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13716-12-6

13716-12-6 | Phosphine, tris(1,1-dimethylethyl)-

CAS No: 13716-12-6 Catalog No: AG0012W0 MDL No:MFCD00015006

Product Description

Catalog Number:
AG0012W0
Chemical Name:
Phosphine, tris(1,1-dimethylethyl)-
CAS Number:
13716-12-6
Molecular Formula:
C12H27P
Molecular Weight:
202.3165
MDL Number:
MFCD00015006
IUPAC Name:
tritert-butylphosphane
InChI:
InChI=1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3
InChI Key:
BWHDROKFUHTORW-UHFFFAOYSA-N
SMILES:
CC(P(C(C)(C)C)C(C)(C)C)(C)C
EC Number:
237-266-4

Properties

Complexity:
128  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
202.185g/mol
Formal Charge:
0
Heavy Atom Count:
13  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
202.322g/mol
Monoisotopic Mass:
202.185g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
2.9  

Literature

Title Journal
Mechanochemical and solution synthesis, X-ray structure and IR and 31P solid state NMR spectroscopic studies of copper(I) thiocyanate adducts with bulky monodentate tertiary phosphine ligands. Dalton transactions (Cambridge, England : 2003) 20120707
Chemically reversible four-electron oxidation and reduction utilizing two inorganic functional groups. Journal of the American Chemical Society 20110309
Reversible, metal-free hydrogen activation by frustrated Lewis pairs. Dalton transactions (Cambridge, England : 2003) 20110207
Synthesis and X-ray structure determination of highly active Pd(II), Pd(I), and Pd(0) complexes of di(tert-butyl)neopentylphosphine (DTBNpP) in the arylation of amines and ketones. The Journal of organic chemistry 20101001
Reactions of the platinum (tri-tert-butylphosphine) group with bridging SbPh2 ligands in rhenium-antimony carbonyl complexes. Inorganic chemistry 20100705
Gold(I)-catalyzed coupling reactions for the synthesis of diverse small molecules using the build/couple/pair strategy. Journal of the American Chemical Society 20090422
Palladium-catalyzed decarboxylative coupling of alkynyl carboxylic acids and aryl halides. The Journal of organic chemistry 20090206
Transformations and reactions of Re2(CO)8(mu-SbPh2)(mu-H) induced by the addition of a platinum(tri-t-butylphosphine) group. Inorganic chemistry 20090119
Sterically hindered benzophenones via rhodium-catalyzed oxidative arylation of aldehydes. The Journal of organic chemistry 20081003
Synthesis of 2-arylpiperidines by palladium couplings of aryl bromides with organozinc species derived from deprotonation of N-boc-piperidine. Organic letters 20080904
Nickel-catalysed reactions with trialkylboranes and silacyclobutanes. Chemical communications (Cambridge, England) 20080728
Palladium-catalysed regioselective addition reaction of ethyl phenylphosphinate with terminal acetylenes: ligand- and solvent-dependent regioselectivity. Chemical communications (Cambridge, England) 20070719
Palladium-catalyzed regiocontrolled alpha-arylation of trimethylsilyl enol ethers with aryl halides. Organic letters 20061207
Stereoselective synthesis of vinylsilanes by a gold(I)-catalyzed acetylenic sila-cope rearrangement. Journal of the American Chemical Society 20060906
Bulky alkylphosphines with neopentyl substituents as ligands in the amination of aryl bromides and chlorides. The Journal of organic chemistry 20060707
Addition of palladium and platinum tri-tert-butylphosphine groups to Re-Sn and Re-Ge bonds. Inorganic chemistry 20050905
Microwave-enhanced carbonylative generation of indanones and 3-acylaminoindanones. The Journal of organic chemistry 20050107
Dinuclear ruthenium and iron complexes containing palladium and platinum with tri-tert-butylphosphine ligands: synthesis, structures, and bonding. Inorganic chemistry 20040628
Bimetallic cluster complexes: the synthesis, structures, and bonding of ruthenium carbonyl cluster complexes containing palladium and platinum with the bulky tri-tert-butyl-phosphine ligand. Journal of the American Chemical Society 20040428
Platinum-rhodium carbonyl clusters: new structures and new types of dynamical activity. Inorganic chemistry 20040419
Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide. Chemical communications (Cambridge, England) 20011007
Synthesis, characterization, and ligand exchange studies of W(6)S(8)L(6) cluster compounds. Inorganic chemistry 20010604
Tris(tert-butyl)phosphine selenide, the missing link in tris(tert-butyl)phosphine chalcogenide structures (t)Bu(3)P==X (X = O, S, Se, Te). Acta crystallographica. Section C, Crystal structure communications 20010301

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