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137349-65-6 | Bis(dicyclohexylphosphino);methane
CAS No: 137349-65-6 Catalog No: AG003OAJ MDL No:MFCD00143763
Product Description
Catalog Number:
AG003OAJ
Chemical Name:
Bis(dicyclohexylphosphino);methane
CAS Number:
137349-65-6
Molecular Formula:
C25H46P2
Molecular Weight:
408.5803
MDL Number:
MFCD00143763
IUPAC Name:
dicyclohexyl(dicyclohexylphosphanylmethyl)phosphane
InChI:
InChI=1S/C25H46P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h22-25H,1-21H2
InChI Key:
OWFLJHJHQKHZJR-UHFFFAOYSA-N
SMILES:
C1CCC(CC1)P(C1CCCCC1)CP(C1CCCCC1)C1CCCCC1
Properties
Complexity:
325
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
408.307g/mol
Formal Charge:
0
Heavy Atom Count:
27
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
408.591g/mol
Monoisotopic Mass:
408.307g/mol
Rotatable Bond Count:
6
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
7
Literature
| Title | Journal |
|---|---|
| Design, synthesis, photophysics, and anion-binding studies of bis(dicyclohexylphosphino)methane-containing dinuclear gold(I) thiolate complexes with urea receptors. | Chemistry (Weinheim an der Bergstrasse, Germany) 20100809 |
| Synthesis, characterization, photoinduced isomerization, and spectroscopic properties of vinyl-1,8-naphthyridine derivatives and their copper(I) complexes. | Inorganic chemistry 20100517 |
| Halogen photoreductive elimination from metal-metal bonded iridium(II)-gold(II) heterobimetallic complexes. | Inorganic chemistry 20100315 |
| The controlled formation and cleavage of an intramolecular d8-d8 Pt-Pt interaction in a dinuclear cycloplatinated molecular 'pivot-hinge'. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090803 |
| Ruthenium-catalyzed stereoselective anti-Markovnikov-addition of thioamides to alkynes. | Organic letters 20081016 |
| Unexpected reactivities of Cu2(diphosphine)2 complexes in alcohol: isolation, x-ray crystal structure, and photoluminescent properties of a remarkably stable [Cu3(diphosphine)3(mu3-H)]2+ hydride complex. | Journal of the American Chemical Society 20050406 |
| Structural variations and spectroscopic properties of luminescent mono- and multinuclear silver(I) and copper(I) complexes bearing phosphine and cyanide ligands. | Inorganic chemistry 20050307 |
| Molecular design of luminescence ion probes for various cations based on weak gold(I)...gold(I) interactions in dinuclear gold(I) complexes. | Inorganic chemistry 20041115 |
| Cuprophilic interactions in luminescent copper(I) clusters with bridging bis(dicyclohexylphosphino)methane and iodide ligands: spectroscopic and structural investigations. | Chemistry (Weinheim an der Bergstrasse, Germany) 20040503 |
| Metal-metal interactions in heterobimetallic d8-d10 complexes. Structures and spectroscopic investigation of [M'M' '(mu-dcpm)2(CN)2]+ (M' = Pt, Pd; M' ' = Cu, Ag, Au) and related complexes by UV-vis absorption and resonance Raman spectroscopy and ab initio calculations. | Journal of the American Chemical Society 20030827 |
| Substrate-Binding reactions of the 3[dsigma*psigma] excited state of binuclear gold(I) complexes with bridging bis(dicyclohexylphosphino)methane ligands: emission and time-resolved absorption spectroscopic studies. | Chemistry (Weinheim an der Bergstrasse, Germany) 20011105 |
| Reaction of Re(2)(mu-O(2)CCH(3))(4)Cl(2) with Bis(dicyclohexylphosphino)methane (dcpm): isolation of the mixed-valent complex O(3)ReReCl(eta(2)-dcpm)(2) containing an unsupported Re-Re bond. | Inorganic chemistry 20010604 |
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