200,000+ products from a single source!
sales@angenechem.com
Home > Fluorides > 115464-59-0
115464-59-0 | Dioxirane, methyl(trifluoromethyl)-
CAS No: 115464-59-0 Catalog No: AG000G1A MDL No:
Product Description
Catalog Number:
AG000G1A
Chemical Name:
Dioxirane, methyl(trifluoromethyl)-
CAS Number:
115464-59-0
Molecular Formula:
C3H3F3O2
Molecular Weight:
128.0499
IUPAC Name:
3-methyl-3-(trifluoromethyl)dioxirane
InChI:
InChI=1S/C3H3F3O2/c1-2(7-8-2)3(4,5)6/h1H3
InChI Key:
NEGUMGNBGIFXAL-UHFFFAOYSA-N
SMILES:
FC(C1(C)OO1)(F)F
UNII:
A7JNM906ZN
Properties
Complexity:
104
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
128.009g/mol
Formal Charge:
0
Heavy Atom Count:
8
Hydrogen Bond Acceptor Count:
5
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
128.05g/mol
Monoisotopic Mass:
128.009g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
25.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.4
Literature
| Title | Journal |
|---|---|
| Design, synthesis, and biological evaluation of novel fluorinated ethanolamines. | Chemistry (Weinheim an der Bergstrasse, Germany) 20111223 |
| Reactions at interfaces: oxygenation of n-butyl ligands anchored on silica surfaces with methyl(trifluoromethyl)dioxirane. | The Journal of organic chemistry 20111216 |
| Selective synthesis of hydroxy analogues of valinomycin using dioxiranes. | Organic letters 20111007 |
| Concerning selectivity in the oxidation of peptides by dioxiranes. Further insight into the effect of carbamate protecting groups. | The Journal of organic chemistry 20100716 |
| Oxyfunctionalization of non-natural targets by dioxiranes. 6. On the selective hydroxylation of cubane. | Organic letters 20090820 |
| A facile synthesis of C-24 and C-25 oxysterols by in situ generated ethyl(trifluoromethyl)dioxirane. | Steroids 20090101 |
| An investigation by means of correlation analysis into the mechanisms of oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane in various solvents. | Organic & biomolecular chemistry 20080221 |
| Oxidation of peptides by methyl(trifluoromethyl)dioxirane: the protecting group matters. | The Journal of organic chemistry 20070119 |
| Oxidative cleavage of p-methoxybenzyl ethers with methyl(trifluoromethyl)dioxirane. | Organic letters 20051013 |
| Oxygenation of alkane C-H bonds with methyl(trifluoromethyl)dioxirane: effect of the substituents and the solvent on the reaction rate. | The Journal of organic chemistry 20050930 |
| Mechanism of the oxidation of sulfides by dioxiranes: conformational mobility and transannular interaction in the oxidation of thianthrene 5-oxide. | The Journal of organic chemistry 20041224 |
| Unexpectedly selective formation and reactions of epoxycyclooctenones under microwave-mediated conditions. | Organic letters 20040415 |
| Singlet-oxygen generation in the catalytic reaction of dioxiranes with nucleophilic anions. | Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20040201 |
| Epoxidation of chiral camphor N-enoylpyrazolidinones with methyl(trifluoromethyl)dioxirane and urea hydrogen peroxide/acid anhydride: reversal of stereoselectivity. | The Journal of organic chemistry 20031212 |
| Oxyfunctionalization of non-natural targets by dioxiranes. 5. Selective oxidation of hydrocarbons bearing cyclopropyl moieties. | The Journal of organic chemistry 20031003 |
| Relative reactivity of peracids versus dioxiranes (DMDO and TFDO) in the epoxidation of alkenes. A combined experimental and theoretical analysis. | Journal of the American Chemical Society 20030129 |
| Mechanism of the oxidation of sulfides by dioxiranes. 1. Intermediacy of a 10-S-4 hypervalent sulfur adduct. | Journal of the American Chemical Society 20020807 |
| Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane. | The Journal of organic chemistry 20020531 |
| Oxyfunctionalization of non-natural targets by dioxiranes. 4. Efficient oxidation of Binor S using methyl(trifluoromethyl)dioxirane. | The Journal of organic chemistry 20011228 |
Related Products
Featured Products
© 2019 Angene International Limited. All rights Reserved.