chemistry 20050418 |
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| Bis-functionalized fullerene-dibenzo[18]crown-6 conjugate: synthesis and cation-complexation dependent redox behavior. | Chemical communications (Cambridge, England) 20030721 |
| New high-dimensional networks based on polyoxometalate and crown ether building blocks. | Inorganic chemistry 20030421 |
| 2D-supramolecular arrangements of dibenzo-18-crown-6-ether and its inclusion complex with potassium ion by potential controlled adsorption. | Organic & biomolecular chemistry 20030121 |
| Liquid-liquid extraction, separation recovery and transport of tantalum by crown-ether. | Talanta 20021112 |
| Potentiometric detection of exogenic beta-adrenergic substances in liquid chromatography. | Journal of chromatography. A 20021011 |
| Integrated acquisition of analytical and biopharmaceutical screening data for beta-adrenergic-drugs employing diversified macrocycle supported potentiometric detection in HPLC systems. | Current medicinal chemistry 20020801 |
| Extractive spectrophotometric and inductively coupled plasma atomic emission spectrophotometric determination of titanium by using dibenzo-18-crown-6. | Talanta 20020422 |
| Phenol-containing macrocyclic diamides as new catalysts in the highly regioselective conversion of epoxides to beta-hydroxy thiocyanates. | The Journal of organic chemistry 20011102 |
| Acyclic neutral carrier-based polymer membrane electrode for a stimulant, phentermine. | Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20010601 |
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